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Water-soluble silver nanoclusters (AgNCs) as a new type of fluorescent material have attracted much attention for their remarkable optical properties and excellent cytocompatibility. However, it is still challenging to synthesize water-soluble AgNCs with good cytocompatibility and excellent fluorescence. Herein, the dialdehyde nanofibrillated cellulose (DANFC)- reduced water-soluble AgNCs capped by glutathione (GSH) with tunable fluorescence emissions were first reported. The DANFC provides a mild reduction environment and crystal growth system for the coordination between silver ions and GSH compared to conventional methods using strong reducing agents. The AgNCs with intense red fluorescence (R-AgNCs@GSH, size ∼2.24 nm) and green fluorescence (G-AgNCs@GSH, size ∼1.93 nm) were produced by varying the ratios of silver sources and ligands, and could maintain stable fluorescence intensity over 6 months. Moreover, the CCK-8 study demonstrated that the R-AgNCs@GSH and G-AgNCs@GSH reduced by DANFC of excellent cytocompatibility (cell viability >90 %) and enable precise multicolor intracellular imaging of Hela cells in 1 h. This work proposes a novel method to synthesize water-soluble AgNCs with tunable fluorescence emission at room temperature based on the classical silver- mirror reaction (SMR) using DANFC as reducing agent, and the synthesized fluorescent AgNCs have great potential as novel luminescent nanomaterials in biological research., Competing Interests: Declaration of competing interest The authors declare no conflict of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Cellulose acetate (CA)-based electrospun nanofiber aerogel (ENA) has drawn extensive attention for wastewater remediation due to its unique separation, inherent porosity and biodegradability. However, the low mechanical strength, poor durability, and limited adsorption ability hinder its further applications. We herein propose using silane-modified ENA, namely T-CA@Si@ZIF-67 (T-ENA), with enhanced resilience, hydrophobicity, durability and hetero-catalysis to remediate a complex wastewater containing oil and drug residues. The robust T-ENA was fabricated by pre-doping tetraethyl orthosilicate (TEOS) and ligand in its spinning precursors, followed by in-situ anchoring of porous ZIF-67 on the electrospun nanofibers (ENFs) via seeding method before freeze-drying and thermal curing (T). Results show that the T-ENA displays enhanced mechanical stability/resilience and hydrophobicity without compromise of its high porosity (>98 %) and low density (10 mg/cm 3 ) due to the silane cross-linking. As a result, the hydrophobic T-ENA shows over 99 % separation efficiency towards different oil-water solutions. Meanwhile, thanks to the enhanced adsorption-catalytic ability and the activation of peroxymonosulfate (PMS) from the porous ZIF-67, fast degradation of carbamazepine (CBZ) residue in the wastewater can be achieved within 20 min. This work might provide a novel strategy for developing CA aerogels to remove organic pollutants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Conductive hydrogels have received increasing attention in the field of wearable electronics, but they also face many challenges such as temperature tolerance, biocompatibility, and stability of mechanical properties. In this paper, a double network hydrogel of MXene/TEMPO bacterial cellulose (TOBC) system is proposed. Through solvent replacement, the hydrogel exhibits wide temperature tolerance (-20-60 °C) and stable mechanical properties. A large number of hydrogen bonds, MXene/TOBC dynamic three-dimensional network system, and micellar interactions endow the hydrogel with excellent mechanical properties (elongation at break ~2800 %, strength at break ~420 kPa) and self-healing ability. The introduction of tannic acid prevents the oxidation of MXene and the loss of electrical properties of the hydrogel. In addition, the sensor can also quickly (74 ms) and sensitive (gauge factor = 15.65) wirelessly monitor human motion, and the biocompatibility can well avoid the stimulation when it comes into contact with the human body. This series of research work reveals the fabrication of MXene-like flexible wearable electronic devices based on self-healing, good cell compatibility, high sensitivity, wide temperature tolerance and durability, which can be used in smart wearable, wireless monitoring, human-machine Interaction and other aspects show great application potential., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The objective of this study was to produce high-performance and biodegradable starch nanocomposites through film casting by using corn starch/nanofibrillated cellulose (CS/NFC) and corn starch/nanofibrillated lignocellulose (CS/NFLC). NFC and NFLC were obtained by super grinding process and added to fibrogenic solutions (1, 3, and 5 g/100 g of starch). The addition of NFC and NFLC from 1 to 5 % was verified to be influential in enhancing mechanical properties (tensile, burst, and tear index) and reducing WVTR, air permeability, and essential properties in food packaging materials. But, in comparison to control samples, the addition of NFC and NFLC from 1 to 5 % decreased the opacity, transparency, and tear index of films. In acidic solutions, produced films were more soluble than in alkaline or water solutions. The soil-biodegradability analysis showed that after 30 days of exposure to soil, the control film lost 79.5 % of its weight. The weight loss of all films was >81 % after 40 days. The results of this study may contribute to expanding the industrial applications of both NFC and NFLC by laying a basis for preparing high-performance CS/NFC or CS/NFLC., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Hydrogels with prominent flexibility, versatility, and high sensitivity play an important role in the design and fabrication of wearable sensors. In particular, these flexible conductive hydrogels exhibit elastic modulus that is highly compatible with human skin, demonstrating the great potential for flexible sensing. However, the preparation of high-performance hydrogel-based sensors that can restrain extreme cold conditions is still challenging. Herein, a novel anti-freezing composite hydrogel with superior conductivity based on polyacrylamide (PAM), LiCl, and PEDOT:PSS coated cellulose nanofibrils (PAM/PEDOT:PSS/CNF) is constructed. The addition of CNF increased the hydrogen bonding sites of the molecular chains in the micro, thus improving the mechanical strength and the conductivity of the hydrogel in the macro. The hydrogels achieve a high tensile strength of 0.19 MPa, compressive strength of 0.92 MPa, and dissipation energy of 41.9 kJ/m 3 . Otherwise, LiCl increases the interactions between the colloidal phase and water molecules, endowing the hydrogels with excellent freezing tolerance. Specifically, the optimized hydrogel of 45 % LiCl exhibited stable mechanical properties at -40 °C. Finally, the composite hydrogel was used to assemble flexible sensors with high sensitivity of 10.3 MPa -1 , which can detect a wide range of human movements and physiological activities., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Hydrogel with 3D networks have shown great potential for ion transportation and energy conversion. However, the micron size pores of hydrogel greatly limit the ion selectivity and energy conversion performance. Here, we report a bacterial cellulose (BC) derived hydrogel membrane with double-network (DN) and tailored ion transport channels by rationally filling acrylic acid (AAc)-co-acrylamide (AAm)-co-methyl methacrylate (MMA) polymers into BC hydrogel micropores. Fabricated AAM/BC DN hydrogel membrane displays a unique hierarchical interconnected porous structure and 3D cation transport channels. From the results, the maximum power density reached up to 7.63 W·m -2 at 50-fold salinity gradient under alkaline conditions (pH 11). Interestingly, the power density of 45.5 W·m -2 was achieved through acid-base neutralization reaction. Furthermore, hydrogel successfully obtained a power density of 28.4 W·m -2 from a mixed system of paper black liquor wastewater/seawater. The results of this investigation suggested the enormous potential of BC-based nanofluidic membrane in sustainable osmotic energy conversion., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Liquid metal (LM) nanodroplets and MXene nanosheets are integrated with sulfonated bacterial nanocellulose (BNC) and acrylic acid (AA). Upon fast sonication, AA polymerization leads to a crosslinked composite hydrogel in which BNC exfoliates Mxene, forming organized conductive pathways. Soft conducting properties are achieved in the presence of colloidally stable core-shell LM nanodroplets. Due to the unique gelation mechanism and the effect of Mxene, the hydrogels spontaneously undergo surface wrinkling, which improves their electrical sensitivity (GF = 8.09). The hydrogels are further shown to display interfacial adhesion to a variety of surfaces, ultra-elasticity (tailorable elongation, from 1000 % to 3200 %), indentation resistance and self-healing capabilities. Such properties are demonstrated in wearable, force mapping, multi-sensing and patternable electroluminescence devices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

