1. cis-(Benzenethiolato)bis(tert-butyl isocyanide)carbonyl(cyclopentadienyl)molybdenum(II), [Mo(C6H5S)(C5H9N)2(C5H5)(CO)]
- Author
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Sylvie Poder-Guillou, Philippe Schollhammer, Kenneth W. Muir, Lindsay C. McDermott, François Y. Pétillon, University of Glasgow, Chimie,Photochimie et Electrochimie Moléculaires (URA CNRS 322), and Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
chemistry.chemical_classification ,Base (chemistry) ,Stereochemistry ,Significant difference ,chemistry.chemical_element ,General Medicine ,Crystal structure ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,Medicinal chemistry ,General Biochemistry, Genetics and Molecular Biology ,0104 chemical sciences ,3. Good health ,Bond length ,chemistry.chemical_compound ,Cyclopentadienyl complex ,chemistry ,Molybdenum ,[CHIM]Chemical Sciences ,Molecule ,tert-Butyl isocyanide - Abstract
International audience; In [CpMo(SPh)(CO)(CNtBu)2], Cp = η5-C5H5, the Mo atom adopts conventional four-legged piano-stool coordination geometry; a pair of cis CNtBu ligands, together with carbonyl and benzenethiolato groups, make up the base. The Mo-CNtBu bond lengths [2.053 (4) Å trans to S, 2.086 (4) Å trans to CO] show a small but significant difference.
- Published
- 1996
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