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We propose a spatial equilibrium problem for a pulp and paper supply chain network under the Emission Trading System (ETS) and the circular economy principles. The developed closed-loop supply chain model, based on the variational inequality theory, accounts for the forest deployment and the production of paper using both virgin pulp and recyclable paper waste in an area that is subject to the ETS. In addition, it considers the exchanges of virgin pulp, paper, recyclable and not-recyclable paper waste between this regulated area and geographical zones where no environmental policies apply. The aim of this paper is to investigate the ETS impacts on the pulp and paper industries located in an environmentally regulated area in terms of operating costs, production and trading volumes of the aforementioned commodities, and emissions generated. The case study focuses on the European pulp and paper companies, which are among the energy-intensive industries deemed to be exposed to the carbon leakage risk as a consequence of the ETS application. Sensitivity analyses on the carbon price value and on the trade flexibility are conducted. Our results show that the ETS implies additional costs for the European pulp and paper companies and induces them to resort more on imports of virgin pulp and paper from not-regulated zones. [ABSTRACT FROM AUTHOR]

An ultra-sensitive paper-based sensor for the rapid and specific detection of apigenin in Scutellaria barbata D. Don was developed. The construction process of the proposed apigenin sensor was to grow ZIF-8 in situ with MXene as a template on carbon paper (CP) electrode. The MXene with excellent conductivity and ZIF-8 with porous structure showed synergistic effect in promoting electron transfer and increasing the number of binding sites, thus providing a highly sensitive detection for apigenin. Under optimal conditions, the sensor showed an excellent linear relationship in the range of 0.01 to 10 µM, with a detection limit of 2.6 nM. This study not only constructed a new sensing platform for sensitive detection of apigenin, but also provided a new method for the detection of apigenin in Scutellaria barbata D. Don, which was of great significance for promoting the construction of an electrochemical sensor for apigenin. [ABSTRACT FROM AUTHOR]

Baicalin (Bn) is one of the flavonoids with various biological activities, and its accurate determination is of great significance to clinical medicine. The new "MOF-on-MOF" materials have a broad application prospect. ZIF-67 and MIL-101(Fe) are typical metal–organic frame (MOF) materials, which have the advantages of flexible structure, large specific surface area, large porosity, and adjustable pore size. In this paper, a disposable and sensitive Bn electrochemical sensor based on ZIF-67/MIL-101(Fe) composite modified carbon paper (CP) electrode was developed for the first time. The sensing nanomaterials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction spectroscopy (XRD), and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) was used to evaluate the electrochemical behavior of Bn on different modified electrodes. The results showed that ZIF-67/MIL-101(Fe)/CP exhibited a well-defined redox peak compared with bare CP, ZIF-67/CP, and MIL-101(Fe)/CP, which was attributed to the synergistic effect of ZIF-67 and MIL-101(Fe). Under optimal conditions, the electrochemical sensor was able to quantify Bn in the ranges of 0.01 ~ 3 µM and 3 ~ 6 µM with a detection limit (LOD) as low as 0.009 µM (S/N = 3). In addition, the sensor was successfully used for the quantitative analysis of Bn in Dual yellow oral liquid with reliable results. [ABSTRACT FROM AUTHOR]

Saccharification of cellulosic material is crucial before utilizing it as the feedstock of fermentation processes. This study focuses on developing of robust catalysts for enzymatic hydrolysis of paper waste. Cellulase enzyme was immobilized on Fe3O4 magnetic nanoparticles (MNPs) via multi-covalent bonds. Therefore, the attachments of MNPs were performed by three approaches (3-aminopropyl)triethoxysilane (APTES) (Method I), polyethyleneimine (PEI) (Method II), and both monolayer molybdenum disulfide and PEI (MoS2-PEI) (Method III). The biocatalysts were characterized using Fourier transform infrared (FTIR) and thermogravimetric analysis (TGA). The immobilization yield and loading efficiency of cellulase were determined at 38.65% and 162 mg g−1 in Method I, 13.33% and 31 mg g−1 in Method II, and 14.38% and 33 mg g−1 in Method III. The specification of the biocatalysts was determined for the hydrolysis of filter paper, carboxymethylcellulose (CMC), microcrystalline cellulose, and cellobiose. The total cellulase activity was 2.77, 0.943, 1.38, and 2.02 µmolGlucose mgEnzyme−1 h−1for free-cellulase and the immobilized biocatalysts prepared by Method I, II, and III, respectively. The prepared biocatalyst in Method I maintained 54.54% of its original activity after five cycles, which was more robust than Method II (20.25%) and Method III (12.33%). Further studies were performed on the saccharification of paper waste. The results showed the biocatalyst obtained by Method II resulted in 5.8 folds of higher glucose than the free-cellulase. The highest glucose recovery of about 72.47% was achieved after 48 h using the immobilized biocatalyst prepared by Method II. [ABSTRACT FROM AUTHOR]

In the present era of agricultural digitalization, documenting on-farm operations is critical. These records contextualize other layers of data and underpin economic analysis and informed decision-making. On-farm recordkeeping is rooted in an ancient tradition and has evolved from pen and paper to digital means integrating diverse tools and methods. These tools vary widely in mode of data recording and this presents challenges in achieving complete, accurate and interoperable data. Assessing this diversity of existing recordkeeping systems is a key step toward the improvement in recordkeeping systems that enhance data quality and interoperability. Despite the importance, as of present, comprehensive studies addressing this challenge are lacking. A systematic review of existing on-farm recordkeeping systems was carried out to address their advantages and weaknesses and to analyze their features and traits, focusing on interoperability and adherence to efficient and comprehensive on-farm recordkeeping. Paper-based recordkeeping, a longstanding and reliable method, is gradually being replaced by digital platforms. Many universities and agencies have released farm management spreadsheets and interactive database forms representing the initial step toward intuitive recordkeeping. Furthermore, farm management software, web apps, and user-friendly smartphone apps are increasingly crucial for handling agricultural big data. Notably, among the surveyed software packages and apps, most of them are not free and only a few support data interoperability. The survey also indicates a scope for further development in open-source tools with automation in recordkeeping. Adopting digital on-farm recordkeeping tools can positively impact both on and off the farm, fostering data interoperability, controlled yet flexible data access, completeness, and appropriate accuracy. [ABSTRACT FROM AUTHOR]

