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This scientific work is dedicated to the research of the topical issue of the procedure and time of acquisition of the right of ownership in the case of acquiring a thing by purchasing it from an unauthorized seller. Such cases are not uncommon in property circulation in society, but without proper legal regulation of their mechanisms and consequences, a significant part of things will be withdrawn from property circulation. Of course, a certain role is played here by the revived institution of acquisitive prescription, but also important importance is attached to the tools of obtaining ownership at the time of occupation of the thing in accordance with the mechanism of Art. 330 of the Central Committee of Ukraine. However, this article is in significant conflict with Art. 388 of the Civil Code of Ukraine, which regulates the procedure and grounds for vindication protection of property, which is a shortcoming of the current legislation. Therefore, the work analyzes theoretical developments in the commented direction and compares them with the practical course of concrete relations when a bona fide purchaser receives an item from a person who was not supposed to alienate the property, but did so voluntarily or involuntarily. Doctrinal approaches to the consequences of such an occupation have been studied. It was established that the good faith of the illegal expropriator does not matter, the legal consequences of such a transaction are determined based on the identity of the acquirer. If he is in good faith, which is presumed, then the acquisition of the right of ownership by acquisitive prescription can occur for a person in good faith only in the case when he owns a thing that was lost, stolen or otherwise removed from authorized subjects. In all other cases, the property is immediately acquired by a bona fide person at the time of receiving the property from an unauthorized seller. However, the author does not support the indicated approach to the acquisition of property at the moment when a bona fide subject receives property from an unauthorized seller, not as a ready- made recipe, but only as a starting material for further theoretical construction. Such work was carried out in this article, specific proposals were made regarding the improvement of the current regulatory framework.

Abstract The development of deposition processes for metal carbide thin films is rapidly advancing, driven by their potential for applications including catalysis, batteries, and semiconductor devices. Within this landscape, atomic layer deposition (ALD) offers exceptional conformality, uniformity, and thickness control on spatially complex structures. This paper presents a comprehensive study on the thermal ALD of MoCx with MoCl5 and 1,4‐bis(trimethylgermyl)‐1,4‐dihydropyrazine [(Me3Ge)2DHP] as precursors, focusing on the functional properties and characterization of the films. The depositions are conducted at 200–300 °C and very smooth films with RMS Rq ≈0.3–0.6 nm on Si, TiN, and HfO2 substrates are obtained. The process has a high growth rate of 1.5 Å cycle−1 and the films appear to be continuous already after 5 cycles. The films are conductive even at thicknesses below 5 nm, and films above 18 nm exhibit superconductivity up to 4.4 K. In lieu of suitable references, Raman modes for molybdenum carbides and nitrides are calculated and X‐ray diffraction and X‐ray photoelectron spectroscopy are used for phase analysis.

Background: Recent attempts to rekindle the decolonisation of education project in South Africa, is a reaction to perceptions that there are fundamental frailties in the existing curriculum. Childhood education is yet to take up the challenge in any substantive way. Aim: To explore the insights critical posthumanism might offer in attempting to address a comprehensive decolonial effort in early childhood education transformational initiatives. Setting: This essay is framed within the context of curriculum decolonisation and transformation work in early childhood education. Methods: This experimental think-piece, attempts to theorise early childhood education alongside critical posthumanism. Results: Staying true to posthuman ways of thinking, doing and becoming, we deliberately avoided presenting any determinist, neatly packaged ‘results’, in order to further open up the debate to include alternative ways of thinking and doing curriculum work in early childhood ecologies. Conclusions: Early childhood transformation initiatives, has to recognise the fundamental embeddedness of the existing school subjects in Western-Eurocentric humanist tradition. The effects of this canonical orientation are, that the tenets of Western-Eurocentrism remain unchallenged, that a racialised colonial education prevails in contemporary times, and that the centering of the adult human at the expense of the more-than-human, including child, is sustained. The nature-culture and child or adult dualisms prevail and, a consolidation of a deficit, sub-human construction of children, as immature, fragile and innocent. Critical Posthumanism suggests thinking anew. Contribution: An interrogation of the assumptions on which contemporary childhood education is based, and consideration for the advancement of posthumanist ways of thinking, doing, and becoming.

