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In this work we study and optimize the single solar cell efficiency of GaN x As 1-x-y Sb y and Ga 1-x In x N y As 1-y deposed on GaAs. The solar cells are simulated, in the aim to find the best concentration of nitrogen and antimony for GaN x As 1-x-y Sb y , and indium and nitrogen for Ga 1-x In x N y As 1-y which gives us a band gap energy around 1 eV with a low strain and a maximum absorption, in fact we do not have only one value but a whole interval for both structures. In the second step we simulate the efficiency of both GaNAsSb and GaInNAs solar cells with the find concentration values in order to see which of the two structures will give a higher efficiency. We noticed that the results were obtained under AM1.5 illumination, 300 K and an ambient pressure. The two structures had a thickness of 300 nm. The N and P layers have a doping level of 1.1015 cm-3 and 1.1016 cm-3 respectively. This study gives us the possibility to produce multi-function solar cells. [ABSTRACT FROM AUTHOR]

In this work we study and optimize the single solar cell efficiency of GaN x As 1-x-y Sb y and Ga 1-x In x N y As 1-y deposed on GaAs. The solar cells are simulated, in the aim to find the best concentration of nitrogen and antimony for GaN x As 1-x-y Sb y , and indium and nitrogen for Ga 1-x In x N y As 1-y which gives us a band gap energy around 1 eV with a low strain and a maximum absorption, in fact we do not have only one value but a whole interval for both structures. In the second step we simulate the efficiency of both GaNAsSb and GaInNAs solar cells with the find concentration values in order to see which of the two structures will give a higher efficiency. We noticed that the results were obtained under AM1.5 illumination, 300 K and an ambient pressure. The two structures had a thickness of 300 nm. The N and P layers have a doping level of 1.1015 cm-3 and 1.1016 cm-3 respectively. This study gives us the possibility to produce multi-function solar cells. [ABSTRACT FROM AUTHOR]

In this paper, we report a simulation and investigation of a single In x Ga 1-x N/GaN axial multiple quantum well nanowire (MQWNW) solar cell of radius r = 190 nm and a length of L = 1165 nm. Our results have been shown that 15 In 0.15 Ga 0.85 N (QW) /GaN (barrier) periods is the maximum number that our structure can be supported with an optimal efficiency of about 1.65% achieved with ε = 1.5%. The insertion of MQWs in nanowire permits the growth of In x Ga 1-x N MQWs with high indium concentration of about 50% and ε = 5%. At this indium concentration, the optimal efficiency obtained was 1.70%. Moreover; the structure has been studied with respect to the nanowire radius. In this context, we have shown that the efficiency enhancement achieved through the increase of radius is attributed to the increase of photo-carriers. Study of polarization and proton irradiations has indicated the negative effect of polarization on structure performances and high resistance of III-N semiconductor materials against the radiations, respectively. From these novel structures we can improve solar cell performance for new applications. [ABSTRACT FROM AUTHOR]

• We report the modelling and optimization of a solar cell based on new material using SCAPS software. • A high absorption coefficient was found. • The influence of thickness, temperature, resistances and defects on the different electrical parameters. • A high conversion efficiency was obtained under optimum parameters. • A respectable compatibility has been shown compared with the results of wxAMPS software. Based on several semiconductor research, we have studied one of the new semiconductors, due to its exciting physical proprieties that in turn solve some problems in the photovoltaic's industry. We have divided this work into two parts. The first part, is to study the optical proprieties of ZnSnN 2 , as calculation of the absorption coefficient, bandgap, reflection coefficient, and transmission coefficient. As for the second part, a study of some parameters that affect the efficiency of p-CuCrO 2 (CCO)/ n-ZnSnN 2 (ZTN) solar cell using SCAPS-1D software, and our results are compared with the results of another software (wxAMPS), where results showed great compatibility with the presence of weak uncertainty. We have studied the influence of many parameters such as the thickness of the absorber layer (n-ZnSnN 2), the thickness of the buffer layer (p-CuCrO 2) , the temperature, the series resistance (R s), the shunt resistance (R sh) and the defect density on the performance of ZnSnN 2 solar cells which included in the real device. The photovoltaic parameters have been calculated using AM1.5G solar irradiance at the intensity of one sun, a temperature of 300 K, and considering the flat band condition at the interface. We have been achieving a high-efficiency of η ≈ 22% without defects. Given the characteristics of this new semiconductor ZnSnN 2 , which composed of earth-abundant, non-toxic and inexpensive element, as well as a high absorption coefficient, it can be considered as an alternative for PV and optoelectronic applications. [ABSTRACT FROM AUTHOR]