Purpose: Excessive paper dust during paper production may harm the workers' respiratory health. We wanted to assess the inhalable paper dust levels and its determinants among paper industry workers. Methods: A study was conducted in Ethiopia to assess the level of personal inhalable paper dust exposure among four paper mills. A total of 150 samples were collected using the IOM sampler attached to Side Kick Casella pumps at a flow rate of 2 L/min. The samples were analyzed in Nemko Norlab, Norway. Linear mixed-effect models were applied to identify determinants of inhalable paper dust. Results: The geometric mean of personal inhalable paper dust was 3.3 mg/m3 with 80% of the measurements exceeding the Swedish occupational exposure limit (OEL) of 2 mg/m3. The linear mixed-effects model showed that the level of dust was 28% higher when using high-speed than when using low-speed rewinding machines, while paper mills with an average of more than four machines per job group had 22% higher exposure than paper mills with a lower number of machines. Furthermore, working in packing and preparation was associated with higher dust exposure than in other areas. Conclusions: The dust exposure levels were above the Swedish OEL for 80% of the samples. This indicates that preventive measures should be established in the industry. The exposure model identified high-speed rewinding machines, a high number of machines, and work in preparation and packing as associated with high levels of paper dust exposure. [ABSTRACT FROM AUTHOR]

An inexpensive, easy-to-use, simple, and non-toxic freshness indicator was developed based on anthocyanins from saffron petal waste material and filter paper to show the quality and shelf life of trout fillets. Previous studies considered the color changes of freshness indicators based on anthocyanins during fish spoilage due to pH changes following the production of volatile nitrogen. However, in this study, we showed that not only volatile nitrogen but also hydrogen sulfide (H2S) gas produced during fish spoilage caused structural and color changes in anthocyanins. The indicator showed a wide range of naked-eye color changes from purple to light blue over a pH of 2–11 and from purple to yellow over different concentrations of H2S gas compounds. The prepared indicator had good color stability and was not affected by various temperatures and times. pH, total volatile basic nitrogen, total viable count of trout fillets, and the color changes of the prepared indicators were simultaneously determined during 8 days of storage in the refrigerator. A significant correlation was observed between fish quality and visible color changes of the indicator. The sensitivity of saffron petal anthocyanins to volatile nitrogen and H2S compounds showed that it could be used as a raw material for producing low-cost and efficient colorimetric indicators for spoilage detection of protein-rich foods. [ABSTRACT FROM AUTHOR]

Paper sludge (PS) from paper mills has a significant potential for bioethanol production. In this study, waste-paper-containing PS is used as the raw material for bioethanol production because the annual waste paper utilization rate has increased globally. Although PS does not require delignification, the antiseptics and deinking agents in waste paper-containing PS inhibit enzymatic reactions such as saccharification and fermentation. Their removal is important, but it has not yet been reported. Using subcritical water pretreatment, the selective decomposition of enzyme inhibitors in PS is examined without the generation of other enzyme inhibitors. The optimum pretreatment conditions are identified as 240 °C, 3.3 MPa, 3 min, and pH 4.5. Glucose was obtained in 71% yield from pretreated 5 wt% PS using cellulase, which is 5.5 times higher than that from unpretreated PS. This is because the reactivity of the pretreated PS increases with increasing surface area of the cellulose fibers, and the cellulase inhibitors are decomposed by subcritical water. Next, semi-simultaneous saccharification and fermentation treatments are performed to produce bioethanol from waste-paper-containing PS. The bioethanol yield based on cellulose after 96 h is 68% for PS pretreated with subcritical water, whereas the bioethanol yield is 6% for unpretreated PS. Therefore, subcritical water pretreatment increases the bioethanol yield by 11 times. The proposed method may enable the use of large amounts of PS as ethanol feedstock in future. [ABSTRACT FROM AUTHOR]

Treatment of cryptococcal meningitis relies primarily on flucytosine (5FC), which is also used to treat candidiasis and infections caused by Cryptococcus neoformans. High dosages of this drug, despite its therapeutic properties, may cause hazardous side effects such as bone marrow suppression, hepatotoxicity, and gastrointestinal toxicity. The detection of trace amounts of 5FC medication may aid in tracking the treatment's efficacy and mitigating unwanted effects. Surface-enhanced Raman spectroscopy (SERS) is a rapid, reliable, and precise approach for detecting extremely low amounts of biological and chemical compounds. A filter paper-based SERS biosensor coated with silver nanoparticles (AgNPs) were employed to detect the 5FC drug. The AgNPs fabricated via the chemical reduction method were characterized by FE-SEM, TEM, XRD, AFM, and UV-Vis spectroscopy. Plasmonic active sites were made by coating the filter paper substrate with AgNPs to detect the 5FC drug's molecular vibrations. As the 5FC drug was coated onto the filter paper substrate, the AgNPs interacted with it, allowing for the detection of very low concentrations of the drug. The SERS filter paper substrate could detect concentrations of 5FC as low as 10−10 M. The Raman spectra and peak signals obtained experimentally were also simulated and validated using the density functional theory (DFT) approach. Six sets of measurements were taken, and the average RSD was obtained to be 4.62%. The experimentally measured enhancement factor for recognizing molecular vibrations of the 5FC was 9.065 × 107, and it was numerically estimated as 10.044 × 107. Therefore, the fabricated SERS-based filter paper substrate is useful for drug monitoring since they can detect even trace amounts of the targeted drug. [ABSTRACT FROM AUTHOR]

Paper sludge consists mainly of wet short cellulose fibers that are lost during papermaking and of residual chemicals used in the manufacturing process that remain dissolved in the water. Each ton of paper generates about 40–50 kg of dry sludge, of which 70% is primary sludge. Paper production, which exceeded 400 million tons globally in 2020, generates vast volumes of solid waste. Primary sludge is usually fiber-rich and hence suitable to be recycled back into the papermaking process. However, if the sludge is to be disposed of in landfills, sustainable practices must be developed in order to recover the fibers as they are valuable source for manufacturing high value-added products. This study investigates the valorization of paper sludge discarded by a filter paper manufacturer, with the purpose of producing cellulose acetate films for food packaging. The process involves recovering cellulose fibers from the sludge, purifying them and through acetylation reaction produce cellulose acetate films. FTIR spectra confirmed successful acetylation of fibers and also that acetyl groups reduced the hydrophilicity of cellulose—the contact angle was increased to over 80° from 50° in native cellulose. The films exhibited very good water barrier properties at both 50% and 90% relative humidity (RH). [ABSTRACT FROM AUTHOR]

Sensitizers are used to prepare photosensitive materials for ink-printing and thermal-recording media. Typical sensitizers contain an aromatic ring and exhibit aryl hydrocarbon receptor-mediated activity. They can accumulate in aquatic biota, leading to the disruption of ecosystems. Effluent from paper recycling plants has been identified as a source of contamination, and the presence of sensitizers in toilet paper may represent a new source of contamination in aquatic environments. To examine possible sources of contamination by sensitizers, this study investigated the levels of sensitizers in recycled toilet paper. We also studied the prevalence of sensitizers in rivers receiving effluents from sewage treatment plants in Japan, from 2020 to 2022. We detected eight sensitizers and related compounds in both toilet paper and river water samples; their total concentrations ranged from 0.78 to 34 µg/g (mean: 12 µg/g) in toilet paper and 58–1167 µg/L (median: 77 µg/L) in water. In the water samples, sensitizers were partitioned between liquid and suspended solid phases, and in suspended solids, sensitizers accounted for an average of 42% of the total. Correlation analysis showed a high correlation between sensitizer composition in the water from a river receiving sewage treatment plant effluents and toilet paper. Since these compounds were also detected in the river water analyzed in this study, toilet paper should be considered a novel source of sensitizers contamination in sewage treatment systems. [ABSTRACT FROM AUTHOR]

