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Pulp and paper are gradually transforming from a traditional industry into a new green strategic industry. In parallel, cellulose-derived transparent paper is gaining ground for the development of advanced functional materials for light management with eco-friendly, high performance, and multifunctionality. This review focuses on methods and processes for the preparation of cellulose-derived transparent papers, highlighting the characterization of raw materials linked to responses to different properties, such as optical and mechanical properties. The applications in electronic devices, energy conversion and storage, and eco-friendly packaging are also highlighted with the objective to showcase the untapped potential of cellulose-derived transparent paper, challenging the prevailing notion that paper is merely a daily life product. Finally, the challenges and propose future directions for the development of cellulose-derived transparent paper are identified. [Display omitted] [ABSTRACT FROM AUTHOR]

Sheet-like transition metal sulfides have promising applications in photocatalysis and energy conversion. This study provides a petal-like Cu 2 WS x nanosheet structure supported on carbon paper (CP) synthesized by a simple one-step solvothermal method. Cu 2 WS x microstructures with different morphologies were synthesized by solvothermal vulcanization of thioacetamide (TAA) at different concentrations. The Cu 2 WS x /CP was used as the counter electrode of DSSCs and compared with the Pt FTO electrode. It was proved that Cu 2 WS x -7 M/CP had the best electrocatalytic performance and obtained 9.01% photoelectric conversion efficiency. The different sulfide concentration changes the morphology of Cu 2 WS x and continuously affects the specific surface area and catalytic activity of the material. The better electrochemical performance shows that Cu 2 WS x /CP is expected to become a substitute for expensive Pt CE materials in dye-sensitized solar cells (DSSCs). [Display omitted] • One-step solvothermal method for the growth of petal-like Cu 2 WS x on carbon paper. • The effect of sulfide concentration on Cu2WSx was explored for the first time by TAA. • For the first time, Cu 2 WS x /CP was used as a counter electrode for DSSCs. • At a sulfide concentration of 7 M, Cu 2 WS x /CP exhibited a value of 9.01% PCE (Pt 7.67%). [ABSTRACT FROM AUTHOR]

In an era of modern smart technology, flexible electrodes are of great interest for different energy conversion as well as energy storage applications like solar cells, all solid-state batteries, and supercapacitors. Flexible metal oxide-based paper electrodes are advantageous in comparison to conventional electrodes due to their economical synthesis, biocompatibility, and environment-friendly characteristics. However, the electrical conductivity of paper electrodes is limited because of the insulating nature of natural fibers employed as a binder for the flexible matrix of metal oxides. The current study is an attempt to tune the electrical properties of lignocelluloses (natural fibers) and titanium dioxide (TiO 2) based paper electrodes by facile electrodeposition technique. The crystalline parts (e.g., TiO 2 , Ag, and Au) of the prepared composite sheets were characterized by XRD analysis while the surface morphology was studied by SEM. FTIR was used to characterize the organic matter in LC fibers by identifying various molecular stretching and vibrational modes of C, H, and O-containing molecules. Electric permittivity was measured as a function of electric field frequency at room temperature which revealed the value of 23. 5 (at 1 kHz) for the sample LC/TiO 2 /Ag 9000s indicating the best charge storing capability of the sample. Impedance analysis was employed to identify various charge carrier mechanisms active in the sheets. It was found through impedance analysis that there is an active diffusion-controlled impedance mechanism of Au-coated samples causing an increased conductivity via the ionic diffusion. This diffusion-controlled conduction was modeled by the Warburg element. The enhanced conductivity due to ionic diffusion makes these samples more useful as electrodes. Cyclic voltammetry (CV) measurements of the electrodeposited samples established the increase in conductive properties and efficient kinetics of LC/TiO 2 paper sheets. The current study suggests that Ag and Au-coated paper electrodes can be potential candidates for energy conversion and storage applications. [ABSTRACT FROM AUTHOR]