The aim of this modeling and simulation is to study the influence of the incorporation of nitrogen (N) and aluminum (Al) on the optoelectronic properties of the structure Al x Ga 1-x As 1-y N y /Ge, and then choose the right combination (N, Al) which gives us a better conversational efficiency of the junction(Al x Ga 1-x As 1-y N y /Ge), in this study, we simulated the effect of N and Al on the strain, the band gap, carrier mobility and structure efficiency where we based on theoretical models experimentally validate, It has been shown that the Al concentration slightly affects the stress and the band gap, but it has a significant influence on the incorporation of nitrogen and in a more homogeneous way introducing a dramatic decrease in the band gap what change considerably the absorption, carrier mobility and final yield of the structure. [ABSTRACT FROM AUTHOR]

This paper reports simulations of gradual bandgap CIGS absorber and its impact on the characteristics of a solar cell. The bandgap of the CIGS absorber varies linearly and drops from E gmax (at the junction limit) to E gmin (in the vicinity of the rear contact).We introduce an effective absorption coefficient based on this variation. We will demonstrate that this gradual profile contributes to an improvement up to 171 mV of the open circuit voltage V oc of the cell that is linked to the modification of the internal electrical field distribution within the absorber. However, a joint reduction of 1.50 mA/cm 2 of short circuit current density, J sc , is observed. Overall, the conversion efficiency increases from 19.2%, for a uniform bandgap absorber structure, to 24.9% in that case of gradual bandgap. Additionally, we investigate the impact of absorber thickness and temperature on cell characteristics. [ABSTRACT FROM AUTHOR]

Considering the chalcopyrite solar cell fabrication process, the commonly reported substrate bending effect that is observed after thermal process, in a front side halogen lamp-based annealing configuration (Rapid Thermal Annealing –RTA- equipment), has been investigated. We first proposed a simple model explaining the substrate bending shape dependence on the initial stress state within the molybdenum (Mo) layer (free, tensile or compressive). Then, we showed that it is possible to overcome this issue by simply using a reactive (oxygen based) sputtering process for the deposition of the Mo layer. Finally, we showed that using a bilayer structure Mo(O)/Mo allows a more precise control of the flatness of the annealed samples. To understand the mechanisms governing such changes in substrate bending, structural and morphological material changes as a function of oxygen flow have been investigated by using X-ray diffraction and scanning electron microscope imaging, respectively. The elemental distribution throughout the Mo(O)/Mo bilayer structure thickness was also investigated. [ABSTRACT FROM AUTHOR]

This paper focuses on the simulation and optimization of electrical and optical properties such as current density-voltage (J-V ) , external quantum efficiency (EQE) and the photoluminescence spectra (PL) of InSb/GaAs quantum dot solar cell (QDSC). The InSb QDs have been inserted in the intrinsic region of p-i-n GaAs solar cell. Our results have been shown that 30 InSb/GaAs QD layers provide a relative enhancement of 22.35% and 29.30% of the short-circuit current and the efficiency, respectively. With the same number of the QD layers, the absorption range edge of low energy photons has been extended from 900 to 1400 nm. The electrical features obtained for InSb/GaAs QDSC have been compared with those obtained for InAs/GaAs QDSC in goal to show the better structure. The PL spectra has been also compared with experimental result for the same structure. Moreover, the QDSC has been optimized with respect to the thickness of QDs. The optimal conversion efficiency of 10 QD layers is improved from 14.85% to 18.30% by increasing the thickness of the QDs from 5 nm to 20 nm. [ABSTRACT FROM AUTHOR]

In this work, the performance of solar cell based on CdS-n/Cu 2 ZnSnS 4 -p hetero-junction is numerically simulated. The aim of the study is to investigate the influence of thickness, defects density and bandgap energy of absorber layer CZTS and the thickness of the buffer layer CdS of the solar cell on electrical parameters J sc , V oc , FF and efficiency η of the cell. The results of our simulation allowed us to optimize the parameters above mentioned in order to get the best efficiency at the optimal band gap which corresponds to the maximum of the solar spectrum with optimal values of the electrical performances of the cell. This results lead to develop CZTS solar cells with high efficiency and low cost and give a help full indication for fabrication process. [ABSTRACT FROM AUTHOR]

