Search

Your search keyword '"Chen, Yunrong"' showing total 3 results
Start Over Author "Chen, Yunrong" Journal advanced synthesis & catalysis
3 results on '"Chen, Yunrong"'

3. Kinetic Resolution of 2‐N‐Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines.

Author

Pan, Yongkai, Jiang, Qianwen, Rajkumar, Subramani, Zhu, Chaofan, Xie, Jinglei, Yu, Shaoze, Chen, Yunrong, He, Yu‐Peng, and Yang, Xiaoyu

Subjects
KINETIC resolution, ALLYL alcohol, ASYMMETRIC synthesis, PHOSPHORIC acid
Abstract

A series of cyclohexyl‐fused SPINOL‐derived phosphoric acids (Cy‐SPA) have been developed to catalyze the kinetic resolution of 2‐N‐acylamido tertiary allylic alcohols, providing access to chiral oxazolines bearing C‐2 alkyl substituents with high enantioselectivities (with s‐factors up to 153). Gram‐scale reaction with 1 mol% catalyst loading and transformations of the chiral products demonstrates the value of these methods. [ABSTRACT FROM AUTHOR]

Published
2021
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results