Honesty of publications is fundamental in science. Unfortunately, science has an increasing fake paper problem with multiple cases having surfaced in recent years, even in renowned journals. There are companies, the so-called paper mills, which professionally fake research data and papers. However, there is no easy way to systematically identify these papers. Here, we show that scanning for exchanged authors in resubmissions is a simple approach to detect potential fake papers. We investigated 2056 withdrawn or rejected submissions to Naunyn–Schmiedeberg's Archives of Pharmacology (NSAP), 952 of which were subsequently published in other journals. In six cases, the stated authors of the final publications differed by more than two thirds from those named in the submission to NSAP. In four cases, they differed completely. Our results reveal that paper mills take advantage of the fact that journals are unaware of submissions to other journals. Consequently, papers can be submitted multiple times (even simultaneously), and authors can be replaced if they withdraw from their purchased authorship. We suggest that publishers collaborate with each other by sharing titles, authors, and abstracts of their submissions. Doing so would allow the detection of suspicious changes in the authorship of submitted and already published papers. Independently of such collaboration across publishers, every scientific journal can make an important contribution to the integrity of the scientific record by analyzing its own pool of withdrawn and rejected papers versus published papers according to the simple algorithm proposed in the present paper. [ABSTRACT FROM AUTHOR]

Innovative and cost-effective paper sheets with superior fire safety and reinforcement properties have been developed. The paper sheets were fabricated via valorization of agricultural waste to paper and then coated with nanoparticles. Paper attained from rice straw was used to create the sheets. Afterward, bentonite sheets were incorporated in these sheets, and finally, PbO nanoparticles were coated on prepared paper nanocomposites. The mass ratio of bentonite sheets was altered. The flammability and mechanical properties of the developed paper nanocomposites were studied. The flame retardancy of developed paper nanocomposite was significantly improved achieving LOI value of 24% compared to 20% for bentonite and PbO nanoparticle-free sample. Additionally, the tensile strength was improved recording 44% enhancement compared to unmodified sample. Furthermore, the flame retardancy mechanism was proposed and studied. [ABSTRACT FROM AUTHOR]

A highly sensitive sensor based on carbon fiber paper modified with a shungite–copper formazanate composite is presented for the voltammetric determination of lidocaine. The synthesized organometallic complex, composite, and modified electrode are characterized by infrared spectroscopy, high-resolution mass spectrometry, elemental analysis, scanning electron microscopy, and cyclic and linear sweep voltammetry. The twofold increase in the current of the lidocaine oxidation peak on the modified electrode compared to the unmodified one is associated with the sensitizing effect of the composite modifier, which is due to an increase in the electroactive area and the number of lidocaine binding sites on the electrode surface. The sensor exhibits a wide dynamic range from 2 to 2120 µM with a low limit of detection of 0.18 µM lidocaine and high sensitivity of 0.755 µA/V µM. The interelectrode and intraelectrode repeatability of the analytical signal do not exceed 3.5%. The sensor response is stable within three weeks. The developed sensor was used for the determination of lidocaine in pharmaceuticals. The results of an analysis of real samples demonstrated good reproducibility (RSD ≤ 5.5%) and recovery (98–102%). [ABSTRACT FROM AUTHOR]

Exosomes as new biomarkers for cancer diagnosis have attracted attention because they are highly released by tumor cells in various biological fluids. In this study, an electrochemical paper-based immunosensor device (Exo-sensing paper) is introduced for the detection of exosome in the serum. The Exo-sensing paper is a three-electrode system that is prepared using pattern paper and carbon and silver inks. The sensor part of this immunosensor contains a three-dimensional porous nanocomposite of nickel nanofoam coupled with graphene oxide and gold nanoparticles. The high specific surface area of this nanocomposite increases the antibody loading on the sensor surface significantly and consequently leads to obtaining a wide linear range of 500–1 × 107 Exospore µL−1 with a detection limit of 110 Exosome µL−1. Due to some advantages of this constructed Exo-sensing paper such as easy storage, simple application, low cost and good selectivity in the real samples, this system has a good potential to be used as a point of care testing for in situ detection of the exosomes and is a promising strategy for minimally invasive liquid biopsy. [ABSTRACT FROM AUTHOR]

Amoxicillin, an antibacterial drug commonly used in food production, requires rapid and accurate detection due to its illegal usage and potential health risks. This study focuses on the development of surface-enhanced Raman scattering (SERS) biosensors using filter paper substrates coated with silver nanoparticles (Ag NPs) for the detection of amoxicillin. The Ag NPs were prepared by employing a chemical method, and their characteristics were analyzed through various techniques. The SERS substrates exhibited an impressive limit of detection (LOD) of 10–12 M for amoxicillin, with a mean relative standard deviation (RSD) of 6.63% for repeated measurements. The experimental and simulated enhancement factors were determined as 4.044 × 104 and 2.996 × 104, respectively. These disposable, reproducible, and chemically stable substrates demonstrate great potential for SERS-based research and the development of highly sensitive biosensors. [ABSTRACT FROM AUTHOR]

Highlights: The large-scale, high-strength, super-tough, and multifunctional nacre-like heterocyclic aramid (HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite papers were fabricated using the in-situ assembly of PPy onto the HA/MXene hydrogel template. The "brick-and-mortar" layered structure and abundant hydrogen-bonding interactions among MXene, PPy, and HA respond cooperatively to external stress and effectively increase the mechanical properties of HMP nanocomposite papers. The templating effect from HA/MXene was utilized to guide the assembly of conducting polymers, leading to high electrical conductivity and outstanding electromagnetic interference shielding performance. Robust, ultra-flexible, and multifunctional MXene-based electromagnetic interference (EMI) shielding nanocomposite films exhibit enormous potential for applications in artificial intelligence, wireless telecommunication, and portable/wearable electronic equipment. In this work, a nacre-inspired multifunctional heterocyclic aramid (HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper with large-scale, high strength, super toughness, and excellent tolerance to complex conditions is fabricated through the strategy of HA/MXene hydrogel template-assisted in-situ assembly of PPy. Benefiting from the "brick-and-mortar" layered structure and the strong hydrogen-bonding interactions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa), outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect of HA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly, the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dB at an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2 g−1. In addition, the papers also have excellent applications in electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developing high-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management. [ABSTRACT FROM AUTHOR]