The in vitro demineralization of bone tissue is used for simulating the osteoporosis related bone loss. This way would be helpful in observations of bone apatite dissolution in microstructural level and may give significant input for understanding crystal-chemistry of bone resorption. In the case of cortical bone, demineralization occurs inhomogeneously, with the formation of a superficial demineralized layer and a transition zone with a gradient of concentration and structural characteristics perpendicular to the reaction advance front. Changes in the microstructural parameters of the bone mineral in this interface zone are of great interest for understanding the resorptive processes in the bone associated with osteoporosis. In this work, the SEM-EDX method was used to estimate the sizes of the demineralized and interface layers in the cortical bone during stepwise demineralization in HCl water solution; the general patterns of changes in the concentrations of Ca, P, and Cl in these layers were established. The calculations of the effective penetration depth of X-rays in diffraction mode for the intact and partially demineralized cortical bone were performed. It is shown that the use of CoKα radiation (instead of the usual CuKα) ensures the depth of probing within the interface zone, which allows to adequately assess the microstructural parameters (crystallite sizes and lattice microdeformations) of altered bioapatite in the zone of its interaction with an acid agent. A nonmonotonic change in the average size of crystallites and microdeformations of the apatite lattice was revealed during acid demineralization of the bone. Using asymmetric XRD geometry, the evidence was obtained that the affected mineral of the transition zone does not contain other crystalline phases except for weakly crystallized apatite. For the first time, the depth-controlled XRD analysis was applied to such a complex (surface-gradient) object as partially demineralized cortical bone. Additionally, we propose a rapid, averaging, and non-destructive method for estimating the depth of the reaction front dividing the demineralized and non-demineralized portions of the bone by XRD. The consistency of XRD and SEM-EDX data on the thickness values of the demineralized layer is shown.

Murris, K. 2022. Karen Barad as Educator: Agential Realism and Education. Singapore: Springer Nature Singapore Ptd Ltd.

The time series of GNSS coordinates contain signals caused by the age-related movement of tectonic plates, the deformation of the Earth’s surface, as well as errors at different time scales from sub-daily tidal deformation to the long-term deformation of the surface load. Depending on the nature of the signal, specific approaches are used for both the visual interpretation and pre-processing of time series and their statistical analysis. However, none of the present software analyzes the nature of the residual errors but assumes their random nature and obedience to the classical normal distribution. One of the methods for analyzing the time series of coordinates with residual, unaccounted-for systematic errors is the non-classical error theory of measurements. The result of this work is a developed software solution for analyzing the time series of GNSS coordinates to test their normality, or in other words, to test whether a particular GNSS station is subject to the influence of small, unaccounted-for errors. Conclusions: After testing our software on four reference stations in Europe, we concluded that none of the chosen stations followed the normal law of distribution; thus, it is vital to perform such tests before conducting any experiments on the time series from reference stations.

Measurement(s) forest management type Technology Type(s) Geo-Wiki toolbox

Active-adaptive system of electric power system (EPS) modes control, using its ideal ("economic") mode is suggested. The process of optimal control is constructed in such a manner that EPS current mode by means of control facilities approaches to "economic" mode. Direction, change of EPS current mode parameters are realized for its improvement and they are determined according to the least action principle (LAP). System of automatic control performs optimization actions in the direction, set by LAP, changing parameters of regulation facilities and controlls limitations of EPS mode parameters. [ABSTRACT FROM AUTHOR]

The velocities of tectonic plates derived from GNSS time series are regularly used as input data for geophysical models. However, as shown by numerous researches, the coordinates time series contain residual errors of a systematic nature, which can significantly affect the reliability of the obtained velocity estimates. This research shows that using non-classical error theory of measurement (NETM) for processing GNSS time series allows detecting the presence of weak, not removed from GNSS processing, sources of systematic errors. Based on the coordinate time series of selected permanent GNSS stations in Europe, we checked the empirical distributions of errors by the NETM on G. Jeffries' recommendations and on the principles of the theory of hypothesis tests according to Pearson's criterion. It is established that the obtained coordinates time series of GNSS-stations only partially confirm the hypothesis of their conformity to the normal Gaussian distribution law, and this may be the main reason for their unrepresentative classification. In the future, it is necessary to identify and take into account the causes of residual errors that distort the real distribution of the results of the GNSS time series.