In the past, electromagnetic interference (EMI) shielding materials have achieved great breakthroughs, however, they still suffer from high reflectivity and poor environmental stability, resulting in detrimental secondary pollution and weak adaptability. Herein, an organohydrogel-based EMI shielding material was prepared through cellulose nanofibril-based Pickering emulsion, composed of an MXene network for electron conduction, encapsulated paraffin wax microspheres with MXene-Fe 3 O 4 shells for multiple scattering of the incident wave, and MXene-CNF-Fe 3 O 4 -polyacrylamide hybrid interfaces for dielectric polarization. The EMI shielding performance of our organohydrogel shows an absorption-dominated feature. It can effectively shield 99.625 % electromagnetic wave, satisfying the requirement of commercial EMI shielding materials. Moreover, the organohydrogel possesses excellent flame retardancy properties and long-time environment properties to improve safety and reliability; and it also demonstrates sensitive deformation responses as an on-skin sensor. Therefore, our organohydrogel can simultaneously detect human motion and protect human from EMI radiation and accidental burn., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The novel photocatalytic advanced oxidation catalyst, ZIF-67@MXene-TA-CNF (ZIF-67@MTC) aerogels, was prepared via introducing tannic acid-coated cellulose nanofibril (TA-CNF), two-dimensional layered MXene, and ZIF-67 into a composite aerogel network. Specially, TA assisted the crosslinking of CNF through hydrogen bonds to construct the flexible aerogel skeleton, accompanied by assembly of MXene and ZIF-67. MXene not only provided sufficient attachment sites for the anchoring of ZIF-67, but also can be used as a repository for electron transfer to facilitate the separation of photogenerated electrons and holes. In the peroxymonosulfate (PMS)/aerogels/visible light system, the SO 4 - , OH and 1 O 2 were generated, and 1 O 2 was the main reactive species. As a result, 99.9 % of Tetrabromobisphenol A (TBBPA) can be degraded and the total organic carbon (TOC) removal efficiency reached 81.8 % within 40 min in this system. The results might provide a new concept for the design of biomass aerogels for applications in organic pollutant removal., Competing Interests: Declaration of competing interest We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influence our work, there is no professional or other personal interest of any nature or kind in any product, service and/or company that could be construed as influencing the position presented in, or the review of, the manuscript entitled, “Ternary ZIF-67/MXene/CNF aerogels for enhanced photocatalytic TBBPA degradation via peroxymonosulfate activation”., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Biodegradable cellulose films with excellent mechanical, optical, and functional properties have attracted considerable attention as promising alternatives to plastics for photoelectronic devices. In this work, mechanically ductile, flame-retardant cellulose films with tunable optical properties were prepared by simple mechanical disintegration of phosphorylated cellulose (PhC) fibers, vacuum filtration of as-prepared dispersions, and subsequent pressing of the wet PhC films to prepare dried films. When mechanical disintegration conditions were optimized, the resultant PhC films exhibited an average density, tensile strength, Young's modulus, tensile toughness, and folding resistance of 1.4 g/cm 3 , 150 MPa, 8.5 GPa, 8.2 MJ/m 3 , and 4580 times, respectively. The PhC film hazes were widely controllable from 9 % to 91 %, while they maintained high light transmittances (>90 %) at a 550-nm wavelength. The PhC films were used for light management of light-emitting diodes by controlling mechanical fibrillation conditions of the PhC fiber/water slurry, showing that the films effectively improved the luminescence uniformity of the devices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Most technologies to produce multifunctional paper involved the defect of poor uniformity and stability. Herein, a high stability multi-functional cellulose-based paper was developed via a multiple chemical modification derived from waste bagasse. Firstly, the acetoacetyl groups was anchored on the surface of bagasse cellulose fibers by a heterogeneous transesterification. Then, paper was made based on these modified fibers. The fluorophore and gentamicin sulfate (Gen) were bonded in-situ to the paper through Hantzsch reaction and the form of enamine bond, respectively. The resulting paper exhibited excellent multifunctional properties, such as fluorescence property, antibacterial property and hydrophobic property. These properties are very stable to external environments. In addition, relatively mild surface modification has no obvious effect on fibers and shows similar whiteness and stiffness properties as that of the CAA paper. Thus, these novel functional papers held great potential for many fields such as food packaging, anti-counterfeiting, and other specialty papers., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

