1. Solid–liquid interface analysis with in‐situ Rutherford backscattering and electrochemical impedance spectroscopy
- Author
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Sabine Apelt, Ute Bergmann, Nasrin B. Khojasteh, and René Heller
- Subjects
In situ ,Materials science ,Analytical chemistry ,Surfaces and Interfaces ,General Chemistry ,Condensed Matter Physics ,Rutherford backscattering spectrometry ,Surfaces, Coatings and Films ,Dielectric spectroscopy ,chemistry.chemical_compound ,electrochemical impedance spectroscopy ,Silicon nitride ,chemistry ,point of zero charge ,Materials Chemistry ,Interface analysis ,Solid liquid ,electrochemical double layer - Abstract
A novel Rutherford backscattering spectrometry (RBS) method is presented to investigate the interface between a solid surface and a surrounding liquid. The introduced measurement system allows to observe and quantify adsorption at the solid–liquid interface and the formation of the electrochemical double layer (EDL). BaCl2 as a bicomponent electrolyte and a Si3N4 membrane surface are chosen as a model system to prove the capabilities of the setup. The results of these RBS measurements are combined with electrochemical impedance spectroscopy (EIS) to validate the findings for the solid–liquid interface under study. Complementary results and discrepancies regarding the formation of the EDL are discussed. Author keywords: electrochemical double layer, electrochemical impedance spectroscopy, Rutherford backscattering spectroscopy, silicon nitride
- Published
- 2020
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