1. Graphdiyne under pressure: A Raman study
- Author
-
Jiajun Dong, Huibiao Liu, Mingguang Yao, Yan Wang, Yanhuan Chen, Ran Liu, Bingbing Liu, Xigui Yang, Yuliang Li, and Mingrun Du
- Subjects
Materials science ,Physics and Astronomy (miscellaneous) ,Graphene ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Molecular physics ,Pressure coefficient ,0104 chemical sciences ,law.invention ,Vibration ,Graphyne ,symbols.namesake ,law ,High pressure ,symbols ,Anomaly (physics) ,0210 nano-technology ,Raman spectroscopy - Abstract
High pressure Raman spectra of graphdiyne (GDY) have been studied up to 34.63 GPa. We found that sp-hybridized carbons in GDY are highly active and start to undergo a bonding change at around 5.2 GPa. Such a bonding change affects the C-C stretching vibration of sp2 hexagon rings in GDY, leading to an anomaly in the corresponding G-band pressure coefficient. A three-dimensional sp2 structure is proposed to form via pressure-induced interlayer cross-linking of sp carbons in GDY and is stable up to at least 34.63 GPa. Our study presents an important example in the study of graphyne family under pressure.
- Published
- 2018