Purpose: verification of the effectiveness of training future masters in physical culture and sports for professional activity in a fitness center. Material and methods: questioning, testing; pedagogical experiment; statistical methods, factor analysis. The study involved 34 applicants for the second (master’s) level of higher education 1-2 years of study, educational and professional program (EPP) «Physical culture and sports», specialty 017 «Physical culture and sports». In order to determine the effectiveness of training future masters in physical culture and sports for professional activity in a fitness center, a survey was carried out of applicants for the second (master’s) level of higher education; the levels of readiness formation of future masters in physical culture and sports for professional activity in a fitness center. Results: after the completion of the formative stage of the pedagogical experiment, the indicators characterizing a high level of readiness for professional activity in a fitness center increased among applicants in the control group from 7,34% to 11,20%, among applicants in the experimental group from 8,44% to 24,12%. Accordingly, the data characterizing a sufficient level of readiness for professional activity has changed - in the control group from 44,47% to 52,55%, in the experimental group from 49,31% to 68,22%. The data characterizing the elemental level of formation of readiness for professional activity decreased in the control group from 48,19% to 36.25%, in the experimental groups from 42,25% to 7,66%. At the end of the pedagogical experiment, the most significant structural components of readiness were the motivational component; cognitive-reflexive component; personality and activity component. Conclusions: the effectiveness of training future masters in physical culture and sports for professional activity in a fitness center has been determined and tested; the structure of training future masters in physical culture and sports for professional activity in a fitness center has been improved; the provisions for the development and design of the content of the physical culture and sports for the preparation of future masters of physical culture and sports have been improved; the criteria and levels of the readiness formation of future masters in physical culture and sports for professional activity in the conditions of a fitness center.

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Copyright of Przegląd Elektrotechniczny is the property of Przeglad Elektrotechniczny and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Introduction and aim. The problem of constructing a training process for highly skilled players at the special preparation phase is not researched well enough. The special preparation phase should involve the specificity of the competition calendar, development of the structure and content of the corresponding types of micro cycles, and scientifically based selection of methods of training. The aim of the research is to analyze the structure and content of the training process of highly skilled football players during the special preparation phase of the preparation period at the first macrocycle of the annual cycle. Materials and methods. 22 highly skilled football players of Kamianets-Podіlskyi National Ivan Ohiienko University aged 18-23 participated in the research. All of them are MA students and elite athletes. Methods of analysis of scientific literature, pedagogical observation, timing of training work, and mathematical statistics were used in the research. Results and conclusions. The special preparation phase consists of two mesocycles. The basic stabilizing (control and preparation) mesocycle - the volume and intensity of training sessions - was characterized by the widespread use of special-training exercises. In comparison with previous mesocycles, considerably more trainings were devoted to technical, tactical and game preparation. Technical and tactical training was carried out in the form of adaptive training exercises along with special physical training. Pre-competition mesocycle rolled up the preparation of the athletes for the competition period. The reparation in this mesocycle had an expressed “integral” character. In this mesocycle, one should not forget about maintaining the level of special physical fitness. Maintaining it throughout the mesocycle is one of the important prerequisites for the steady growth of athletes’ physical state, but the composition of the means significantly changed by increasing the proportion of special technical and tactical exercises being held. In this mesocycle, the largest number of control games, starts, competitions, etc. were carried out. A special place in pre-competition mesocycle was taken by tactical and psychological training. The proportion of theoretical training also increased.

An experimental study of the magnetocaloric effect in tetraaquabis(hydrogen maleato)nickel(II), [Ni(C4H3O4)2(H2O)4] powder sample is presented. The magnetocaloric properties of the studied sample were investigated using specific heat and magnetization measurements in magnetic fields up to 9 T in the temperature range from 0.4 to 50 K. A large conventional magnetocaloric effect was found at a temperature of about 3.5 K, where −ΔSM = 8.5 Jkg−1K−1 and 11.2 Jkg−1K−1 for a magnetic field of 5 T and 7 T, respectively. Assuming a substantial role of the crystal field, the temperature dependence of the magnetic specific heat in a zero magnetic field was compared with an S = 1 model with single-ion anisotropy parameters D and E (axial and rhombic). The best agreement was found for the parameters D/kB = −7.82 K and E/kB = −2.15 K. On the other hand, the experimental temperature dependence of −ΔSM shows higher values compared to the theoretical prediction for the mentioned model, indicating the presence of additional factors in the system, such as an exchange interaction between magnetic ions. The first exchange pathway can be realized through maleic rings between the nearest Ni(II) ions. The second exchange pathway can be realized through water molecules approximately along the a crystallographic axis. Broken-symmetry DFT calculations performed using the computational package ORCA provided the values of ferromagnetic exchange interactions, J1/kB = 1.50 K and J2/kB = 1.44 K (using B3LYP functional). The presence of such ferromagnetic correlations in the studied system may explain the enhanced magnetocaloric effect compared with the model of an anisotropic spin-1 paramagnet.