In this study, colorimetric indicator films (CIFs) were developed by integrating neutral red covalently immobilized onto TEMPO-oxidized cellulose nanofibrils (NR@TOCNFs) and poly(acrylic acid) (PAA) inside a poly(vinyl alcohol) (PVA) matrix. The successful covalent immobilization of NR onto the TOCNFs was confirmed using attenuated total reflection-Fourier transform infrared, X-ray photoelectron spectroscopy, and thermogravimetric analyses. The CIFs had a visible color change from red to yellow as the pH changed from 2.0 to 10.0. The colorimetric response of CIFs improved as the NR@TOCNF content increased, while it decreased as the PAA level increased. The critical pH ranges for the color change of CIFs were 6-7, 7-8, and 8-9 for 3 %, 5 %, and 7 % PAA, respectively, at 0.3 % NR@TOCNF. The best ammonia sensitivity was found in the indicator films containing 3 % PAA and 0.3 % NR@TOCNF. These results showed that the CIFs could be applied for freshness detection in food packaging., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The degree of polymerization (DP) of cellulose plays an essential role in unlocking the superior mechanical potential of wood cellulose nanofibrils (CNFs). However, severe degradation of cellulose chains during the chemical pulping is a big challenge to obtain CNFs with high DP. In this work, we tend to improve the DP of wood CNFs by significantly preserving the native structure of wood fibers in an industrial method. Wood sticks are first pretreated with hydrothermal treatment to partially remove hemicellulose, thus leading to an increased porous structure that facilitates the penetration of cooking liquid and lignin removal during delignification, and dilute-alkali-sulfate pulping is then employed to obtain wood fibers with highest viscosity average DP (DP V ) of nearly 2400. After that, the as-prepared wood fibers with high DP are separated into CNFs with highest average DP V of 1333. Finally, we demonstrate the potential application of wood CNFs with improved DP V in the fabrication of strong and tough isotropic films and macrofibers., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Low-temperature two-step concentrated H 2 SO 4 was discovered to be a solvent with high cellulose solubility [>300 g/L (17 wt%)], fast cellulose dissolution, high regeneration yield (>0.92 g/g), and cellulose being mouldable during regeneration. The superior performance was enabled by the much better compatibility of cellulose with lower concentrated H 2 SO 4 at low temperature, compared with that of high concentrated H 2 SO 4 . The regenerated cellulose was characterized by mostly unchanged composition and highly tunable degree of polymerization (DP). The H 2 SO 4 starting content, cotton fibre temperature, dissolution temperature, regeneration temperature, regeneration bath and storage time were factors determining the DP of regenerated cellulose, which could be equivalent to 4-90 % of the original cotton. These advantages of the solvent enabled versatile application in fabrication of extra strong cellulose hydrogels, manufacture of strong cellulose fibres, preparation of various homogenous composites which would be prepared with much more difficulty by using other solvents, and facile manufacture of cellooligosaccharides., Competing Interests: Declaration of competing interest There is no financial and personal relationship with other people or organizations that could inappropriately influence the current work., (Copyright © 2022. Published by Elsevier Ltd.)

Generally, the thermal conductivity (TC) of composite based on cellulose nanofibrils (CNF) is improved by adding thermal conductive filler, which inevitably leads to the loss of its mechanical properties. In this work, it is the first to simultaneously improve the toughness and TC of CNF/boron nitride nanosheets (BNNS) composite from the perspective of thermal conductive filler addition and CNF crystal change. The hydrophilic-modified BNNSs were successfully prepared by xylose-assisted ball-milling prior to adding into CNF. Compared with that of CNF film (1.34 W/(m·K)), the in-plane TC of CNF/BNNS composite (12.68 W/(m·K)) increased significantly by 846 % with loading 30 % BNNS. Afterwards, both toughness (8.0 MJ·m -3 , increased ~250 %) and TC (14.7 W/(m·K), increased ~16 %) of CNF/BNNS composite were further enhanced significantly by mercerization with 12.5 % NaOH solution. The simultaneously improvement of toughness and TC is unprecedented in related studies, which contributes to the effective preparation of thermal management materials., Competing Interests: Declaration of competing interest The authors declare no competing interest., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Cellulose provides promising alternatives to synthetic plastics to achieve a low carbon footprint and biodegradable materials, which have significant positive impacts on environmental protection and on human health. In this work, sulfated holocellulose fibers and sulfated holocellulose nanofibrils (SHCNFs) are prepared using a combination of delignification with derivatization to achieve high fiber yield, superior recycling performance, and less energy consumption of the final products by means of preserving hemicellulose. Derivatization of the surface with sulfate groups provides a further means to avoid excessive aggregation between adjacent cellulose surfaces. Interestingly, hemicellulose increases the accessibility of holocellulose fibers and reduces the embodied energy during sulfate esterification. The presence of hemicellulose imparts high optical transmittance, mechanical performance (ultimate strength, 390 MPa; Young's modulus, 33 GPa), and recyclability for SHCNFs. This combination of two treatments can unlock the greater potential of cellulose as a sustainable material over its entire life cycle., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Enzymatic degradation of plant polysaccharide networks is a complex process that involves disrupting an intimate assembly of cellulose and hemicelluloses in fibrous matrices. To mimic this assembly and to elucidate the efficiency of enzymatic degradation in a rapid way, models with physicochemical equivalence to natural systems are needed. Here, we employ xylan-coated cellulose thin films to monitor the hydrolyzing activity of an endo-1,4-β-xylanase. In situ surface plasmon resonance spectroscopy (SPRS) revealed a decrease in xylan areal mass ranging from 0.01 ± 0.02 to 0.52 ± 0.04 mg·m -2 . The extent of digestion correlates to increasing xylanase concentration. In addition, ex situ determination of released monosaccharides revealed that incubation time was also a significant factor in degradation (P > 0.01). For both experiments, atomic force microscopy confirmed the removal of xylans from the cellulose thin films. We provide a new model platform that offers nanoscale sensitivity for investigating biopolymer interactions and their susceptibility to enzymatic hydrolysis., (Copyright © 2022. Published by Elsevier Ltd.)