This work deals with the modeling and optimization of the CuInGaSe/CdS based structure for photovoltaic applications. We took into consideration the effect of the gallium concentration and the temperature on the strain, band gap energy, absorption and efficiency of the structure. It has been demonstrated that increasing the gallium concentration increases the ban gap energy, while increasing temperature decreases it. These two parameters vary the efficiency significantly. For x = 30% and T = 300 K, the band gap energy is equal to 1.15 eV with a deformation of 0.5% and efficiency around 20%. We have also found that at this value of the band gap energy the structure absorbs most of the incident photons. Then to achieve a reliable cell based on CuInGaSe/CdS it is adequate to find a compromise between the gallium concentration in the alloy, the temperature and the strain. [ABSTRACT FROM AUTHOR]

Room temperature deposited aluminium-doped zinc oxide thin films on glass substrate, using pulsed-DC magnetron sputtering, have shown high optical transmittance and low electrical resistivity with high uniformity of its spatial distribution after they were exposed to a rapid thermal annealing process at 400 °C under N 2 H 2 atmosphere. It is particularly interesting to note that such an annealing process of AZO thin films for only 30 s was sufficient, on one hand to improve their optical transmittance from 73% to 86%, on the other hand to both decrease their resistivity from 1.7 × 10 −3 Ω cm to 5.1 × 10 −4 Ω cm and achieve the highest uniformity spatial distribution. To understand the mechanisms behind such improvements of the optoelectronic properties, electrical, optical, structural and morphological changes as a function of annealing time have been investigated by using hall measurement, UV–visible spectrometry, X-ray diffraction and scanning electron microscope imaging, respectively. [ABSTRACT FROM AUTHOR]

In this paper, the CuInGaSe 2 based solar cell optimization has been established. We have simulated the structural strain effect. The effect of gallium concentration on the optical properties and the quantum external efficiency EQE was investigated. We also optimized the concentration x at low defect densities. The optimal gallium concentration is 0.30. We obtained an efficiency of the CuIn 0.70 Ga 0.30 Se 2 absorber solar cell around 24% with a strain ɛ = 0.64% and material defects densities equal to 1.2x1015cm−3. This work has been validated by theoretical and experimental studies. This study allows us to find a compromise between concentration x and defect concentrations in order to improve the performance and high efficiency of the solar cell. • The effect of structural deformation has been studied and simulated. • The effect of gallium on the optical properties and EQE was investigated. • We optimized the x concentration at low defect concentrations. • An efficiency of the solar cell which is equal to 24% with ɛ = 0.6% was obtained. • This work is validated by a theoretical and experimental study. [ABSTRACT FROM AUTHOR]

This study aims to investigate the different optical properties of the ZnSnN 2 absorber layer such as absorption, reflection and transmission coefficients. The effects of the ZnSnN 2 absorber layer thickness, temperature,and defect density on electrical parameters such as short circuit current density, open circuit voltage, fill factor and efficiency have also been studied in detail. These factors play an important role in the performance of the ZnO/CdS/ZnSnN 2 /Si/Mo structure. The highest efficiency of about 23.32 % is achieved without defects in the ZnSnN 2 absorber layer, under the 1-sun AM1.5 solar spectrum, by applying the flat band condition and considering the strain values of 0.37 % (ZnSnN 2 /Cds) and 7.17 % (ZnSnN 2 /Si). In addition to high efficiency, the ZnSnN 2 has a high absorption coefficient. This device will play a crucial role in optoelectronic applications. This structure is a promising candidate for low cost and high efficiency photovoltaic technology. [ABSTRACT FROM AUTHOR]

