Search

Your search keyword '"*ELECTRONIC spectra"' showing total 2 results
Start Over Descriptor "*ELECTRONIC spectra" Topic complex compounds Topic phosphorescence Journal inorganic chemistry communications
2 results on '"*ELECTRONIC spectra"'

1. Can silver exert a heavy-atom effect in organic ligands? Intraligand phosphorescence of Ag(binap)NO3 with binap=2,2′-bis (diphenylphosphino)-1,1′-binaphthyl under ambient conditions

Author

Kunkely, Horst and Vogler, Arnd

Subjects
*PHOSPHORUS compounds, *SILVER, *SPECTRUM analysis, *COMPLEX compounds
Abstract

Abstract: The solid compound Ag(binap)NO3 with binap=2,2′-bis(diphenylphosphino)-1,1′-binaphthyl shows an IL phosphorescence at λ max =510nm under ambient conditions. The silver–phosphine bonding is sufficiently covalent to transmit the heavy-atom effect of silver to the binaphthyl chromophore. [Copyright &y& Elsevier]

Published
2006
Full Text
View/download PDF

2. Photoluminescence of PtII(cyclooctatetraene)(CN)2 originating from a MLCT triplet

Author

Kunkely, Horst and Vogler, Arnd

Subjects
*PHOTOLUMINESCENCE, *COMPLEX compounds, *SPECTRUM analysis, *MATHEMATICAL transformations
Abstract

Abstract: The complex PtII(cyclooctatetraene)(CN)2 shows a longest-wavelength absorption (λ max =430nm) which is assigned to a (PtII →π∗ C8H8) MLCT transition. At r.t. the solid complex displays an intense orange emission at 572nm which originates from the MLCT triplet. The emission spectrum exhibits a vibrational structure which may indicate an IL contribution. [Copyright &y& Elsevier]

Published
2006
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results