Flax (Linum usitatissimum) is a bast fiber plant known for its long fibers, making it an excellent source of pulp for paper production. In Ethiopia, flax is primarily cultivated for oil, with the residual straw utilized for papermaking. This study focuses on pulping flax straw using the Kraft process and investigates its chemical composition, proximate analysis, and morphological properties. The proximate analysis revealed an ash content of 4.13% and moisture content of 11%. Chemical composition analysis showed cellulose at 51.34%, hemicellulose at 25.20%, lignin at 14.12%, ash at 4.13%, and extractives at 5.21%. The morphological properties included a fiber length of 1.41 mm, diameter of 16.78 μm, lumen width of 9.45 μm, and cell wall thickness of 3.77 μm. Flax straw exhibited an acceptable Runkel ratio (0.8) and flexibility coefficient (56.32), placing it within the range of non-wood fibers. SEM analysis of the pulp's morphology was conducted to assess fiber structure, including the presence of cracks. Pulp quality and length are directly linked to paper strength. Various pulping conditions were studied using a full-factorial design, with optimum conditions being 10% alkaline, 131.74°C, and 120 min of cooking time, yielding a pulp with a Kappa number of 10.45 and a yield of 40.56%. The resulting paper demonstrated standard tensile, tearing, and burst strengths, indicating that flax straw is a promising raw material for paper production. [ABSTRACT FROM AUTHOR]

Activated carbon paper is a type of porous carbon material with a highly developed pore structure and a large specific surface area. It finds extensive applications in adsorption, complexation, and catalyst support. To prepare high-performance activated carbon paper, this study investigates the changes in performance and structure of Poly(p-phenylene terephthalamide) (PPTA) paper under CO2 activation, ZnCl2 activation, H3PO4 activation, and NaOH activation conditions. The research reveals that carbon paper after CO2 activation has a certain tensile strength (0.36 MPa), while chemically activated carbon paper lacks tensile strength. Incorporating 15% carbon fiber (CF) into PPTA paper increases the tensile stress (1.26 MPa) and tensile strain (4.18%) of the activated carbon paper. NaOH-activated carbon paper has the highest specific surface area (1321.6 m2/g), the most disordered carbon structure (ID/IG = 1.22), the lowest carbon yield (23.9%), and a pore rate 4.16% higher than that of CO2-activated samples. The activated carbon paper prepared by ZnCl2 activation has the highest content of C = N bonds, with the nitrogen content of pyridine increasing by 31.8% compared to CO2 activation. This indicates that ZnCl2 protects the N elements in PPTA paper during the activation process, preventing their decomposition during carbonization. The activated carbon paper prepared by H3PO4 activation has the lowest electrical conductivity (1.62 S/cm). [ABSTRACT FROM AUTHOR]

The reactivity during enzymatic hydrolysis of eight industrially produced samples of pulps and semichemical pulps by enzyme preparations of glycosyl hydrolases B151 and F10 produced by a strain of the ascomycete fungus Penicillium verruculosum has been determined. It is shown for the first time that among fibrous pulps available on the market of pulp and paper industry in Russia, the highest level of yield of glucose from the initial wood during biocatalysis using cellulases and hemicellulases is characteristic of semichemical pulps obtained after green liquor cooking of hardwood. A high degree of enzymatic conversion of softwood bleached kraft pulp has been established, which in combination with the possibility of obtaining modified polysaccharide materials from non-hydrolysable residue makes this cellulosic substrate the most promising for the development of biological processes at pulp and paper industries. It is shown that drying of pulp negatively affects the efficiency of cellulose hydrolysis, while mechanical refining improves the performance of the enzymatic saccharification process. [ABSTRACT FROM AUTHOR]

An invisible layer of knowledge is progressively growing with the emergence of situated visualizations and reality-based information retrieval systems. In essence, digital content will overlap with real-world entities, eventually providing insights into the surrounding environment and useful information for the user. The implementation of such a vision may appear close, but many subtle details separate us from its fulfillment. This kind of implementation, as the overlap between rendered virtual annotations and the camera's real-world view, requires different computer vision paradigms for object recognition and tracking which often require high computing power and large-scale datasets of images. Nevertheless, these resources are not always available, and in some specific domains, the lack of an appropriate reference dataset could be disruptive for a considered task. In this particular scenario, we here consider the problem of wine recognition to support an augmented reading of their labels. In fact, images of wine bottle labels may not be available as wineries periodically change their designs, product information regulations may vary, and specific bottles may be rare, making the label recognition process hard or even impossible. In this work, we present augmented wine recognition, an augmented reality system that exploits optical character recognition paradigms to interpret and exploit the text within a wine label, without requiring any reference image. Our experiments show that such a framework can overcome the limitations posed by image retrieval-based systems while exhibiting a comparable performance. [ABSTRACT FROM AUTHOR]

A virus is a sub-microscopic infectious organism that causes diseases in humans, animals, and plants resulting in morbidity and may cause mortality. Proper diagnosis is necessary to initiate the treatment and pave the way to eradicate the viral infection. The current diagnostic kits for nucleic acid amplification assay, blood filtration, single-cell analysis are highly accurate, even though the procedure necessitates large sample volumes, complicated fabrication steps, time-consuming processes, and high costs. The filtration of viral samples from the blood is a tedious process. In this research, we have presented a home-based fabricated paper microfluidic chip to effectively filtrate viral particles from the sample to facilitate the nucleic acid amplification assay. The filtration analysis was exhibited for lateral and vertical flow paper chips fabricated via laser printing and polyethylene terephthalate (PET) encapsulation that circumvents the necessity of a traditional wax printer and hot plate. The results convey that the vertical flow paper chip with grade 4 inlet and outlet filters 98.57% of unnecessary particles from the sample. The paper-based microfluidic chip developed in this research is simple, easy to fabricate, and inexpensive to access in underdeveloped countries. The paper chip can pave the way for applications like lab-on-chip devices, POC assays, rapid nucleic acid amplification tests, cell cultures, and biomolecular research. [ABSTRACT FROM AUTHOR]