A combination of a Copper Indium Gallium Selenide (CIGS) and Silicon (Si) layer has been recognized as an excellent choice for producing heterojunction based solar cells with improved efficiency and low cost processing techniques. The quaternary compound CIGS and silicon (Si) regions exhibit a lattice mismatch of about 5%, which induces a strain and impacts the electronic characteristics of the CIGS/Si heterojunction solar cell. A new viewpoint suggests the integration of a silicon germanium (Si 1-y Ge y) layer in the CIGS/Si region to reduce the impact of lattice mismatch. The objective of this study is to investigate how different gallium and germanium concentrations (x Ga and y Ge) affect the following factors: lattice mismatch (ε) , critical thickness (h c) and absorption coefficient (α)of CIGS/SiGe based solar cells. It also aims to analyze how these concentrations impact the primary parameters used to evaluate solar cell performance such as external quantum efficiency, short circuit current density, fill factor, open circuit voltage and conversion efficiency. The simulation results agree well with the existing theoretical and experimental literature data, confirming the suitability of the physical characteristics employed in this numerical study. By tuning the concentrations of Gallium and Germanium, it is feasible to attain an efficiency of 24% owing to the lattice compensation phenomenon in Si 1-y Ge y layers. These findings hold significant implications for the development and advancement of solar cell technology, as well as for enhancing their conversion efficiency and commercialization. • A strain-compensated CIGS/Si structure was achieved by adding SiGe layer. • The incorporation of SiGe improves the absorbance and EQE of the CIGS solar cell. • The improvement of the solar performances of the CIGS is ensured by the SiGe layer. • Optimizing Ga, Ge concentrations makes it possible to achieve an efficiency of 24%. [ABSTRACT FROM AUTHOR]

In this work we propose a modeling and simulation of core/shell p-i-n Si/Si 0.2 Ge 0.8 nanowire for photovoltaic. In the first step of this work, we have compared the core/shell p-i-n homojunction Si and heterojunction Si/Si 0.2 Ge 0.8 Nanowire (NW) solar cell having a length of 3 μm and a radius of 0.19 μm, by studying their current-voltage and external quantum efficiency (EQE). Our results have shown that blending Silicon with 80% of Germanium enhances relatively the short circuit current and efficiency by 3.04% and 8.48% respectively. In other hand, the absorption edge of Silicon NW has extended from 1100 nm to 1200 nm, with a gain of EQE of 15% obtained in this range. In the second part, we have tried to optimize the Si/Si 0.2 Ge 0.8 structure, by varying their radius and length. The corresponding results have indicated that a radius of 0.28 μm and a length of 10 μm are the optimal geometric parameters for any optimization of such structure. [ABSTRACT FROM AUTHOR]

The electrical properties of InAsP/Si quantum dot solar cell (QDSC) are numerically studied and analyzed in this paper. Many effects like number of quantum dot (QD) layers inserted and Arsenic content of InAs x P 1-x on photovoltaic properties such as current density-voltage J-V and the external quantum efficiency (EQE) are investigated. Our results have been shown that the optimal Arsenic content is 0.6. With 30 InAsP/Si QDs layers, relative enhancements of about 7% and 6.70% of short-circuit current and efficiency are achieved, respectively. Otherwise, the absorption range edge of low energy photons was extended from 1120 to 1200 nm. This reveals that introduction of QDs in the intrinsic region of p -i- n Silicon (Si) solar cell enhances significantly the device characteristics beyond what has been reported for conventional semiconductor-based solar cells. [ABSTRACT FROM AUTHOR]

In this investigation, the mechanical properties of the different layers composing a CuIn 1 − x Ga x Se 2 (CIGS) based solar cell were studied. Magnetron sputtering technique was used for the deposition of these layers except for the cadmium sulphide (CdS) layer which was deposited using chemical bath deposition process. We performed several indentation tests on the individual layers, i.e. molybdenum (Mo) back contact layer, CIGS absorber layer, CdS and alternative zinc sulphide oxide (ZnOS) buffer layers, and zinc oxide (ZnO)-AZO (aluminium-doped zinc oxide) transparent window layer; all were deposited on glass substrates. We report the values of the hardness ( H ) and of the Young's modulus ( E ) for each material, using indentation tests and an analytical model. The Mo layer remained the hardest and the most rigid, with H = 8.7 GPa and E = 185 GPa, while the CIGS layer has shown poor mechanical properties with H = 3 GPa and E = 58 GPa. On the other hand, the observed similarity in mechanical properties of the ZnO and ZnOS layers might be attributed to the similarity of their microstructures. [ABSTRACT FROM AUTHOR]

In recent years, the development of quantum well solar cells QWSCs (Quantum Well Solar Cells) has generated a great deal of interest. These configurations have shown good promise to optimize the low conversion efficiency of conventional solar cells because of the high rate of absorption losses present in them. In this work, we are interested in modeling and simulation of two different structures of solar cells, a simple solar cell based on silicon Si and a quantum well solar cell SiGe/Si. When a solar cell is compared to 80 quantum well layers of Si 0.8 Ge 0.2 with a pin solar cell based on Si. The short circuit current J sc increases from 23.55 to 37.48 mA/cm 2 with a relative increase of 59.15% found. In addition, the limit of the absorption band of the lower energy photons extends from 1100 nm to 2000 nm. [ABSTRACT FROM AUTHOR]