Cellulose with distinct colloidal states exhibited different adsorption capability for ions and whether the intake of cellulose would bring positive or negative influence on the mineral bioavailability is inconclusive. This work investigated the binding behavior of carboxymethyl cellulose (CMC), TEMPO-oxidized nanofibrillated/nanocrystalline cellulose (TOCNF/TOCNC), and microcrystalline cellulose (MCC) with Ca 2+ and Zn 2+ and compared their effects on mineral bioavailability in vitro and in vivo. The results suggested that CMC displayed a higher adsorption capability (36.6 mg g -1 for Ca 2+ and 66.2 mg g -1 for Zn 2+ ) than the other types of cellulose because of the strong interaction between carboxyl groups of cellulose and the ions. Although the cellulose derivatives had adverse effects on ion adsorption in vitro, the fermentability endowed by TOCNF/TOCNC counterbalanced the negative impacts in vivo. The findings suggested that the colloidal states of cellulose affected the bioavailability of minerals and could provide useful guidance for applications of specific cellulose., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Nanocellulose has undergone substantial development as a high value-added cellulose product with broad applications. Dried products are advantageous to decrease transportation costs. However, dried nanocellulose has redispersion challenges when rewetting. In this work, drying techniques, factors affecting redispersibility, and strategies improving the nanocellulose redispersibility are comprehensively reviewed. Hydrogen bonds of nanocellulose are unavoidably developed during drying, leading to inferior redispersibility of dried nanocellulose, even hornification. Drying processes of nanocellulose are discussed first. Then, factors affecting redispersibility are discussed. Following that, strategies improving the nanocellulose redispersibility are analyzed and their advantages and disadvantages are highlighted. Surface charge modification and steric hindrance concept are two main pathways to overcome the redispersion challenge, which are mainly carried out by chemical modification, additive incorporation and non-cellulosic component preservation. Despite several advancements having been achieved, new approaches for enhancing the nanocellulose redispersibility are still required to promote the industrial-scale applications of nanocellulose in various domains., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Inspired by acute temperature sensors in the mammalian sensory system to seek comfortable living environment, we construct temperature sensing nanochannels that are tightly linked to photo gating to form photothermal controlled nanochannels membrane. This membrane arises from the composite of laminar regenerated cellulose (RC) membrane formed by dissolution and regeneration of cellulose in the novel superbase-derived ionic liquid and poly-l-lysine (PLL)-modified conical nanochannels polyethylene terephthalate (PET) substrate. Fe 3 O 4 nanoparticles are introduced into RC membrane as gating modifiers, controlling ion flux and osmotic energy conversion. Nanochannels are activated upon photo, inducing temperature changes result in PLL molecule structure shifted from α-helix to β-sheet. The difference in the rectification ratio at different temperatures is associated with photothermal-dependent opening and closing, its maximum is 116.76. This system could deliver an output power of approximately 4.9 W/m 2 in osmotic energy harvesting. Our results suggest a simple photothermal-gating ion transport principle in laminar RC membrane., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Mimicking the cellular machineries-based ion transport phenomenon for multipurpose applications of the nanofluidic devices has inspired scientific community. Owing to this phenomenon, various artificial nanofluidic systems are highly desirable for energy-environment associated fields including energy storage and conversion, biosensing, and desalination of seawater. Nevertheless, high cost and low efficiency hamper the development of nanofluidic devices in the respective fields. Pertinently, cellulose-based nanofluidic devices rectified the ionic transport property and offer an efficient and sustainable platform for harvesting osmotic energy. Recently, the design strategies of cellulose-based nanofluidic materials provided a more targeted material design for specific applications. Herein, we briefly introduce the structural aspects of cellulose, review the structural features and ion transport properties of cellulose-based nanofluidic materials, and highlight their applications as osmotic energy generators, sensors, transistors, flexible electronic skins, and bio-detection devices. In summary, the challenges and future perspectives of cellulose-based nanofluidic materials are described., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Mineral fillers hinder cellulosic fiber bonding and thus limit the increase of filler content in paper. Herein, precipitated calcium carbonate (PCC)/cellulose nanofibrils (CNF) composites were fabricated by a facile and efficient strategy, i.e., co-refining process (CRP). During this process, CNF and PCC were activated by mechanochemical effect and formed encapsulation structure by calcium ion coordination and hydrogen bonding. The encapsulation structure and H-bond/ionic coordination interactions not only endowed the composite with excellent size stability but also enhanced interfacial interaction between composite fillers and cellulosic fibers. Compare with the paper filled with only PCC, PCC + CNF mixture, the tensile index of the cellulosic paper containing PCC/CNF composite was increased by 44.48% and 12.14%, respectively. These results not only provide a facile and scalable approach to increase interaction between cellulosic fiber and mineral filler but also create more possibilities for special paper-based materials with requiring high content of inorganic materials., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Drying-induced hornification is an inevitable phenomenon of cellulosic fibers, which is used to describe internal aggregation structure changes of cellulosic fibers upon drying or water removal. To investigate the hornification process, never-dried cellulosic fibers with different components were thermally dried to different moisture contents. The results indicated that the hornification process could be divided into four stages, including the first crystallization period (>70% moisture), the cocrystallization period (70-31% moisture), the hemicellulose control period (31-11% moisture), and the second crystallization period (11-0% moisture). The decrease of water retention value (WRV) occurred in the cocrystallization period and the second crystallization period, which meant hornification happened in these two periods. Besides, hemicellulose and lignin inhibited hornification by reducing cellulose cocrystallization. The work elucidates the hornification process and mechanism of cellulosic fibers,which will be helpful to control the properties of cellulosic materials for extended utilization., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Herein, a facile strategy was proposed for preparing a high-strength and super-hydrophobic packaging paper with improved moisture and air barrier properties, which was derived from cellulosic pulps, micro-fibrillated cellulose (MFC), and nano-silica (n-SiO 2 ). Owning to the laminated process followed by spraying approach, MFC and n-SiO 2 were assembled onto two surfaces of the cellulose paper base, respectively, endowing the mechanical behaviors and superhydrophobic performance of this biodegradable composite papers as packaging material. The as-obtained multilayered papers demonstrated impressive dry tensile strength and remarkable wet tensile strength of 6542.5 N/m and 5875 N/m, which were increased by 56% and 2277%, respectively. In addition, the multilayered paper with rational mechanical properties possessed low permeabilities of air (3.17 × 10 -3  μm·Pa -1 ·s -1 ), oxygen (9.687 cm 3 ·m -2 ·day -1 ·atm), and water vapor (378.24 g·m -2 ·day -1 ), respectively, as well as a superhydrophobic performance with the contact angle of ~151.2°. Overall, the feasibility of large-scale production of biodegradable packaging materials in the paper-making industry is demonstrated by the fact that the micro/nanostructures and hydrophobic surfaces could be directly constructed on cellulosic paperboard., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Nanocellulose has great potential in the biomedical field due to its biocompatibility, large specific surface area, and customizable surface chemistry. However, due to the bioinert nature and mismatch of the mechanical strength, nanocellulose itself has no cell adhesion ability and cannot directly promote cell growth and reproduction. Recently, surface functionalization of nanocellulose has been reported as an indispensable strategy for improving its bioactivities or other physic-chemical properties. In this paper, functionalization strategies of nanocellulose based on its inherent hydroxyl, aldehyde, carboxyl, and sulfate group reactions are reviewed. Biomacromolecules, such as peptides, proteins, and DNA that are commonly used in functionalization for different biomedical applications are summarized. Prospects and ongoing challenges of nanocellulose-based biomaterials application, as well as these advanced processing technologies such as additive manufacturing, nanomanufacturing, and bio-manufacturing are also discussed. This review is supposed to serve as a guideline for the development of nanocellulose-based biomaterials in biomedical applications., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