У статті досліджено випадки пограбування жертв Голокосту у трьох невеликих містечках Західної Волині: Дубровиці, Корці й Костополі. Такі дії, окрім фінансування німецької мілітарної машини та збагачення німців, слугували легітимації геноциду й серед місцевого населення, його заохоченню до колаборації. На поведінку частини населення під час організації злочину в Костополі, Корці та Дубровиці впливали економічні чинники. Вже на початковому етапі Голокосту мешканці цих містечок долучилися до грабунку єврейських сусідів під час погромницьких акцій наприкінці червня – на початку липня 1941 р. У процесі створення гетто відбувалися стихійні пограбування помешкань жертв і «легалізована» нацистською окупаційною владою торгівля їхнім майном (переважно одягом і побутовими речами). У період існування гетто в Костополі, Дубровиці та Корці тутешнє населення (переважно селяни) активно долучилося до нерівноцінних торгових обмінів із єврейськими бранцями. В обмін на одяг, взуття, прикраси та гроші селяни приносили євреям їжу. Коли кошти закінчувалися, євреї пропонували свою працю в обмін на їжу. Таку взаємодію значно легше було організувати бранцям гетто відкритого типу в Корці та Дубровиці. Голод у гетто був найстрашнішим тоді, коли в мешканців закінчувалися цінні речі, за які можна було вимінювати продовольство, а селяни втрачали інтерес надалі приносити їжу. На етапі знищення гетто в усіх трьох містечках відбувалися стихійні пограбування будинків убитих євреїв. Після ліквідаційних акцій щоразу розпочиналася торгівля єврейським майном (переважно одягом, меблями й нерухомістю). «Легалізовану» нацистською окупаційною владою торгівлю у Дубровиці та Костополі здійснювали працівники міських управ (це були переважно місцеві українці). Найбільшу вигоду мали сусіди євреїв (українці й поляки), що мешкали у цих містах і довколишніх селах. У Корці торгівлю майном убитих євреїв контролювала районна управа, а участь у ній брали переважно місцеві українські селяни. Окрім фізичних осіб, у цьому районі участь у придбанні меблів і будинків жертв Голокосту брали й українські організації (сільські філії товариства «Просвіта», українські школи тощо). Доля тих євреїв, яким вдалося утекти з гетто або місць розстрілів, залежала від ставлення місцевого населення. Мешканці довколишніх сіл по-різному ставилися до жертв, які мусили переховуватися поза межами гетто. Зокрема, селяни і містяни в нечисленних випадках безкорисливо переховували жертв (поведінка рятівників), надавали прихисток або їжу, допомагали євреям з метою отримання якихось зиску (використання жертв Голокосту як робочої сили, нерівноцінні обміни їжі на матеріальні цінності), переховували за гроші або інші цінності, видавали представникам окупаційної влади жертв в обмін на матеріальну вигоду (яка зазвичай вимірювалася такими дефіцитними у воєнний час товарами, як керосин, спиртні напої, сіль і цукор) і навіть брали активну участь у виявленні місць переховування євреїв як за винагороду, так і незначні кар’єрні преференції. Як засвідчують спогади жертв Голокосту, значна частина українських і польських селян вибудовували різноманітні моделі взаємодії з жертвами Голокосту саме з метою отримати вигоду. В одних випадках це допомагало жертвам вижити (допомога в обмін на матеріальні речі). В інших – призводило до катастрофи. Хай там як, а «праведна» поведінка траплялася значно рідше, ніж та, що була мотивована економічним зиском