In this aim, we were interested in the optimization and simulation of pin-In 1−x Ga x N structure and InGaN multi quantum well structures for photovoltaic applications. This ternary alloy which is an III–V semiconductor presents important characteristics especially its gap energy, thus, the increase of the photons absorption of wavelengths. It has been shown that the increase in indium concentration increases the current density J sc and the maximum output power. In return, the V oc decreases consequently. For In 0.50 Ga 0.50 N structure we observed that the current density and the maximum power are respectively around 19.50 mA/cm 2 and 27.50 mW/cm 2 with a ratio of 21.65 mA/cm 2 . Also it is shown that the incorporation of the quantum well in the active region results in an increase of J sc and P max but V oc remains unchanged. The incorporation of 50 quantum well structure in the In 0.50 Ga 0.50 N gives 22 mA/cm 2 of the current density and 32 mW/cm 2 of the maximum output power. The use of the structure based on In 0.50 Ga 0.50 N (MQW) induces an efficiency of 32%. We deduced that the relative efficiency is improved by 10.9%. [ABSTRACT FROM AUTHOR]

This paper proposes a method of modeling and simulation of InAs/GaAs-based quantum dots (QDs) for solar cell. The main objective is to find the growth parameters in order to produce an optimal double heterostructure using two semiconductor materials InAs and GaAs. We are interested in particular on the impact of the growth control parameters on the physical properties of the two-dimensional InAs mono-layer. We report here a complete but non-exhaustive analysis of the electronic states of the InAs based QDs layers grown on a GaAs substrate. In this work, the reader will find the modeling and the simulation results for both rectangular and elliptical geometries of InAs QDs. In the first part of this work, we provided the change of the electronic transition energy as a function of quantum dots’ radius whilst the second one concerns the absorption coefficient as a function of the incident photon wavelength. The curves we have obtained indicate clearly that the geometrical shape of the InAs QDs does significantly modify the various parameters above. We could therefore confirm that the more appropriate geometry is the elliptical one because of the higher performances. [ABSTRACT FROM AUTHOR]

In this study, we experimentally elaborated Copper- and Indium-doped Zinc Oxide (Cu: ZnO and In: ZnO) thin films at different temperatures (T 1 = 480 °C and T 2 = 520 °C), the doping ratio were varied between 0% and 8%. Using a low cost solution-based chemical deposition, we have developed a ZnO thin film deposition process that offers fine-control of the surface morphology. It consists in spraying a volatile compound of the material to be deposited on a substrate maintained at high temperature to cause a chemical reaction in order to form at least one solid product. Therefore, the proposed ZnO doped layer is highly promising for applications for the next-generation solar cells. [ABSTRACT FROM AUTHOR]

Although solar cells operate under illumination, most electrical characterization methods are carried out in darkness, which implies some bias. In this work, we study the influence of light on the contact resistivity of the electron and hole contacts of a silicon heterojunction (SHJ) cell using the transfer length method (TLM) method in order to determine them in conditions representative of an operating solar cell at maximum power point. A specific fabrication process has been developed to preserve the passivation level. Therefore, we first focus on the patterning approach used for processing, and show that we can fabricate TLM samples with good passivation properties. Using simulations, we also discuss on the influence of inhomogeneities in the excess minority carrier spatial concentration on the TLM analysis. These inhomogeneities, due to shading, local damages in the passivation or to carrier drift under bias voltage make the measurement complicated to carry out without significant error. Our results suggest that the measurement is more precise in darkness and at very high injection levels, under rear illumination and a low voltage bias. • TLM samples for ρ C (e-) and ρ C (h+) measurement in SHJ cells can be fabricated while maintaining good passivation properties. • TLM measurements are carried out under illumination in order to probe ρ C (e-) and ρ C (h+) under operating conditions. • ρ C is influenced by the excess minority carrier density: it should preferably be extracted under operating conditions. • A meaningful characterization requires a good and homogeneous passivation across the TLM sample, minimal shading and low voltage bias. • Our simulations suggest a moderate impact of light on ρ C (e-) for standard c-Si doping levels. [ABSTRACT FROM AUTHOR]