An environmental-friendly lipase induced highly hydrophobic NFC film was fabricated through lipase induced dimethyl adipate (DA) esterification followed by silver nanowires (AgNWs) coating for strain sensor application. Due to the lipase activation, the substitution degree (DS NMR ) of 0.18 was achieved, which was three times higher than that of the control sample (without lipase treatment of NFC-DA). As a result, the water contact angle (WCA) of lipase induced adipated-NFC film was reached to 105 ± 3° from 50 ± 2.3° of NFC-DA. In addition, the cellulose structure and performance were well maintained after lipase induced esterification, confirmed by AFM, SEM, TG/DTG, and XRD analysis. After AgNWs coating and annealing, the hydrophobic NFC film-based strain sensor exhibited excellent sensitivity towards human motion, such as finger/wrist movement in real-time, even under wet conditions. Overall, a highly hydrophobic NFC film-based strain sensor was fabricated, which has promising application in wearable devices for human motion monitoring., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

To date, flexible pressure sensors built on silver nanowires (AgNWs) have attracted tremendous attention, owing to their versatile applications in wearable, human-interactive, health-monitoring devices. Cellulose and its derivatives, which show great promise in serving flexible pressure sensors as the desired substrate due to their natural abundance, biocompatibility, easy processibility, and low costs. Herein, we reported a rational strategy to design a silver nanowires-dual-cellulose conductive paper. Its morphology, chemical and crystal structures, thermal stability, mechanical performances, and electrical properties were carefully studied. The results suggested that good tensile properties (tensile strength ≤8.10 MPa), high electrical conductivity (≤ 1.74 × 10 4  S·m -1 ) with long-term stability, and good adhesion stability (bending cycles over 500) were obtained. Furthermore, the use of such conductive paper as substrate for versatile flexible pressure sensors was demonstrated, which exhibited fast response (~ 0.48 s) and high sensitivity, in response to finger motion, voice recognition, and human pulse, etc., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Cellulose conversion into 5-hydroxymethylfurfural (5-HMF) is difficult because of the strong hydrogen bonding existed in cellulose chains. Brønsted/Lewis (B/L) biacidic functionalized ionic liquids (ILs) have great advantages in acid-catalyzed tandem reactions, but the catalytic effect of ILs differs considerably depending on B/L acid ratios. Therefore, this work designed a series of reactions with different proportions of biacidic ILs for the preparation of 5-HMF from cellulose. The tandem reaction is often performed in the presence of a solvent, and the activity of the catalyst is also affected by the solvent. Therefore, in this work, the solvation model density(SMD) model was introduced into the quantum chemical calculation method for molecular design to predict the catalytic effect and explore the catalytic mechanism. The calculation results and experiments jointly showed that [(HSO 3 -P) 2 im]Cl·ZnCl 2 had the highest efficiency, with a 5-HMF yield of 65.66%. This study facilitates the directional optimization design of the catalyst., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Recently, great efforts have been devoted to developing conductive adhesive hydrogels to meet the needs of various applications. However, grand challenges remain in achieving anisotropic hydrogels simultaneously featuring multiple properties using natural polymers and renewable resources. Here, a cellulose-based conductive hydrogel with strong, ultrastretchable, and adhesive properties is prepared via a simple magnetic field-induced strategy. This strategy involves the formation of a suspension mixture with well-oriented cellulose-polydopamine nanocomposites under magnetic fields, followed by rapid orientation via covalent crosslinking. The tensile strength of the oriented hydrogel in longitudinal direction is ~0.22 MPa, which is ~1.4 times higher than that in radial direction. Moreover, the hydrogel shows good cyclic loading-unloading ability, high conductivity (6.9 ± 0.6 S m -1 ), and strong adhesion (71 kPa). The hydrogel also shows significant anisotropic properties and made it a versatile platform for wearable sensors to monitor large and subtle human motion in the foreseeable future., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Ionic conductive hydrogels have been widely applied in sensors, energy storage and soft electronics recently. However, most of the polyvinyl alcohol (PVA) based ionic hydrogels are mainly fabricated by soaking the hydrogels in high concentration electrolyte solution which can induce the waste of electrolyte and solvent. Herein, we have designed cellulose nanofibrils (CNF) and ZnSO 4 reinforced PVA based hydrogels through a one-pot simple freezing-thawing method at low ZnSO 4 concentration without any soaking process. Furthermore, the hydrogel with 0.4% CNF exhibited stress up to 0.79 MPa (242% strain) and high ionic conductivity of 0.32 S m -1 (0.07 M ZnSO 4 ). Moreover, hydrogel sensor displayed high linear gauge factor 1.70 (0-200% strain), excellent stability, durability and reliability. The integrated hydrogel sensor also showed excellent sensor performance for human motion monitoring. This work provides a new prospect for the design of cellulose reinforced conductive hydrogels via a facile method., (Copyright © 2021. Published by Elsevier Ltd.)

