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Start Over Author "Kärkäs, Markus D." Journal angewandte chemie international edition
6 results on '"Kärkäs, Markus D."'

2. Electrosynthetic C−O Bond Activation in Alcohols and Alcohol Derivatives.

Author

Villo, Piret, Shatskiy, Andrey, Kärkäs, Markus D., and Lundberg, Helena

Subjects
SCISSION (Chemistry), CHARGE exchange, ORGANIC synthesis, ALCOHOL
Abstract

Alcohols and their derivatives are ubiquitous and versatile motifs in organic synthesis. Deoxygenative transformations of these compounds are often challenging due to the thermodynamic penalty associated with the cleavage of the C−O bond. However, electrochemically driven redox events have been shown to facilitate the C−O bond cleavage in alcohols and their derivatives either through direct electron transfer or through the use of electron transfer mediators and electroactive catalysts. Herein, a comprehensive overview of preparative electrochemically mediated protocols for C−O bond activation and functionalization is detailed, including direct and indirect electrosynthetic methods, as well as photoelectrochemical strategies. [ABSTRACT FROM AUTHOR]

Published
2023
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