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The solution reaction of 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole (bpt), benzene-1,2,4,5-tetracarboxylic acid (H4betc) and Co(NO3)2·6H2O led to the formation of the title cocrystal compound Hbpt·H3betc or C12H11N6+·C10H5O8-, in which strong hydrogen-bonding interactions assemble the ions into a three-dimensional supramolecular framework. [ABSTRACT FROM AUTHOR]

Hydro­thermal reaction of Zn(NO3)2·6H2O with pyridine-2,5-dicarboxylic acid, 4,4′-bipyridine and pyridine in a 1:1:1:2 molar ratio affords the title complex, (C10H10N2)[Zn(C7H3NO4)2(H2O)2], in which both ions are centrosymmetric. The ZnII atom is octahedrally coordin­ated by two pyridine-2,5-dicarboxyl­ate chelating ligands and two water mol­ecules in a distorted octa­hedral geometry. 4,4′-Bipyridinium, acting as counter-ion, has hydrogen-bonding inter­actions with pyridine-2,5-dicarboxyl­ate, forming a three-dimensional structure. [ABSTRACT FROM AUTHOR]

The solution reaction of Zn2+ with 5-aminoisoquinoline and NaN3 afforded the mononuclear title complex, [Zn(N3)2(C9H8N2)2]. The azide anions and the 5-aminoisoquinoline molecules act as monodentate ligands, resulting in a slightly distorted ZnN4 tetrahedron. A network of weak N—H...N hydrogen bonds helps to consolidate the crystal packing. [ABSTRACT FROM AUTHOR]

The solution reaction of FeII with 1,10-phenanthroline and NaN3 affords the title complex, [Fe(N3)2(C12H8N2)2]. In this complex, the central atom adopts a six-coordinate octahedral geometry, with monodentate azide ligands occupying the cis sites and two phenanthroline ligands occupying the other four sites, forming a cis isomer. [ABSTRACT FROM AUTHOR]