In recent years, smart-responsive nanocellulose composite hydrogels have attracted extensive attention due to their unique porous substrate, hydrophilic properties, biocompatibility and stimulus responsiveness. At present, the research on smart response nanocellulose composite hydrogel mainly focuses on the selection of composite materials and the construction of internal chemical bonds. The common composite materials and connection methods used for preparation of smart response nanocellulose composite hydrogels are compared according to the different types of response sources such as temperature, pH and so on. The response mechanisms and the application prospects of different response types of nanocellulose composite hydrogels are summarized, and the transformation of internal ions, functional groups and chemical bonds, as well as the changes in mechanical properties such as modulus and strength are discussed. Finally, the shortcomings and application prospects of nanocellulose smart response composite hydrogels are summarized and prospected., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

We prepared super-hydrophobic nanocellulose films using a non-toxic octadecylamine/polydopamine system. Octadecylamine, a low surface energy material, was used to provide hydrophobic alkyl long chains. Polydopamine was produced by dopamine under alkaline conditions, creating an adhesive substance, which reinforced the hydrophobic long chains and increased the surface roughness of nanocellulose. The effects of reagent concentration, reaction temperature, and reaction time on hydrophobicity were then investigated. The results showed that with a 1:1 mass ratio of nanocellulose to octadecylamine, and reacting at 60 °C for 4 h, the contact angle of the obtained composite membrane reached 168.2°. Scanning electron microscope images revealed that the modified nanocellulose had a smaller particle size and more uniform distribution, which effectively improved the hydrophobicity of the nanocellulose. Thus, the green preparation of superhydrophobic films with high-temperature resistance and wear resistance was realized, which contributed to the high-value utilization of nanocellulose., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

This work demonstrated a facile and sustainable approach to functionalize cellulose nanopaper (CNP) by impregnation of chitosan (CS) and the followed halogenation. It was found that the tensile strength of the functionalized CNP (CNP/CS-Cl) was enhanced by 38.3% and 512.6% at dry and wet conditions, respectively. Meanwhile, the total transmittance (at 550 nm) of CNP/CS-Cl was increased from 75% of pure CNP to 85%, with 35% decrease in optical haze. Moreover, the CNP/CS-Cl exhibited significant enhancement in barrier properties. Importantly, part of the amino groups on CS were transformed into N-halamines during the halogenation process, which endowed the CNP/CS-Cl with excellent antibacterial performance against both S. aureus and E. coli with 100% bacterial reduction after 10 min of contact. Thus, this work provides a simple and efficient approach to functionalize CNP with water resistance, high transparency, excellent antibacterial and barrier properties, which will expand the potential applications of CNP., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

γ-Valerolactone (GVL), a biomass-derived green chemical, offers an environmentally responsible solvent for conversion of lignocellulose to high value-added chemicals. Herein, we report a two-step process for directly producing cellulosic residual, furfural and lignin from Miscanthus × giganteus (M. × giganteus) bypassing the isolation of xylose, which exhibits promising advantage in energy reduction. The optimized pretreatment (100 mM FeCl 3 at 160 °C for 60 min) induced significant xylan removal (98.4%), resulting in rugged fibre surface, thus leading to the peak cellulose conversion of 99.3%. Furfural yield in the second step reached to 76.6% after 100 mM FeCl 3 catalyzed GVL/H 2 O treatment at 180 °C for 10 min without addition of any chemical. The extracted lignin showed representative structure (such as β-O-4', β-β' linkages) and medium molecular weight (4275.5 g/mol). 79.6% of furfural can be recovered by distillation. This study proposes a systematic and energy efficient approach for maximizing biomass utilization., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

In this work, we study interactions of five different hemicellulose models, i.e. Galactoglucomannan, O-Acetyl-Galactoglucomannan, Fuco-Galacto-Xyloglucan, 4-O-Methylglucuronoxylan, and 4-O-Methylglucuronoarabinoxylan, and their respective binding strength to cellulose nanocrystals by molecular dynamics simulations. Glucuronoarabinoxylan showed the highest free energy of binding, whereas Xyloglucan had the lowest interaction energies amongst the five models. We further performed simulated shear tests and concluded that failure mostly happens at the inter-molecular interaction level within the hemicellulose fraction, rather than at the interface with cellulose. The presence of water molecules seems to have a weakening effect on the interactions of hemicellulose and cellulose, taking up the available hydroxyl groups on the surface of the cellulose for hydrogen bonding. We believe that these studies can shed light on better understanding of plant cell walls, as well as providing evidence on variability of the structures of different plant sources for extractions, purification, and operation of biorefineries., (Copyright © 2021 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Ionic conductive hydrogel with multifunctional properties have shown promising application potential in various fields, including electronic skin, wearable devices and sensors. Herein, a highly stretchable (up to 2800% strain), tough, adhesive ionic conductive hydrogel are prepared using cationic nanocellulose (CCNC) to disperse/stabilize graphitic carbon nitride (g-C 3 N 4 ), forming CCNC-g-C 3 N 4 complexes and in situ radical polymerization process. The ionic interactions between CNCC and g-C 3 N 4 acted as sacrificial bonds enabled highly stretchability of the hydrogel. The hydrogel showed high sensitivity (gauge factor≈5.6, 0-1.6% strain), enabling the detection of human body motion, speech and exhalation. Furthermore, the hydrogel based self-powered device can charge 2.2 μF capacitor up to 15 V from human motion. This multifunctional hydrogel presents potential applications in self-powered wearable electronics., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Developing green and simple methods for the preparation of cellulose nanofibrils (CNFs) is of great significance. Herein, a green deep eutectic solvent (DES) system based on choline chloride (ChCl) and citric acid (CA) is employed to pretreat cellulose fibers for the preparation of CNFs. The effect of the pretreatment temperature on the chemo-physical properties of the CNFs is comprehensively investigated. A high CNFs yield of up to 84.19% can be achieved under optimized conditions. The optimal CNFs show a narrow diameter distribution and length up to several microns, high crystallinity and thermal stability, as well as excellent dispersibility in water. Furthermore, semi-transparent and flexible cellulose nanopaper (CNP) was fabricated through a facile vacuum filtration process. The optimal CNP shows high tensile strength (175.15 MPa) and toughness (7.51 MJ/m 3 ). Therefore, this work provides a sustainable and facile approach to fabricate CNFs and CNP, which can be potentially used for various high-tech applications., (Copyright © 2021. Published by Elsevier Ltd.)

