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Start Over Author "Su, Junyi" Journal chemistry - an asian journal
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2. Iodine‐promoted Intermolecular Dehydrogenation Diamination: Synthesis of Unsymmetrical α,β‐Diamido Ketones.

Author

Zhang, YongJian, Su, Junyi, Niu, Wenjie, and Li, Yujin

Subjects
*KETONES, *DEHYDROGENATION, *SECONDARY amines, *HYPERVALENCE (Theoretical chemistry), *ORGANIC synthesis
Abstract

Iodine‐promoted direct diamination of α,β‐unsaturated ketone to form two C−N bonds has been developed starting from chalcone and secondary amine. This reaction was performed in THF at 50 °C in the presence of I2 and K2CO3. The protocol is metal‐free, operationally simple and carried out under mild conditions, providing an effective new way for directing diamination reactions. [ABSTRACT FROM AUTHOR]

Published
2019
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