The non-wood pulp fibers in the paper and printing industry have been in demand for economic and environmental necessity. In this communication, the agro-processing waste sugarcane bagasse (SCB) and amla pomace was used to develop a packaging application paper. The physical and mechanical properties of non-wood pulp remain an issue for further application. The synergistic effect of nanoparticle TiO2 and amla pomace addition into the SCB was investigated. The developed SCB paper evaluated the physical, mechanical, and barriers to moisture. The molecular interaction between the constituents of paper was investigated with FTIR. The paper's morphological crystallinity and surface topology behavior were observed in FESEM, XRD, and AFM analysis. The analysis results indicate that the SCB utilization approach could bring a sustainable solution for non-wood pulp. The mechanical properties of the paper have not been considerably affected by the addition of TiO2. The water vapor barrier quality improved as compared to the control bagasse paper. The microstructural topology of the paper is well elaborated through FESEM and AFM. The crystallinity of the paper has been significantly affected by the addition of TiO2. The EDX analysis confirms the elemental composition of cellulose and TiO2 particles in the paper sheets. In conclusion, the results may not have significantly affected the paper's performance. The antibacterial effectiveness of paper was determined by analyzing its ability to inhibit the growth of E. coli. It was discovered that the antibacterial activity of paper increased as TiO2 concentration increased. Still, the approach to developing paper from agro-processing waste sources with nanoparticles can take a step toward a sustainable packaging solution. [ABSTRACT FROM AUTHOR]

In the engine of heavy trucks, the built-in fuel filter assumes the role of "lungs". The core of the filter, namely the fuel filter paper, acts as a filter for small impurities and separates oil and water. In order to be able to separate minute impurities from the fuel, in this study, we prepared a novel fuel oil filter paper with high efficiency and high dust holding capacity based on wet-laid forming by laminating PBT/PP two-component melt-blown nonwoven material and cellulose nanocrystals (CNC)-doped cellulose wood fiber pulp with the fiber mesh combination forming technology. The effects of the CNC mixing ratio, surface density of melt-blown nonwoven material layer, surface density of cellulose wood pulp paper layer and calendaring pressure on the pore size and filtration performance of the composite samples were investigated, and the filtration efficiency of the composite samples on the tiny impurities in the fuel were also studied. The results showed that the novel composite fuel filter paper material prepared by the combined forming technology of fibrous web had high filtration efficiency and dust holding capacity, and the filtration efficiency of the composite samples could respectively reach 99.90% and 99.52% for particles larger than 14 μm and 4 μm in diameter in the fuel. At the same time, the dust holding capacity of the composite sample can reach up to 27.63 mgcm−2. [ABSTRACT FROM AUTHOR]

The Progress in International Reading Literacy Study (PIRLS) was conducted in paper and online reading modes in 2016 using the same samples of students in a number of countries. Differences in reading literacy scores were found in several European countries. In some countries, the differences favored the electronic reading mode. Yet in others, the paper reading mode was favored. As the electronic reading mode differs substantially in the cognitive demands compared to the paper mode, it can be expected that the differences between the two modes are related to the variables related to technology: availability and access, general use, use for educational purposes in class or out-of-school, and self-efficacy with technology. This study investigates the Information and Communication Technology (ICT) factors related to the differences in paper and online reading in six European countries participating in both modes in PIRLS 2016. This study uses linear regression models as the application of multilevel modeling is not suitable because of the low between-school variances across countries. The results from this study show limited support for the relative effect that the student individual, school, and classroom ICT variables have on the differences between paper and electronic reading. Access to technology is related to mode differences only in Italy, and the use of computer devices in and out of school is related to the mode differences in Italy and Portugal. Student self-efficacy is related to the mode differences in Portugal and Slovenia. School resources show significant effects in Denmark (computers to students ratio) and Italy (instruction affected by digital resource shortages). None of the classroom variables showed any significant relationship in any of the countries. In addition, socio-economic status (which is proxied by the variable on home resources for learning) is a significant predictor in half of the countries. In addition to these findings, the general technological context within countries is discussed as part of an evaluation of the difference in reading in the two test delivery modes. The general uptake of technology in different social and economic aspects, as measured by the Digital Economy and Society Index (DESI), follows the differences between the two reading modes. [ABSTRACT FROM AUTHOR]

Background: This study aims to identify trends, research gaps, leading journals, institutions, countries, and authors by examining the top 100 cited Yttrium-90 Radioembolization (Y90) research articles. The insights gained will assist funding and collaboration efforts in Y90 research. The team analyzed 981 articles from 36 peer-reviewed journals, gathering data on authors, publication year, journal, citations, affiliations, keywords, and references. Author affiliations were scrutinized to pinpoint institutions and countries. p values < 0.05 were deemed statistically significant. The most cited paper (703 citations) was authored by Salem et al. (2010), and the journal with the most publications (16) was Journal of Vascular and Interventional Radiology. There was no significant correlation between journal impact factor and citation metrics. A decreasing trend in the number of top 100 articles was observed since the peak period (2008–2013). Most papers were published in high-impact factor (IF > 3, n = 31/35) and SCImago Q1 journals (86/100), with Northwestern University, Clínica Universidad de Navarra, and Ludwig Maximilian University of Munich being the leading institutions. The most prolific authors were Salem, R., Lewandowski, R.J., and Mulcahy, M.F., with Salem, R. as the most influential. A statistically significant positive correlation between collaborative links and published articles was also discovered. Short conclusion: The top 100 cited articles were primarily published in high-impact journals, and Northwestern University and the USA showed greater productivity and collaboration. These findings have crucial implications for researchers, policymakers, and institutions, aiding in the improvement of Y90 application and understanding in clinical practice. [ABSTRACT FROM AUTHOR]

The pulp and paper industry is critical to global industrial and economic development. Recently, India's pulp and paper industries have been facing severe competitive challenges. The challenges have impaired the environmental performance and resulted in the closure of several operations. Assessment and prediction of the performance of the Indian pulp and paper industry using various parameters is a critical task for researchers. This study proposes a framework for performance assessment and prediction based on Data Envelopment Analysis (DEA), Artificial Neural Networks, and Deep Learning (DL) to assist industry administration and decision-making. We presented a case study based on eight industries to demonstrate the methodology's applicability. This study analyses and predicts industry performance based on sample data observations over 30 years. The result suggests the DEA-DL-based efficiency prediction has an overall MSE of 0.08 compared with the actual efficiency. Furthermore, the efficiency rankings are compared between the three techniques. The results suggest that the integrated DEA-DL method is primarily accurate in most scenarios with the actual values. The findings of this study provide a comprehensive analysis of environmental performance for policymakers. [ABSTRACT FROM AUTHOR]

This study developed a novel paper-based sensor for the simultaneous analysis of ascorbic acid (AA) and hydroquinone (HQ). The sensor utilized polyvinyl alcohol (PVA)-stabilized silver nanoparticles (AgNPs-PVA) as the reagent probe and PVA media acted as the filter for separation of the analytes. Polydimethylsiloxane (PDMS) and ethanol serve as the stationary phase and eluent, respectively, exploiting the differences in analyte reactions and solubility to achieve their separation on the filter paper. The circular sensor's central zone was AA's detection area, while HQ was detected in the outer ring region. AA induced an immediate color change in the test kit, whereas HQ required a 20-minute elution with ethanol followed by colorimetric analysis. All analytes exhibited relative standard deviations of repeatability and reproducibility below 2.7% and 9.5%, respectively. Under optimal conditions, the linear detection range for HQ was 0.2-2.0 mg⋅L− 1, while AA was 0.1-2.0 mg⋅L− 1. The detection limit was determined to be 0.05 mg⋅L− 1 for AA and 0.1 mg⋅L− 1 for HQ. The recoveries of AA and HQ in cosmetic cream samples ranged from 80 to 110%. The accuracy of the sensor's measurements was further validated by comparison with the HPLC-DAD method. [ABSTRACT FROM AUTHOR]

