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Start Over Descriptor "Monomers -- Properties" Journal journal of the american chemical society
1 results on '"Monomers -- Properties"'

1. Rationalization of anomalous nonlinear effects in the alkylation of substituted benzaldehydes

Author

Buono, Frederic, Walsh, Patrick J., and Blackmond, Donna G.

Subjects
Monomers -- Properties, Benzene -- Chemical properties, Alkylation -- Causes of, Chemistry
Abstract

The reactions of benzaldehydes with electron-donating substituents on the aromic ring exhibited a more significant nonlinear effect in these reactions than the electron-withdrawing substituents. The modification of Noyori model rationalizes the apparently anomalous results that were observed through a simple extension of the Noyori model to allow for nonthermodynamically controlled monomer/dimer partitioning.

Published
2002

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