1. Porphyrin based-optical fiber sensor for pattern recognition of chlorides and nitrates.
- Author
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Yadav, Mukti, Kundu, Kaustubh, Kaler, R.S., and Kundu, T.
- Subjects
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PATTERN recognition systems , *CHLORIDE ions , *OPTICAL fiber detectors , *MACHINE learning , *PORPHYRINS , *NITRATES , *OPTICAL pattern recognition , *PHOTONIC crystal fibers - Abstract
• Novel Photonic Device Development : The paper introduces a groundbreaking approach to create a photonic device for chemical applications, utilizing an evanescent wave absorption technique-based optical fiber probe. • Free-base Porphyrin Monolayering: The sensing probe incorporates a Tetraamine porphyrin (TAPP) monolayer, exploiting the unique optical properties of TAPP to enhance chemical sensing capabilities through the optical fiber. • Distinct Optical Patterns: The study focuses on monitoring interactions between TAPP and nitrate and chloride ions in the solution phase, emphasizing on absorption spectra variations of porphyrin molecules significantly in Soret and Q-bands. Distinct optical patterns emerge from the interaction, and the paper thoroughly analyses ion-dependent shifts in both the bands across eight samples of nitrates and chlorides. • Spectral Pattern Recognition: It employs unsupervised learning algorithms for spectral pattern recognition, allowing the discernment of ion groups based on their unique optical signatures. The use of PCA and Dtrend techniques helps to extract significant data to cluster different compounds. The sensor probe however exhibits remarkable sensitivity to nitrate and chloride ions, showcasing an impressive rapid response time of 2-3 s. • Practical Implications: The findings highlight the potential practical applications of the developed photonic device, emphasizing its utility in environmental monitoring and chemical analysis. The study positions porphyrin-based optical fiber sensor as a valuable technology, demonstrating their efficacy in detecting and analysing chemical compounds, particularly nitrate and chloride ions. The paper introduces a novel approach to develop a photonic device for chemical applications using an evanescent wave absorption technique-based optical fiber probe layered with a Tetraamine porphyrin (TAPP) monolayer exploiting the optical properties of TAPP. The interactions between the TAPP and nitrate and chloride ions in the solution phase were monitored and the changes in the absorption spectra of TAPP molecules were recorded. Distinct optical patterns emerge, and ion-dependent shifts in the Soret and Q-bands are analyzed for eight samples of nitrates and chlorides. Principal Component Analysis (PCA) is employed to discern ion groups based on the spectral pattern recognition. These fiber probes exhibit sensitivity to nitrate and chloride ions, with enhanced selectivity, robustness, and a rapid response time of 2–3 seconds. The study demonstrates the emergence of porphyrin-based optical fiber sensors as a useful sensor technology in environmental monitoring. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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