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1. Amine-Induced Decomposition of Perfluoroalkanesulfonyl Fluorides

Author

Helmut Vorbrüggen, Ulrich Klar, and B. Bennua‐Skalmowski

Subjects
Chemistry, Organic Chemistry, Polymer chemistry, Fluorine, chemistry.chemical_element, Organic chemistry, Amine gas treating, Decomposition, Catalysis, Adduct
Abstract

Perfluoroalkanesulfonyl fluorides (C n F 2n+1 SO 2 F) decompose slowly even at -20 °C in the presence of tertiary heteroaromatic or aliphatic amines to form the corresponding perfluorinated alkanes (C n F 2n+2 ) and amine-sulfur dioxide adducts.

Published
2008
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