A general mathematical model is developed for electrochemical energy conversion in paper-based, capillary-driven, microfluidic flow cells. A two-dimensional version of the model is implemented to simulate a novel flow cell of this kind called PowerPAD. The methodology developed is validated against experimental data for this particular cell under both steady and unsteady modes of operation. It is shown that a 2D model can represent a 3D cell in unsteady flows provided that the Nernst-Planck equation is properly refined. The results are interpreted in terms of transient back-diffusion and crossover of the reactant species which are found to be the key factors controlling the electrochemical performance of this cell. The validated model is used to enhance the power output, runtime, and energy efficiency of this particular cell through altering its flow architecture and microstructure of electrodes and absorbent pad. The refined cell design is shown to roughly triple the power output and runtime of the device. The optimized design also outperforms the original design in terms of energy efficiency. The developed mathematical model, the fundamental understanding, and the proposed cell design may be utilized to develop new devices and concepts for capillary-based electrochemical systems, including biodegradable batteries, fuel cells, and electrolyzers. [Display omitted] • A dynamic mathematical model is developed for paper-based microfluidic flow cells. • A 2D model can represent a 3D cell subject to Nernst-Planck equation refinement. • The model reveals the unique working mechanism of imbibition and back-diffusion. • Crossover is identified as the key limiting factor for cell performance and runtime. • An optimized cell design is proposed with 3x performance improvement. [ABSTRACT FROM AUTHOR]

Clean energy devices have a great ability to change the world because they strengthen the economy and preserve society. The continuous improvement and progress in nanomaterials and nanotechnology have a great role in human life. The increasing prevalence of PEM fuel cells makes them one of the most viable sustainable energy sources. Nanostructured materials synthesis methodologies have introduced a breakthrough and found to overcome the obstacles for PEMFC commercialization. Amongst them, wet chemical approaches are rapidly expanding and beneficial for the fabrication of nanoparticles since they contribute toward the attainment of a range of essential nanoparticle characteristics like sizes, morphologies, structures, and phases. Wet chemical manufacturing enables fine-tuning of reaction parameters to generate the desired nanomaterials. This review article focuses on the latest improvements in wet chemical methods to better regulate the quality of nanomaterials. This paper examines how wet chemical approaches (hydrothermal synthesis, spray pyrolysis, sol-gel processing, and co-precipitate synthesis, among others) can contribute to the scalable manufacturing of nanoparticles to uphold rising industrial requirements. And how wet chemical methods have a significant influence on power generation systems (Fuel cells) along with their pros and cons. This review carefully analyzes and summarizes synthetic methods and optimized factors in order to prepare nanoparticles and carefully analyzes the reported data. In this paper, the electrochemical analysis, morphological evaluation, compositional analysis, and performance testing of materials produced using wet chemical techniques have been investigated. Recent signs of progress and innovative techniques used to overcome the complexities of synthetic nanoparticle processing. This article is a holistic approach including social, economic, and ecological aspects in the wet chemical process and will certainly help in the fabrication, and application of nanoparticles for PEM Fuel cells. [Display omitted] • Introduction to the status of materials synthesis in energy generating devices. • Overview of wet chemistry Approaches for PEMFC. • Impact of synthesis parameters on properties of materials. • Pros and Cons of wet chemistry techniques for material synthesis. [ABSTRACT FROM AUTHOR]

In the field of research on renewable energy conversion and storage methods, the development of catalysts with excellent properties and outstanding stability for oxygen evolution reaction (OER) acting at various pH values has become a much-anticipated research focus. RuO 2 as a benchmark OER catalyst, its wide application has always been limited by slow reaction kinetics and limited persistence. In this paper, Mn-doped RuO 2 material was developed and the optimum doping ratio was identified for using as an OER electrocatalyst under general purpose pH media. Mn 0.1 Ru 0.9 O 2 exhibited a lower overpotential value of 224 mV in acidic environment with a Tafel slope value of 51.62 mV dec−1. Moreover, in alkaline and neutral environments, overpotentials of 231 mV and 376 mV were required to obtain a current density of 10 mA cm−2, respectively. In addition, through continuous stability testing over 24 h in alkaline, acidic and neutral solutions, it has been further demonstrated that the Mn-doped RuO 2 material exhibits extremely high stability. The advancements in this research offer crucial insight into the rational development of efficient and durable RuO 2 -based catalysts. [Display omitted] • Mn 0.1 Ru 0.9 O 2 is successfully synthesized by a facile sol-gel method. • Mn doping modulates the electronic structure of RuO 2. • The catalyst exhibits enhanced OER activity and stability in pH-Universal media. [ABSTRACT FROM AUTHOR]

