Search

Your search keyword '"Day, Benjamin M."' showing total 7 results
Start Over Author "Day, Benjamin M." Journal angewandte chemie international edition
7 results on '"Day, Benjamin M."'

7. Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.

Author

Pal, Kuntal, Hemming, Oliver B., Day, Benjamin M., Pugh, Thomas, Evans, David J., and Layfield, Richard A.

Subjects
CARBENE synthesis, PHOSPHINIDENES, IRON catalysts, COBALT catalysts, HETEROCYCLIC compounds, STOICHIOMETRY
Abstract

In the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)⋅PAr. The formation of (IMe4)⋅PMes (Mes=mesityl) is also catalyzed by the phosphinidene-bridged complex [(IMe4)2Fe(μ-PMes)]2, which provides evidence for metal-catalyzed phosphinidene transfer. [ABSTRACT FROM AUTHOR]

Published
2016
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results