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Start Over Author "Miao Du" Topic polymers Journal chemical communications
1 results on '"Miao Du"'

1. Controllable preparation of ZnII coordination polymers: unusual solvothermal formation of a LiGe-type framework directed by in situ S–S coupling of 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol.

Author

Xu-Dong Chen, Hui-Fang Wu, and Miao Du

Subjects
POLYMERS, LIGANDS (Chemistry), THIOLS, ORGANOSULFUR compounds
Abstract

Controlled assembly of ZnII with a versatile ligand 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol (Hptt) in conventional or solvothermal condition affords two distinct coordination frameworks, in which the former shows a unique 3-D pseudo-polyrotaxane architecture with 1-D water tapes penetrating the 2-D Zn–ptt layers, whereas the later is generated from in situ S–S coupling of Hptt and has a very rare 2-fold interpenetrating LiGe (lig) topology. [ABSTRACT FROM AUTHOR]

Published
2008
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