With the energy revolution and the proposal of "double carbon" background, hydrogen energy with rich reserves, clean and low carbon and broad application prospects has gradually become a global hot spot. The combination of seawater hydrogen production and offshore wind power is undoubtedly the focus of research in this field. However, this new research field is not yet mature and is still in its infancy, so in order to reduce unnecessary losses, it is crucial to identify the key risks and prevent them. Secondly, the adaptability of a single model is no longer reliable for the risk assessment of this emerging field, especially the conversion from offshore wind to electric energy to hydrogen energy. Based on the above, this paper first considers the ambiguity and uncertainty of information, as well as the risk attitude of decision makers in the evaluation process, and develops a novel evaluation model. The reliability and optimization of the model are verified by sensitivity analysis and comparative analysis, and a case is introduced for practical analysis. The final results show that the key risks of hydrogen production from offshore wind power are seawater electrolysis technology, hydrogen energy storage technology and high-quality wind energy resources. The overall risk is 0.4198, which is medium risk. Decision-making managers can make targeted risk prevention to reduce losses and promote the stable operation of offshore wind power hydrogen production. [Display omitted] • Offshore wind power combined with seawater hydrogen production. • An improved model based on spherical fuzzy theory and cumulative prospect theory. • Taking China 's first large-scale offshore wind power hydrogen production project as a case study. • Key risks: seawater electrolysis technology, hydrogen storage technology and wind energy resources. • The quantitative result of the overall risk assessment was 0.4198. [ABSTRACT FROM AUTHOR]

Vanadium Flow Batteries (VFBs) are a stationary energy storage technology, that can play a pivotal role in the integration of renewable sources into the electrical grid, thanks to unique advantages like power and energy independent sizing, no risk of explosion or fire and extremely long operating life. The first part of this paper presents the main features and the basic performance parameters of VFB, which determine their electric, hydraulic, thermal, and aging feature. The latter part outlines the strengths and weaknesses of the technology, the services that it can provide to the grid, and a short economic analysis. After presenting the fundaments of the technology, prospects and trends of VFBs deployment are outlined. Most of the considerations highlighted in this paper are inspired to studies performed on an industrial-size VFB operated at the Electrochemical Energy Storage and Conversion Lab (EESCoLab) at the University of Padua (Italy). [ABSTRACT FROM AUTHOR]

Electrocatalytic nitrate reduction reaction (NO 3 RR) provides a promising method for ammonia (NH 3) producing. It is urgent to develop efficient catalysts with improved NO 3 RR performance. In this paper, Cu 3 P@Co(OH) 2 /CF heterostructure catalyst is constructed by electrodeposition of cobalt hydroxide (Co(OH) 2) nanosheet on the surface of copper phosphide (Cu 3 P) nanorod, and used as a self-supporting cathode for electrocatalytic reduction of nitrate to ammonia. The NH 3 yield reaches 0.19 mmol h−1 cm−2 at a potential of −0.17 V vs. RHE, and the faraday efficiency (FE) is 86.7 %. The study manifests that the built-in electric field generated at the p-n heterojunction interface optimizes the electron migration kinetics, and promotes the adsorption of nitrate and the convention of intermediate product NO 2 − into ammonia. As a consequence, the selectivity of NH3 is improved. The Zn-nitrate battery is assembled with the designed catalyst as the cathode, to reach a peak power density of 5.16 mW cm−2. The prepared catalyst realizes three effective functions: power output, ammonia synthesis, and nitrate pollutants treatment. [Display omitted] • Cu 3 P@Co(OH) 2 /CF heterostructure material was synthesized by low temperature phosphating and electrodeposition methods. • The built-in electric field at the p-n heterojunction promotes the convention of intermediate NO 2 − into ammonia. • Cu 3 P@Co(OH) 2 /CF effectively promotes the *H pathway for NO 3 − reduction to NH 3. • Zn-nitrate battery was built with Cu 3 P@Co(OH) 2 /CF cathode to realize multi-functional applications. [ABSTRACT FROM AUTHOR]