A wearable potentiometric device is reported based on an innovative butterfly-like paper-based microfluidic system, allowing for continuous monitoring of pH and Na+ levels in sweat during physical activity. Specifically, the use of the butterfly-like configuration avoids evaporation phenomena and memory effects, enabling precise and timely biomarker determination in sweat. Two ad hoc modified screen-printed electrodes were embedded in the butterfly-like paper-based microfluidics, and the sensing device was further integrated with a portable and miniaturized potentiostat, leveraging Bluetooth technology for efficient data transmission. First, the paper-based microfluidic configuration was tested for optimal fluidic management to obtain optimized performance of the device. Subsequently, the two electrodes were individually tested to detect the two biomarkers, namely pH and Na+. The results demonstrated highly promising near-Nernstian (0.056 ± 0.002 V/dec) and super-Nernstian (− 0.080 ± 0.003 V/pH) responses, for Na+ and pH detection, respectively. Additionally, several important parameters such as storage stability, interferents, and memory effect by hysteresis study were also investigated. Finally, the butterfly-like paper-based microfluidic wearable device was tested for Na+ and pH monitoring during the physical activity of three volunteers engaged in different exercises, obtaining a good correlation between Na+ increase and dehydration phenomena. Furthermore, one volunteer was tested through a cardiopulmonary test, demonstrating a correlation between sodium Na+ increase and the energetic effort by the volunteer. Our wearable device highlights the high potential to enable early evaluation of dehydration and open up new opportunities in sports activity monitoring. [ABSTRACT FROM AUTHOR]

The flame spread behavior over a filter paper in opposed flow was investigated on the ISS/Kibo, and the results were compared with the flammability map predicted in advance by scale analysis for a two-dimensional flame. The on-orbit experiments were conducted in the solid combustion experimental module (SCEM) as the first combustion test of the FLARE project by JAXA. A filter paper with a length of 130 mm, a width of 40 mm or 20 mm, and a thickness of 0.12 mm was used as the specimen. The opposed flow velocity and the oxygen concentration were varied from 0 cm/s to 25 cm/s, and from 13.5% to 34%, respectively. The ambient pressure is 101.3 kPa. The predicted limiting curve reasonably agreed with the minimum limiting oxygen concentration observed. On the other hand, in extremely slow flows, very robust flames were observed beyond the limiting curve. When the condition reached the limit of two-dimensional flame, the flame front changed from a linear shape to a spherical shape (flamelet) to shorten the preheat zone length, reducing the radiative heat loss to survive. In these cases, the flamelet was sustained for a long time (> 100 s), and a large amount of decomposed gas was released at the periphery of the pyrolysis zone generating a combustible vapor cloud around the spherical flame font. The presence of a long-life robust flamelet and the accumulation of such combustible mist can be fire hazards in microgravity. [ABSTRACT FROM AUTHOR]

Background The bleach-boosting capability of xylanases is well-known. The use of xylanase pre-treatment before the application of chemical bleach has multiple advantages including (i) lesser use of polluting chemicals of the traditional bleaching process; (ii) less damage to the cellulosic fbers, therefore better recyclability; and (iii) better brightness of chemical bleach. The major impediment in the application is the availability of commercial enzymes that are active at the elevated temperature and pH that exist during the industrial pulping process. In the present paper, xylanase having suitability for application in deinking is reported. Results The xylanase used showed high deinking potential. Optimal deinking was obtained at the xylanase dosing of 20U/g of the dried pulp at 60°C for a treatment time of 1h. It could bring about a 50% reduction in the usage of chemical bleach that was applied after xylanase pre-treatment. The comparison of FTIR spectra showed changes in intensity without signifcant changes in the functional group signatures implying that there is negligible damage to the fber strength in the xylanase pre-treatment process as compared to the chemical bleach process. Conclusion The xylanase used in this study was efective in deinking paper pulp and can be used for bio-bleaching of recycled paper. [ABSTRACT FROM AUTHOR]

Paper bookbindings have been disregarded for centuries by scholars since they were only considered temporary covering materials for manuscripts and books. Recently, there is a willingness to reconsider these bindings and to evaluate their role. Thanks to the collaboration with the Marciana National Library in Venice, which stores an impressive collection of 849 detached bindings, the current research provides a chemical-physical elucidation about the composition and the manufacture of paper bookbindings realized between the 16th and the eighteenth century in the Venetian area. A selection of bookbindings was analysed by the means of complementary methods (thickness measurements, Attenuated Total Reflection—Fourier-Transform Infrared Spectroscopy (ATR-FTIR), Pyrolysis–Gas Chromatography–Mass Spectrometry (Py-GC–MS) and X-Ray Fluorescence (XRF)). Data evidence the presence of cellulose as the main component of paper pulp; hemicellulose and lignin were identified too, probably related to the presence of linen/hemp rags in the paper production. Gelatine was detected muck likely related to paper sizing; among inorganic additives CaCO3 was found in all samples. The presence of waxy material may be due to past undocumented conservation treatments. [ABSTRACT FROM AUTHOR]

In this paper, by a simple hydrothermal method vertically aligned ZnO nanorod arrays were grown on the carbon fiber paper (CFP) and then through a facile chemical bath deposition method CuO nanosheets were loaded on ZnO nanorod arrays, following by thermal spraying method, carboxylated carbon nanotubes (CCNTs) were successfully integrated with CuO/ZnO@CFP to form a binder-free CuO/ZnO-CCNT@CFP sensor. The sensor shows enhanced sensing activity for baicalein and luteolin determination due to the improved structural integration and synergism of different electrode material components. Remarkably, the CuO/ZnO-CCNT@CFP sensor showed good linear relationships over wide concentration ranges of 0.03–0.70 µM and 0.70–20 µM for baicalein and 0.03–0.45 µM and 0.45–8.5 µM for luteolin detection, with the detection limits of 1.7 nM for baicalein and 0.5 nM for luteolin, respectively. More importantly, the CuO/ZnO-CCNT@CFP sensor was utilized in the simultaneous determination of baicalein and luteolin, delivering linear ranges of 0.4–14 µM (baicalein) and 0.2–6 µM (luteolin) with the limit of detection of 0.05 µM and 0.03 µM, respectively. In addition, the developed CuO/ZnO-CCNT@CFP electrode was further investigated to detect baicalein and luteolin in traditional herbal medicine samples, showing satisfied results in comparison with analytic results from high performance liquid chromatography. [ABSTRACT FROM AUTHOR]

