1. Bi-functional 3D-NiCu-Double Hydroxide@Partially Etched 3D-NiCu Catalysts for Non-Enzymatic Glucose Detection and the Hydrogen Evolution Reaction
- Author
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Kyeong-Nam Kang, Sun-I Kim, Jong-Chul Yoon, Jinho Kim, Collin Cahoon, and Ji-Hyun Jang
- Subjects
General Materials Science - Abstract
Hydrogen production, which is in the spotlight as a promising eco-friendly fuel, and the need for inexpensive and accurate electronic devices in the biochemistry field are important emerging technologies. However, the use of electrocatalytic devices based on expensive noble metal catalysts limits commercial applications. In recent years, to improve performance and reduce cost, electrocatalysts based on cheaper copper or nickel materials have been investigated for the non-enzymatic glucose oxidation reaction (GOR) and hydrogen evolution reaction (HER). In this study, we demonstrate a facile and easy electrochemical method of forming a cheap nickel copper double hydroxide (NiCu-DH) electrocatalyst deposited onto a three-dimensional (3D) CuNi current collector, which can effectively handle two different reactions due to its high activity for both the GOR and the HER. The as-prepared electrode has a structure comprising abundant 3D-interconnected porous dendritic walls for easy access of the electrolyte ions and highly conductive networks for fast electron transfer; additionally, it provides numerous electroactive sites. The synergistic combination of the dendritic 3D-CuNi with its abundant active sites and the self-made NiCu-DH with its excellent electrocatalytic activity toward the oxidation of glucose and HER enables use of the catalyst for both reactions. The as-prepared electrode as a glucose sensor exhibits an outstanding glucose detection limit value (0.4 μM) and a wide detection range (from 0.4 μM to 1.4 mM) with an excellent sensitivity of 1452.5 μA/cm
- Published
- 2022
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