To alleviate the energy crisis and achieve green energy conversion, the heterojunctions that can be applied to the photocatalytic decomposition of water have attracted attention. In this paper, we design a novel two-dimensional GeC/SnSe 2 heterostructure and investigate in detail the structural stability, electronic characteristics, photocatalytic activity and optical behavior as well as the effects due to the applied strain based on the first-principles. Firstly, the most stable γ-stacking mode is determined by combining energy comparison, thermodynamic and dynamic studies. Second, the analysis of electronic properties demonstrates that the GeC/SnSe 2 heterostructure exhibits a type-II energy band arrangement and a direct Z-scheme photocatalytic mechanism. This pivotal aspect enhances the separation of photogenerated carriers at the interface and facilitates the active participation of the most proficient materials in oxidation-reduction processes during photocatalytic hydrolysis reactions. The hydrolysis reaction's Gibbs free energy shift demonstrates the GeC/SnSe 2 heterostructure's superior photocatalytic activity in neutral and alkaline environments and can spontaneously carry out the overall hydrolysis reaction, and this outstanding ability is not affected by the −4% to 4% strain range. In addition, the GeC/SnSe 2 heterostructure has outstanding solar-to-hydrogen efficiency (58.18%) and excellent light absorption capability (up to 4 × 1 0 5 cm − 1 ) within visible light. The implications of these discoveries point towards the direct Z-scheme GeC/SnSe 2 heterostructure holds promise as an excellent candidate for photocatalytic water splitting applications. Free energy descriptions of the GeC/SnSe 2 heterostructure participating in water splitting (a) hydrogen evolution reaction and (b) oxygen evolution reaction under different conditions. Top and side views of the most stable adsorption sites for (c) H on the GeC layer and (d) OH, (e) O and (f) OOH on the SnSe 2 layer of the GeC/SnSe 2 heterostructure. The H and O atoms are represented by pink and red balls, respectively. [Display omitted] • The GeC/SnSe 2 heterostructure is thermodynamic, dynamic and thermal stable. • The GeC/SnSe 2 heterostructure exhibits direct Z-scheme mechanism and strong redox capacity. • Gibbs free energy diagram of water splitting demonstrates its excellent spontaneous reaction capability. • The GeC/SnSe 2 heterostructure has excellent light absorption capability within visible light. [ABSTRACT FROM AUTHOR]

Achieving low cost at high performance is difficult for direct ammonia microfluidic fuel cell (DAMFC) as a portable clean energy conversion device. In this work, a DAMFC with Ni nanoparticles anode and catalyst-free cathode is proposed to realize low cost and high performance of the fuel cell at room temperature. Due to the uniform distribution and spherical geometry of the Ni nano-catalyst, the Ni anode prepared by cyclic voltammetry owns excellent activity of ammonia oxidation. Meanwhile, sodium persulfate having strong oxidizing properties is selected as the oxidant, resulting in catalyst-free carbon paper by cyclic voltammetry treatment directly used as the cathode to greatly reduce the cost of the DAMFC. By optimizing the electrodeposition conditions of Ni electrode and the operating conditions of fuel cell, the DAMFC achieves optimal performance. The maximum power density is 8.43 mW cm−2 and the limiting current density is 78.58 mA cm−2, which is higher than that of most previously reported low-temperature ammonia fuel cells. Moreover, the fuel cell has good stability. Therefore, it proves that a DAMFC with Ni nanoparticles anode and catalyst-free cathode is an effective method to realize low cost and high performance of the ammonia fuel cell at room temperature. [Display omitted] • A low-cost and high-performance ammonia microfluidic fuel cell is proposed. • The spherical nickel nanoparticle catalyst with uniform dispersion is prepared. • Sodium persulfate with strong oxidizing property is selected as oxidant. • The effect of reactant concentration on cell performance is discussed. • The introduction of sodium persulfate removes noble-metal catalyst and improves cell performance. [ABSTRACT FROM AUTHOR]

