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1. An efficient synthesis of optically active trifluoromethyl aldimines via asymmetric biomimetic transamination.

Author

Liu, Mao, Li, Jing, Xiao, Xiao, Xie, Ying, and Shi, Yian

Subjects
TRIFLUOROMETHYL compounds synthesis, ALDIMINES, AMINATION, BIOMIMETIC chemicals, FUNCTIONAL groups
Abstract

This communication describes a chiral base-catalyzed asymmetric [1,3]-proton shift of trifluoromethyl ketimines, giving a wide variety of trifluoromethyl aldimines containing various functional groups with up to 94% ee. [ABSTRACT FROM AUTHOR]

Published
2013
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