The present study explored chitosan, a biodegradable nontoxic biopolymer, at different dosages for surface treatment of recycled paper to improve various properties relevant to packaging. Chitosan, at all applied concentrations, improved important paper properties like surface, strength and barrier due to which the low strength paper can also be used as a packaging paper. The effects of surface treatment of chitosan solutions of different concentrations on paper were analyzed by measuring breaking length, burst index, tear index, double fold, stiffness, air permeance, water vapor transmission rate (WVTR), wax pick, tensile energy absorption (TEA), and stretch. After surface treatment by 1% solution of chitosan, the breaking length, double fold, TEA, and stretch in machine direction were increased by 53.8%, 243%, 93%, and 75%, respectively, whereas burst index was increased by 38.4% in comparison with the base paper. The WVTR was reduced from 706 to 496 g/m2/24 h, and air passage time was increased from 18 to 65 Gurley s after surface treatment by 1% chitosan solution on the base paper. The chitosan solution at all the concentrations showed antibacterial activity in plate assay therefore reducing the susceptibility of paper to microbial attack. [ABSTRACT FROM AUTHOR]

Background: The mobile device diffusion has increasingly highlighted the opportunity to collect patient-reported outcomes (PROs) through electronic patient-reported outcomes measurements (ePROMs) during the clinical routine. Despite the ePROMs promises and advantages, the equivalence when a PRO measure is moved from the original paper-and-pencil to the electronic version is still little investigated. This study aims at evaluating equivalence between PROMs and ePROMs self-administration in people with multiple sclerosis (PwMS); in addition, preference of self-administration type was evaluated. Methods: The Manual Ability Measure-36 (MAM-36) and Fatigue Severity Scale (FSS) were selected for the equivalence test. The app ABOUTCOME was developed through a user-centered design approach to administer the questionnaires on tablet. Both paper-and-pencil and electronic versions were randomly self-administered. Intrarater reliability between both versions was evaluated through the intraclass correlation coefficient (ICC, excellent for values ≥ 0.75). Results: Fifty PwMS (35 females) participated to the study (mean age: 54.7±11.0 years, disease course: 27 relapsing-remitting and 23 progressive; mean EDSS: 4.7±1.9; mean disease duration: 13.3±9.5 years). No statistically significant differences were found for the means total scores of MAM-36 (p = 0.61) and FSS (p = 0.78). The ICC value for MAM-36 and FSS was excellent (0.98 and 0.94, respectively). Most of participants preferred the tablet version (84%). Conclusion: The results of the study provide evidence about the equivalence between the paper-and-pencil and electronic versions of PROs administration. In addition, PwMS prefer electronic methods rather than paper because the information can be provided more efficiently and accurately. The results could be easily extended to other MS PROs. [ABSTRACT FROM AUTHOR]

Background: Oil spills are widespread and can cause devastating environmental consequences. Rapid oil identification is critical to find the origin of the spill, monitor the environment, and lead to informed mitigation measures. The current standard methods in oil spill identification are precise and reliable, but require extensive sample preparation, long instrument runs, and time-consuming data processing. Direct analysis in real time time-of-flight mass spectrometry (DART-ToF MS) has been employed to screen for spilled petroleum oils, with results obtained in mere hours. The present study introduced an innovative, simple, and fast oil sampling method using hydrophobic filter paper and demonstrated its compatibility with DART-ToF MS analysis. Motor oils, jet fuels, marine diesels, crude oils, intermediate fuel oils, heavy fuel oils, and diluted bitumen were collected using the filter paper sampling method. Classification models were constructed from the spectral data by heat map inspection followed by principal component analysis (PCA) and discriminant analysis of principal components (DAPC). Oil slicks and weathered oil slicks were prepared from five oil types, and samples from each slick were collected using filter paper. Results: The filter paper technique allowed for effective oil sampling and data acquisition by DART-ToF MS for diluted source oils, oil slicks and weathered oil slicks. Classification via the constructed DAPC models indicated that the DART-ToF MS instrument in tandem with filter paper sampling and multivariate statistics can accurately identify common oil types, with significant improvement of sample collection and turnaround time. Conclusions: The promising classification results, simple sample collection, and rapid data analysis illustrate the potential use of hydrophobic filter paper and DART-ToF MS as tools in managing large scale oil spill emergency situations. [ABSTRACT FROM AUTHOR]

We previously used a grinder to prepare cellulose nanofibers (CNFs) that were then added to pulp to improve the wet strength of paper, with subsequent alkali treatment further improving its wet tensile strength. However, mass production of CNF using ultra-fine grinders is not feasible; moreover, fabricating paper sheets by first preparing CNFs and adding them to pulp is a complex process. Therefore, in this study, we directly fibrillated pulp using a refiner instead separately preparing CNFs, with the refined pulp used to make paper sheets, thereby simplifying the process. The resulting dried sheets were subsequently treated with 8 and 16 wt% NaOH, after which the co-reinforcing effect of the refiner and NaOH treatments on the wet tensile strength of paper was examined. Unexpectedly, wet tensile strength of 39 and 45 MPa was achieved. These values are higher than values obtained using the CNFs and NaOH treatment, and comparable to the dry strength of untreated and unrefined pulp sheet. Moreover, the dewatering time of the refiner-treated pulp was significantly shorter than that of the CNF-mixed pulp, which reduces the time required to prepare paper. This study demonstrated that refiner-treated pulp is more suitable than CNF-mixed pulp for improving paper wet strength. [ABSTRACT FROM AUTHOR]

In 1980, Prof. Bimla Buti derived, for the first time, an exact solution for localized nonlinear ion-acoustic waves in a plasma with two electron components. Her theory predicted that in the presence of a second electron component, ion-acoustic holes (i.e., solitons with density dips) can exist in addition to regular ion-acoustic solitons having density humps. In 1982, Temerin, et al. [1] reported the observations of ion holes in the Earth's auroral acceleration region between 6000 and 8000 km altitude by S3-3 spacecraft, thus confirming the theoretical predictions of Buti's model. Later on, ion holes were observed on auroral field lines by the Viking spacecraft [2,3] and the Polar spacecraft [4]. It is indeed a nice example where theory leads space experiments and observations. [ABSTRACT FROM AUTHOR]