Modern energy systems are large distributed systems and, as a rule, contain energy storage systems and, in particular, hydrogen batteries and hydrogen production systems. The use of hydrogen for energy transportation has recently been actively studied in a number of scientific projects. To ensure continuous operation of instrumentation and control equipment on long hydrogen pipelines (gas and cryogenic), it is important to ensure constant autonomous power supply to these systems. This can be solved using micromechanical energy microgeneration systems for the uninterrupted operation of various sensors, which are installed in large numbers on almost all elements of the structure and infrastructure. In addition, an important area of scientific research is the revision of the concepts and appearance of traditional devices of modern renewable energy: windmills, solar cells, turbines, etc. Fundamentally new energy devices are on the agenda, capable of recovering mechanical energy of any power and supplying it to the consumer in the form of a given specific energy flow. Collection of chaotically distributed natural energy of the environment (mechanical energy in the form of: vibrations, acoustic vibrations, wave energy, gusts of wind, tornadoes, precipitation, vibrations of the earth's crust, etc.), as well as collection of dissipated energy from artificial sources (iron and automobile highways, airstrips, spaceports, production facilities, etc.) with the help of mechanical microgenerators will allow the recovery and conversion of mechanical energy of various powers, including low power, into a universal energy carrier - hydrogen. Mechanical vibrations of artificial origin are of particular interest due to their widespread use for domestic and industrial purposes in a wide range of vibrations. The energy of mechanical vibrations can be collected and converted into electrical energy using piezoelectric, electromagnetic, triboelectric or electrostatic (capacitive) energy converters. Electrostatic microelectromechanical energy converters are considered the most promising among other energy converters, since their manufacturing processes are based on standard technology for the production of integrated circuits and microelectromechanical systems. Energy conversion by an electrostatic converter is carried out due to an external mechanical force that does work against the force of attraction of the charged electrodes of a variable capacitor. To transfer the received electrical energy to the load of the consuming device, the electrostatic converter is connected to the corresponding electrical circuits (conditioning circuits). Such a system as a whole is a kind of microgenerator or energy collector. Microenergy flow recovery systems integrated into large energy systems will ensure the collection and recovery of significant amounts of energy for remote energy consumers. At the same time, the concept of a distributed mechanical energy recovery system is quite simple: a mechanical energy receiver - a converter into electrical energy - a preliminary electrical storage device - an energy distributor - an electric energy accumulator - an electrolyser - a hydrogen accumulator - a fuel cell. To optimize the operation of the working circuit, including preliminary electrical systems for energy storage and conversion: capacitors and electric energy accumulators, electrolyzers; To ensure their durability and reliability, flexible automatic control of electrical power distribution is necessary. The real work was done to solve that problem. In addition, for extended and large power facilities it is important to ensure widespread sensory control of system parameters. At the same time, if all sensors receive power from an autonomous energy-generating device, then the costs of creating extended communications for instrumentation will be sharply reduced. In addition, the reliability of the control system will significantly increase. The results of studying operation features of a kinetic microgenerator with reduced output voltage are presented. The performance of a multi-stage modified Bennet doubler is compared to a system including a two-stage modified Bennet doubler and a diode-capacitor voltage divider. It is shown that with an increase of the number of stages in the modified Bennet doubler, the conversion of mechanical energy into electrical energy becomes less and less efficient. At the same time, for achieving the maximum energy accumulation rate (power), a two-stage power amplifier based on the Bennet doubler is preferable. It is established that when analyzing the operation of a diode-capacitor voltage divider, it is necessary to take into account the intrinsic (reverse) capacitances of the discharging diodes affecting the divider operation significantly. The divider behavior features while changing the load resistance and the intrinsic capacitances of the discharge diodes are found and analyzed. Analytical expressions linking the main characteristics of the microgenerator as a whole with the parameters of the electronic components used are derived. It is shown that for expanding the range of the "correct" division of the divider, it is necessary to use discharge diodes with minimal intrinsic capacitances, and also that connecting a load to the Bennet doubler as a voltage divider changes the permissible capacitance modulation depth of the variable capacitor. This paper examines the concepts of creating large energy-generating flows based on arrays of micromechanical energy converters placed on optimal energy-efficient receiving surfaces and analyzes the issues of cryogenic production, storage, consumption and transportation of hydrogen. Stationary and mobile cryogenic storage systems for hydrogen are considered. Much attention is paid to the safety of large cryogenic and gas hydrogen systems. [ABSTRACT FROM AUTHOR]