Surfaces engineered to identify and enrich glycoproteins are of considerable interest in the diagnostic and detection fields. A boronate affinity (BA) material was proposed as a potential candidate for the isolation of glycoproteins. However, this material has the disadvantages of low efficiency and non-degradability. Herein, a novel dendrimer-amplified BA cellulose foam (PEI-PBA-CF) was fabricated via a mild two-step approach. The as-prepared PEI-PBA-CF exhibited a rapid adsorption equilibrium rate (within 60 min) and outstanding adsorption capacity for horseradish peroxidase (537.4 mg g -1 ) and ovalbumin (495.5 mg g -1 ). Furthermore, competitive adsorption experiments demonstrated that PEI-PBA-CF could achieve selective separation and purification of glycoproteins from complex biological samples due to the synergistic effect of the improved BA capacity by the dendrimer and the well-interconnected porous structure of the biomass matrix. Consequently, these cellulose foams might present new application opportunities in analytical and biomedical fields., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Transparent-wood (TW) is an emerging research topic that can be applied to biobased products. However, it is necessary to fill pores in TW with natural substances to prepare all-biobased TW. This paper reports an all-biobased TW by infiltrating cellulose nanofiber (CNF) and chitosan (CTS) suspensions into the bleached wood. CNF was isolated by combining the chemical and physical methods, and CTS was dissolved in acetic acid, and they were infiltrated into the pores of the bleached Fir veneer wood using a vacuum jar. The CNF and chitosan effects on the mechanical properties of the TW were studied, and the morphologies, crystallinity index, water contact angle, antioxidant, thermal degradation, and UV-shielding properties were investigated. The prepared TW showed 80 % total transmittance and 30-60 % haze, suitable for solar cell application. The all-biobased TW showed good thermal stability up to 315 °C and excellent UV shielding property for UV-B and UV-C. The antioxidant property of the CTS-TW significantly increased as compared to the original wood. The CNF-TW showed considerable tensile strength and yield strength of more than 200 % improved from the original wood. The potential for environment-friendly packaging applications was demonstrated by making a bag, medicine packaging, and straw for a drink., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

It is still a challenge to integrate high sensitivity, mechanical adaptability, and self-powered properties for hydrogels. Herein, we report a conductive polyvinyl alcohol (PVA) hydrogel based on natural nanoclay and cellulose nanofibrils (CNFs). The CNFs and PVA chains could construct a double network structure, resulting in a high mechanical composite hydrogel. Meanwhile, the nanoclay could be well dispersed and immobilized in the network of the hydrogel, thus improving mechanical adaptability of the hydrogel for curved and dynamic surfaces. Moreover, the conductive ions (Al 3+ ) imparted the hydrogel with high conductivity (6.67 S m -1 ) and gauge factor (1.17). Therefore, the composite hydrogel exhibited high sensitivity to tiny pressure changes, enabling recognition of the complicated sounding and handwriting. More importantly, the composite hydrogel possessed self-powered property, which could generate an output voltage of up to 78 mV. In summary, the multi-functional composite hydrogel may have giant applications in artificial electronic skins or wearable devices., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The existence of hydroxyl and carboxyl groups makes the photothermal stability of cellulose nanofibers (CNFs) poor and thus limits its scale application. This problem could be solved by doping layered double hydroxides (LDHs) nanopowders with opposite charge on the surface of CNFs. This work mainly focused on investigation of the influence of the crystal morphology of the inorganic ultraviolet shielding agent (i.e. ZnAl-LDHs) on the thermal stability of CNFs/ZnAl-LDHs composited films. The results showed that the morphology of LDHs was positively correlated with the photothermal stability of CNFs-based films. Specially, the ZnAl-LDHs with uniform crystal morphology could be prepared by controlling the molar ratio of Zn/Al at 3:1 and thus enhance the photothermal stability of CNFs-based films without any serious light transmittance deteriorating after doping. This work provided a practical and effective way for preparation of photothermal-stable CNFs-based transparent films for industrial application in the fields of photonics and electronics., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Flexible electronics products have attracted wide attention because of their excellent flexibility, conductivity and stability. In this study, the liquid phase reduction method was used to in situ reduce fractal-structured silver particles (FSSPs) on cellulose surface to prepare conductive paper with excellent conductivity, and good stability and flexibility. The experimental results show that when the mass ratio of silver to cellulose was 1.5:1, the sheet resistance of conductive paper is as low as 0.02 Ω·sq -1 , and the conductivity reaches 1041.33 S cm -1 , which shows excellent conductivity. In order to expand the application of conductive paper in the field of flexible wearable electronic products, the mechanical stability and oxidation resistance of conductive paper were tested. The results show that the conductive paper has good stability and is expected to replace the flexible electronics products made of plastic., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

A novel approach was introduced to prepare very low density, highly porous, economic, reusable, hydrophobic, and magnetic cellulose aerogels from hardwood dissolving pulp via a simple freeze-drying procedure. The aerogels showed outstanding adsorption efficiency for several oils and organic solvents and demonstrated excellent selectivity for absorbing oil from an oil/water mixture. Moreover, they were easily collected by an external magnet, indicating excellent recyclability and reusable for at least 10 cycles while still retaining supreme adsorption capacity (up to 181 g/g for silicone oil). This study proposes an economic and novel method for the large-scale preparation of hydrophobic and magnetic cellulose aerogels, making them a promising candidate for the efficient and sustainable cleaning of oils and chemical spills., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