In this study, two methods were examined to optimize the immobilization of antibodies on paper when conducting a paper-based enzyme-linked immunosorbent assay (P-ELISA). Human IgG, as a test-capture protein, was immobilized on paper via the formation of Schiff bases. Aldehyde groups were introduced onto the surface of the paper via two methods: NaIO4 and 3-aminopropyltriethoxysilane (APTS) with glutaraldehyde (APTS-glutaraldehyde). In the assay, horseradish peroxidase-conjugated anti-human IgG (HRP-anti-IgG) binds to the immobilized human IgG, and the colorimetric reaction of 3,3′,5,5′-tetramethylbenzyzine (TMB) produces a blue color in the presence of H2O2 and HRP-anti-IgG as a model analyte. The immobilization of human IgG, the enzymatic reaction conditions, and the reduction of the chemical bond between the paper surface and immobilized human IgG all were optimized in order to improve both the analytical performance and the stability. In addition, the thickness of the paper was examined to stabilize the analytical signal. Consequently, the APTS-glutaraldehyde method was superior to the NaIO4 method in terms of sensitivity and reproducibility. Conversely, the reduction of imine to amine with NaBH4 proved to exert only minimal influence on sensitivity and stability, although it tended to degrade reproducibility. We also found that thick paper was preferential when using P-ELISA because a rigid paper substrate prevents distortion of the paper surface that is often caused by repeated washing processes. [ABSTRACT FROM AUTHOR]

The Home Literacy model predicts different outcomes depending on formal and informal literacy practices carried out at home. However, this model does not explicitly consider the potential differences that the media (paper vs. tablets) in which these practices are carried out can have on performance. The present study explored this issue. Participants were 136 children aged 6–7 years old and their parents. The different activities performed at home were analysed through reports of the parents, and children were assessed at school for their reading performance (decoding and comprehension). Results showed how formal practices using traditional materials predicted reading comprehension, but informal practices did not predict any performance measure. The digital home literacy environment showed no impact on reading performance, suggesting that two different environments (paper and digital) might exist, each one of them having differential impacts on performance. Implications for research and education are discussed. [ABSTRACT FROM AUTHOR]

A comparative study of the supramolecular structure, physicochemical properties, and morphology of the powder celluloses (PCs) obtained from the waste paper of newsprint and cardboard, plant celluloses, and nonconventional raw materials was conducted using the methods of FT-IR spectroscopy, high-resolution solid-state 13C NMR spectroscopy, wide-angle X-ray scattering, and scanning electron microscopy (SEM). According to the FT-IR and 13C NMR spectroscopy results, the functional composition of the PCs is similar to that of the wood PCs and matches highly purified cellulose samples. The crystallographic structure of the powder samples corresponds to the structure of cellulose I. The crystallinity and the transverse dimensions of the crystallites are 39.4 and 40.2%, and 45 Å [110] and 54 Å [110], for the PCs from newsprint paper and cardboard, respectively. These values considerably exceed those for the initial waste paper samples. A comparative analysis of the SEM results showed a significant similarity among the PC fibers of different origin. The results of the study of the physicochemical properties of the PCs isolated from the waste paper allow predicting their competitive application in comparison with plant PCs. [ABSTRACT FROM AUTHOR]

There has always been an interest in the professional communities of libraries, archives and conservation science to find ways of estimating the rate of degradation of paper under archival conservation conditions. Previously we reported a number of considerations for developing a kinetic degradation model based on Whatman no.1 paper. In the present research, this model was extended to 10 different papers and validated. Various physical and chemical properties of acidic, neutral, and alkaline papers were measured, such as the degree of polymerization (DP), tensile strength, equilibrium moisture content, and pH, as well as alkaline fillers content when applicable. The activation energy (Ea) based on DP of cellulose and zero-span tensile strength were determined. Ea and pH had the most significant influence on the simulated decay of paper. Papers with a high Ea (> 120 kJ mol−1), alkaline such as those containing at least 2% CaCO3, and acidic—but good printing quality papers made of bleached chemical pulp– were found the most durable in ambient conditions. Papers with a lower Ea (< 110 kJ mol−1) such as lignocellulosic papers containing significant amount of mechanical pulp were much less stable over time. Whatman filter papers, used as models of pure cellulosic papers, were found to have low Ea despite the good quality cotton fibers. A generic isoperm equation based on Ea was developed to predict the changes in the state of papers under various climatic conditions, and was applicable independently of the pH of the paper. The model developed allows a better quantification of the deterioration rate of printing papers such as those that are currently, and will be in the future, found in our archival collections. [ABSTRACT FROM AUTHOR]

Traditionally, cellulose nanofiber (CNF) production has primarily relied on virgin cellulose sources. Yet, the shift to using paper mill sludge (PMS) as a source for CNF underscores the significance of reusing and recycling industrial byproducts. PMS contains significant amounts of cellulose that can be extracted as a raw material. The purpose of present study is to provide a sustainable approach to PMS utilization as a paper coating additive in the cellulose nanofibrils (CNFPMS) form via simply scalable wire-wound rod coating method. The effect of CNFPMS additive amounts at two coating layers on microstructure and surface properties of coatings such as porosity, air permeability surface roughness and optical properties such as brightness, gloss and CIE L*a*b* is studied, which they can also provide insight for the eventual print performance. Results indicated that the obtained CNFPMS in paper coating shows 52% decrease in porosity, presenting significant improvement in the coating microstructure. The marginal increase in permeability coefficient and surface roughness, 54% and 10%, respectively, suggests improving color reproduction and preventing color density losses. Optical analysis showed slight decrease in brightness and gloss, as was expected. Notably, the lightness was improved, which also indicates increasing color gamut volume in printing applications. As a result, the current work offers a sustainable approach to manage PMS for use in paper coatings as a high-value-added material. [ABSTRACT FROM AUTHOR]

In this work, solid-surface fluorescence spectra of Rhodamine B (RhB) and fluorescein (FLU), two extensively used fluorophores, were studied and their concentrations were semi-quantitatively determined using the three-dimensional excitation–emission matrix (3D-EEM) data. In order to measure the solid fluorescence spectra, a trace amount of fluorophores was physically adsorbed on a piece of filter paper as a fluorescent paper, and the fluorescence spectra were recorded from the surface of the fluorescent paper instead of the inner parts of the solution. The spectral measurement was performed utilizing a routine spectrofluorimeter designed to measure the fluorescence of solution only by placing the fluorescent paper in a simple handmade holder at an adjusted incident angle of radiation. The results revealed a significant increase in the fluorescence intensity of the fluorescent paper strip compared to the solution phase. Moreover, in the RhB–FLU paper strip the forster resonance energy transfer was observed between FLU and RhB, similar to the observed phenomenon in the solution phase. For quantifying fluorophores, the EEM data were successfully resolved by applying multivariate partial least squares and parallel factor analysis (PARAFAC) modeling, and the results were compared with the univariate method. This study may provide a general guideline in further developing the solid fluorescence measurement of concentrated solutions or solid samples that have fluorescence measurement limitations such as high self-absorption and highly scattered spectra by using a conventional spectrofluorimeter, and also of biological samples where a trace amount of the analyte is available and high sensitivity is required. [ABSTRACT FROM AUTHOR]