• A novel system is proposed to utilize LNG cold energy in cascade. • Thermodynamic and economic analyses are carried out for the proposed system. • The system is compared to other systems in the same field for performance evaluation. • The round-trip efficiency of the proposed energy storage system is 138.81 %. For cutting down the energy consumption and improving the cold energy conversion efficiency of the traditional liquefied air energy storage system (LAES), a novel energy system integration solution is proposed by combining the LAES with liquefied natural gas (LNG) regasification process. In this paper, the principal energy storage and energy release processes are simulated by Aspen Hysys. The influences of air mass flow rate and LNG regasification pressure on the performance are analyzed. The results indicate that the introducted system can attain 137.82 % round-trip efficiency, which is about 20 % higher than the conventional LAES system. Besides, the energy capacity reaches up to 10.87 MW and the exergy efficiency is 39.58 % during long-distance transportation. It's noteworthy that the power output in the liquefied air energy discharging period far exceeds the power generation from the organic Rankine cycle. The higher LNG transport pressure, the worse LNG-LAES system performance. When the air mass flow rate raises from 40,000 kg/h to 64,000 kg/h, the exergy efficiency is 3.4 % higher than the original, while the round-trip efficiency decreases by 29.79 %. Finally, through economic viability calculations, the dynamic recovery period of the LNG-LAES system is 5.41 years. [ABSTRACT FROM AUTHOR]

The escalating concern over conventional antibiotic resistance has emphasized the urgency in developing innovative antimicrobial agents. In recent times, metal−organic frameworks (MOFs) have garnered significant attention within the realm of antimicrobial research due to their multifaceted antimicrobial attributes, including the sustained release of intrinsic or exogenous antimicrobial components, chemodynamically catalyzed generation of reactive oxygen species (ROS), and formation of photogenerated ROS. This comprehensive review provides a thorough overview of the synthetic approaches employed in the production of MOF-based materials, elucidating their underlying antimicrobial mechanisms in depth. The focal point lies in elucidating the research advancements across various antimicrobial modalities, encompassing intrinsic component release system, extraneous component release system, auto-catalytical system, and energy conversion system. Additionally, the progress of MOF-based antimicrobial materials in addressing wound infections, osteomyelitis, and periodontitis is meticulously elucidated, culminating in a summary of the challenges and potential opportunities inherent within the realm of antimicrobial applications for MOF-based materials. Growing concerns about conventional antibiotic resistance emphasized the need for alternative antimicrobial solutions. Metal-organic frameworks (MOFs) have gained significant attention in antimicrobial research due to their diverse attributes like sustained antimicrobial components release, catalytic generation of reactive oxygen species (ROS), and photogenerated ROS. This review covers MOF synthesis and their antimicrobial mechanisms. It explores advancements in intrinsic and extraneous component release, auto-catalysis, and energy conversion systems. The paper also discusses MOF-based materials' progress in addressing wound infections, osteomyelitis, and periodontitis, along with existing challenges and opportunities. Given the lack of related reviews, our findings hold promise for future MOF applications in antibacterial research, making it relevant to your journal's readership. [Display omitted] [ABSTRACT FROM AUTHOR]