High-value utilization of cellulosic biomasses via the most promising enzymatic method is the key to solve a series of global strategic issues but its industrialization was seriously hindered by the high cost. Immobilization of enzyme to realize its recycling is one solution; however, how to capture and hydrolyze the insoluble cellulose effectively via the immobilization system remains challenging. Herein, inspired by the predation process of the sea anemone, a cost-effective biomimetic cellulase-loaded enzymatic film was constructed. The cellulase loaded on the film can adjust its spatial orientation freely, thus their catalytic centres can easily reach the surface of the cellulose to perform the "predation" process effectively. As a result, this immobilization system can largely increase the efficiency of the insoluble cellulose hydrolysis and can be recycled for at least 8 cycles without activities loss. Therefore, it can largely reduce the cost of the cellulose conversion in the industrial areas., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

A high-performance flexible conductive substrate is one of the key components for developing promising wearable devices. Concerning this, a sustainable, flexible, transparent, and conductive cellulose/ZnO/AZO (CZA) film was developed in this study. The cellulose was used as the transparent substrate. The added AZO was as the conductive layer and ZnO functioned as an interface buffer layer. Results showed that the interface buffer layer of ZnO effectively alleviated the intrinsic incompatibility of organic cellulose and inorganic AZO, resulting in the improvement of the performance of CZA film. In compared with the controlled cellulose/AZO (CA) film with 365 Ω/sq sheet resistance and 87% transmittance, this CZA film featured a low conductive sheet resistance of 115 Ω/sq and high transmittance of 89%, as well as low roughness of 1.85 nm Moreover, the existence of conducive ZnO buffer layer enabled the conductivity of CZA film to be stable under the bending treatment. Herein, a flexible electronic device was successfully prepared with the biomass materials, which would be available by a roll-to-roll production process., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

To date, the production of bacterial nanocellulose (BNC) by standard methods has been well known, while the use of low-cost feedstock as an alternative medium still needs to be explored for BNC commercialization. This study explores the prospect for the use of the different aqueous extract of fruit peel wastes (aE-FPW) as a nutrient and carbon source for the production of BNC. Herein, this objective was accomplished by the use of a novel, high- yielding strain, isolated from rotten apple and further identified as Komagataeibacter xylinus IITR DKH20 using 16 s rRNA sequencing analysis. The physicochemical properties of BNC matrix collected from the various aE-FPW mediums were similar or advanced to those collected with the HS medium. Statistical optimization of BNC based on Central Composite Design was performed to study the effect of significant parameters and the results demonstrated that the BNC yield (11.44 g L -1 ) was increased by 4.5 fold after optimization., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

This study introduces a new combined method of wood impregnation and chemical pulping processes leading to the production of superparamagnetic cellulose fibers with a magnetic nanoparticle-free outer surface. First, magnetic wood chips (MWCs) were prepared by in situ synthesizing of magnetite (Fe 3 O 4 ) nanoparticles during the wood impregnation process. The MWCs were then converted into magnetic fibers by kraft pulping. The results showed that the resulting magnetic fibers had an outer surface comparable to that of non-magnetic fibers while showing superparamagnetic behavior. The XRD results confirmed that the in situ synthesized magnetic nanoparticles were magnetite. Papers made from the new type of magnetic cellulose fibers had much more desirable tensile properties, appearance, and printability than papers made from conventional magnetic cellulose fibers, comparable to those made from non-magnetic fibers., (Copyright © 2020. Published by Elsevier Ltd.)

In this paper, we have isolated cellulose nanocrystallines (CNCs) with different morphologies by enzymatic hydrolysis, and prepared flexible and transparent nanocomposite films with PVA matrix via solution casting. By means of SEM, UV-vis, XRD, DTG, FT-IR and mechanical methods, the effects of rod-shaped cellulose nanocrystallines (RCNCs) and spherical cellulose nanocrystallines (SCNCs) on PVA nanocomposite films were compared systematically. The results showed CNCs with different morphologies had little effect on the transparency of the composite films, and the crystallinity fluctuated with the change of CNCs additive amount. Compared with the RCNCs, SCNCs had a better improve ability to the thermal stability of the composite films by promoting pyrolysis temperature 60-80 °C. On the contrary, the maximum mechanical properties of the composite films of RCNCs were much higher than those of SCNCs, and the Young's modulus of the PVA/RCNCs composite film were increased by 120.97 % in comparison with the pure PVA., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

The asymmetric wetting membranes have attracted intense attention in liquid directional transportation. However, it is a huge challenge to prepare surface layer membrane for sanitary products with antibacterial and asymmetric wettability by a simple method. Herein, the bacterial cellulose grafted with chitosan (BC-CS) was used as the hydrophilic agent to modify polypropylene nonwoven fabric (PPF) substrate via easy and effective one-sided layer-by-layer spraying to prepare the asymmetric wetting and antibacterial composite membrane (BC-CS/PPF). It showed that the BC-CS/PPF had good physical properties, which was attributed to the strong and uniform physical combination between nano-sized BC-CS and PPF. The sanitary products with BC-CS/PPF surface layer, denoted as BC-CS/PPF sanitary products, also had good absorption and anti-return property. The antibacterial test revealed that BC-CS had an excellent performance against S. aureus and E. coli in the simulated application environment. Moreover, the antibacterial performance was better than that of commercial sanitary products., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

This study aims to investigate the relationship between lignin content, morphology, and rheology of lignin containing cellulose nanofibers (LCNFs). The morphology and rheology of LCNFs were dominated by lignin content. Lignin content had two-sides on mechanical fibrillation. At high lignin content (23.79 %), reduced efficiency of defibrillation resulted in large LCNFs connecting with lignin patches. LCNF suspensions exhibited low viscosity, weak gel behavior due to infirm fibril network. Small yield stress of 1.14 Pa suggested that fibril network was easily disrupted. At residual lignin of 6.52 %, fibril bundles were sensitive to defibrillation, producing long and flexible LCNFs with high capacity of entanglement. The entangled fibril network had high viscosity and strong gel like behavior. Creep compliance of 0.09 Pa -1 and large yield stress of 4.25 Pa indicated excellent resistance to deformation. The desired rheology can be tailored by lignin content, providing practical guidance on novel rheology-dependent LCNF based materials., (Copyright © 2020 Elsevier Ltd. All rights reserved.)