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In the crystal structure of the title compound, [Pd2(C22H17N2)2(C12H12N2)2](PF6)2·C4H10O·H2O, two Pd(dmbpy) units (dmbpy is 4,4′-dimethyl-2,2′-bipyridine) are bridged by 4-benzyl-3,5-diphenylpyrazolate ligands in an exodentate fashion, which results in a clip-like cavity between the two Pd(dmbpy)Pd planes. A disordered hexafluoridophosphate anion is held in the cavity by an anion–π interaction [P—F... Cg1 = 3.435 (15) Å ( Cg1 is the centroid of the Pd–dmbpy chelate ring system) and P—F... Cg2 = 3.187 (15) Å ( Cg2 is the centroid of a pyridine ring)]. A crystallographic twofold rotation axis passes through an F atom of the disordered anion and the mid-point of the two Pd atoms. The P and two F atoms of the second anion also lie on a twofold rotation axis, as do the O atom of the diethyl ether and the water O atom. The crystal structure is stabilized by electrostatic forces between the cations and anions, and intermolecular hydrogen bonds involving hexafluoridophosphate anions (C—H...F), the solvent diethyl ether molecules and water molecules (C—H...O). [ABSTRACT FROM AUTHOR]

In the crytal structure of the title compound, [Pd2(C56H50N8)]2(BF4)4·8CH3CN·H2O, the asymmetric 5-phenyl-3- p-tolyl­pyrazolate ligands bridge (4,4′-dimethyl-2,2′-bipyridine-κ2 N, N′)palladium(II) units in cis and trans fashions, resulting in two coexistent dipalladium complexes. The six-membered rings consisting of the two Pd atoms and the four pyrazolyl N atoms have boat-shaped conformations in both independent complexes; the Pd atoms are four-coordinate in square-planar environments. The crystal structure is stabilized by electrostatic forces between the cations and anions, and weak inter­molecular hydrogen bonds involving tetraflurido­borate anions (C—H⋯F), the solvent acetonitrile mol­ecules (C—H⋯N) and water mol­ecules (C—H⋯O). [ABSTRACT FROM AUTHOR]

In the title complex, [Pd2(C10H12O4)(C12H8N2)2](PF6)2·CH3CN, the PdII centre has a distorted cis square-planar geometry defined by an O, O′-bidentate bis­acetyl­acetonate dianion ligand and a chelating 1,10-phenanthroline ligand. The crystal structure features electrostatic inter­actions between the cations and anions, inter­molecular π–π inter­actions between pairs of 1,10-phenanthroline rings, and weak hydrogen bonds involving hexa­fluoro­phosphate anions (C—H⋯F) and the acetonitrile solvent mol­ecules (C—H⋯N). [ABSTRACT FROM AUTHOR]

In the title complex, (C12H9N2)[ReO4], the ions are connected together via hydrogen bonds. The crystal structure comprises alternating layers of cations and anions aligned along the b-axis direction. [ABSTRACT FROM AUTHOR]

In the title complex, [Pd2(C10H12O4)2(C10H8N2)2](PF6)2--CH3CN, the PdII centers have a distorted cis-square-planar geometry defined by an O,O'-bidentate bisacetylacetonate dianion ligand and a chelating 2,20-bipyridine ligand. The crystal structure is stabilized by electrostatic forces between the cations and anions, intermolecular π-π stacking interactions between pairs of 2,20-bipyridine rings, and weak intermolecular hydrogen bonds involving exafluorophosphate anions (C—H…F) and the solvent acetonitrile molecules (C—H…N). [ABSTRACT FROM AUTHOR]

In the crystal structure of the title salt, [Pd2(C15H11N2)2(C12H12N2)2](PF6)2, two (4,4′-dimethyl-2,2′-bipyridine)palladium(II) units are bridged by two pyrazolate ligands in an exodentate fashion. The six-membered ring consisting of the two Pd atoms and the four pyrazolyl N atoms has a boat-shaped conformation and the Pd atoms are four-coordinate in square-planar environments. The cation and both anions have crystallographically imposed mirror symmetry. [ABSTRACT FROM AUTHOR]