Multigenerational energy conversion plants are one of the most promising solutions for tackling environmental challenges and making efficient use of energy sources. In this regard, a newly designed multigeneration plant integrated with a methane-based Brayton cycle, a steam Rankine cycle, a supercritical CO 2 -based Brayton cycle, a multi-effect desalination process, a PEM unit, a domestic water heater process, and two thermoelectric generators is integrated, proposed and analyzed. The thermodynamic and environmental assessments of the developed paper are conducted and examined with energy and exergy efficiencies as well as CO 2 emission rate. Similarly, a parametric study is executed and reported, by the way, to define the impact of the various significant factors on the developed plant's efficiency. In the end, the CO 2 emission rate is determined and compared according to different energy conversion plants. In light of the analysis results, the net power, hydrogen, and freshwater production capacities of the reference study are calculated to be 1336 kW, 0.002004 kgs−1, and 0.954 kgs−1, respectively. Additionally, it is found that the developed study's energetic and exergetic performances are 55.76% and 52.17%. According to emission analysis results, the multigeneration system emits 272.2 k g / M W h less CO 2 emissions than the single energy conversion system. • A newly designed multigeneration plant is suggested. • Combination of a superciritical CO 2 based Brayton cycle is proposed. • Thermodynamic and environmental analysis of the multigeneration plant is conducted. • Freshwater, hydrogen, power and heating purposes are fulfilled. • The overall energy and exergy efficiencies are 55.76% and 52.17%, respectively. [ABSTRACT FROM AUTHOR]

This paper presents a novel energy management strategy (EMS) to control a wind-hydrogen microgrid which includes a wind turbine paired with a hydrogen-based energy storage system (HESS), i.e., hydrogen production, storage and re-electrification facilities, and a local load. This complies with the mini-grid use case as per the IEA-HIA Task 24 Final Report, where three different use cases and configurations of wind farms paired with HESS are proposed in order to promote the integration of wind energy into the grid. Hydrogen production surpluses by wind generation are stored and used to provide a demand-side management solution for energy supply to the local and contractual loads, both in the grid-islanded and connected modes, with corresponding different control objectives. The EMS is based on a hierarchical model predictive control (MPC) in which long-term and short-term operations are addressed. The long-term operations are managed by a high-level MPC, in which power production by wind generation and load demand forecasts are considered in combination with day-ahead market participation. Accordingly, the hydrogen production and re-electrification are scheduled so as to jointly track the load demand, maximize the revenue through electricity market participation and minimize the HESS operating costs. Instead, the management of the short-term operations is entrusted to a low-level MPC, which compensates for any deviations of the actual conditions from the forecasts and refines the power production so as to address the real-time market participation and the short time-scale equipment dynamics and constraints. Both levels also take into account operation requirements and devices' operating ranges through appropriate constraints. The mathematical modeling relies on the mixed-logic dynamic (MLD) framework so that the various logic states and corresponding continuous dynamics of the HESS are considered. This results in a mixed-integer linear program which is solved numerically. The effectiveness of the controller is analyzed by simulations which are carried out using wind forecasts and spot prices of a wind farm in center-south of Italy. • Design of control algorithms for islanded and grid-connected microgrids. • Development of hierarchical MPCs to target long-term and short-term operations. • Tracking the load demand and maximizing the revenue via electricity markets. • Minimization of the HESS operational costs. [ABSTRACT FROM AUTHOR]

At present, energy shortage and environmental pollution are becoming more and more serious. If environmental governance and energy supply can be combined, it will be more consistent with the long-term concept of sustainable development. Urea electrooxidation may achieve the degradation of pollutants and the conversion of energy supply, urea oxidation occurs at the anode and hydrogen evolution occurs at the cathode. However, the electrochemical oxidation process of urea requires the transfer of six electrons, and the reaction rate is slow. The electrocatalyst is a key factor in improving the reaction kinetics. In this context, catalysts used in urea electrocatalytic oxidation in recent years are reviewed in this paper. The application of the electrocatalyst in electrolytic hydrogen production, urea wastewater treatment, urea fuel cells and urea sensors are described in detail. In addition, the future research directions, research emphases and areas needing improvement of these catalysts are discussed. [Display omitted] • Urea electrooxidation has double benefits of environmental protection and energy supply. • Electrocatalysts for urea electrooxidation in alkaline electrolytes are reviewed. • The applications of electrocatalyst in the electrooxidation of urea are demonstrated. [ABSTRACT FROM AUTHOR]

