1. Li+ intercalcation pseudocapacitance in Sn-based metal-organic framework for high capacity and ultra-stable Li ion storage
- Author
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Shu-Biao Xia, Li-Feng Yao, Fei-Xiang Cheng, Hong Guo, Jian-Jun Liu, Jiaming Liu, and Xiang Shen
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,Energy Engineering and Power Technology ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Lithium-ion battery ,Pseudocapacitance ,0104 chemical sciences ,Anode ,Electronegativity ,Chemical engineering ,X-ray photoelectron spectroscopy ,chemistry ,Electrode ,Metal-organic framework ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,0210 nano-technology ,Tin - Abstract
Tin (Sn)-based materials are potential alternatives to the commercial graphite anode for next-generation Li-ion batteries (LIBs) due to their high theoretical capacity. However, the poor cyclic stability, originating from the large volumetric changes during charge/discharge process, hinder their practical utilization. Herein, we have successfully prepared a Sn-based metal-organic framework (MOF, Sn-PMA), and explored as potential anode materials in LIBs. Benefiting from its layered structure and efficient electron transport channels, Sn-PMA electrodes deliver a high initial capacity of 1567 mAh g−1, at 100 mA g−1, and maintained a reversible capacity of 707 mAh g−1, at 800 mA g−1, after 400 cycles. Furthermore, the detailed post-electrochemical structural, morphological and compositional analysis is carried out to unveil the structural changes and Li-ion storage mechanism of electrodes. Ex-situ XRD and XPS results revealed that, in Sn-PMA electrode, O atom, coordinated to the Sn atom, exhibited higher electronegativity, served as major Li-ion storage site and rendered excellent cyclic stability due to a stable structure. Kinetic analyses reveal that the excellent performance of the Sn-PMA is typical attributed to the pseudocapacitive contribution induced by the special porous structure.
- Published
- 2019