The utilization of heterostructures as photocatalysts for water decomposition is a promising method to tackle contemporary environmental challenges. This research paper presents the design of a direct Z-scheme heterostructure utilizing a monolayer of GeC and a monolayer of arsenene, based on first-principle calculations. The photocatalytic efficiency of this GeC/arsenene van der Waals (vdW) heterostructure in a direct Z scheme has been investigated. The presence of a built-in electric field from the GeC monolayer to the arsenene monolayer has been established through an analysis of band alignment, work function, charge density, and Bader charge. The GeC/arsenene heterostructure exhibits excellent and robust optical absorption efficiency for the sunlight, alongside achieving the maximum solar-to-hydrogen (STH) energy conversion efficiency, amounting to 7.28%, under a biaxial strain of +4%. Furthermore, the Gibbs free energy changes in the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) of the GeC/arsenene heterostructure have been calculated. The outcomes indicate that the GeC/arsenene heterostructure is a feasible semiconductor for photocatalytic water splitting. Band edge positions and Z-scheme photocatalytic mechanism of the GeC/arsenene heterojunction. [Display omitted] • GeC/arsenene heterostructure has a built-in electric field from GeC to arsenene layer. • GeC/arsenene heterostructure exhibits a high optical absorption under biaxial tensile strain. • The highest solar-to-hydrogen efficiency of 7.28% is obtained under +4% strain. • High catalytic activity for the hydrogen evolution reaction is confirmed by free energy calculations. [ABSTRACT FROM AUTHOR]

Linear transverse flux permanent magnet machines (LTFPMs) are categorized as high force density topologies, which are suitable candidates for direct drive and low-speed applications. This paper introduces a novel LTFPM topology, which also proposes advantages of the flux-switching machines. This proposed linear transverse flux switching PM machine (LTFSPM) has two long passive translators located at the armature's top and bottom sides. The topology offers a high value of force density, and also, it is a cost-effective topology due to its double-sided passive translator. Furthermore, the PMs are fully utilized in the magnetic circuit, the end winding length is negligible, and the iron cores can be laminated easily. In this paper, the operation principle of the topology is explained and its magnetic circuit is discussed. To reduce the computational time of optimization procedure, a double-layer method is adopted, which provides high robustness, low computational time, and high precision. Results of the finite element method indicate that the proposed machine can be considered a potential candidate for linear motion applications especially direct drive wave energy conversion systems, which require high force density values. [ABSTRACT FROM AUTHOR]

The miniaturization, portability, and reduction in power consumption of wearable devices have greatly facilitated significant advancements in the field of wearable human energy harvesting systems. Human metabolism results in waste heat production and dissipation to the surroundings via skin radiation, convection, and evaporation. Wearable flexible thermo-electric and moist-electric devices uses skin waste heat harvesting to convert thermal energy into electricity without user involvement. The principle and structure of the device is simple and pollution free with great application potential in generating power supply. Skin waste heat can be dissipated in the forms of both sensible and latent heat. Wearable thermo-electric generators (WTEGs) collects sensible heat, and wearable moist-electric generators (WMEGs) collects latent heat. This paper reviews the mechanism behind the generator of WTEG and WMEG, as well as state-of-the-art research progress made in material properties and structural design of thermoelectric devices. The performance optimization and design of wearable, flexible thermoelectric devices for skin waste heat harvesting at the material and device levels are studied, followed by a breakdown on the fibers and fabrics used in the foundation for future development of WTEG and WMEG's. The research findings provides valuable insight on the future development of WTEG and WMEG's, providing integration into wearable applications for health and physiological monitoring and disease diagnosis. This paper reviews the mechanism behind the generator of WTEG and WMEG, as well as state-of-the-art research progress made in material properties and structural design of thermoelectric devices. The performance optimization and design of wearable, flexible thermoelectric devices for skin waste heat harvesting at the material and device levels are studied, followed by a breakdown on the fibers and fabrics used in the foundation for future development of WTEG and WMEG's. The research findings provides valuable insight on the future development of WTEG and WMEG's, providing integration into wearable applications for health and physiological monitoring and disease diagnosis. [Display omitted] • Explored the theory of thermoelectric energy conversion from skin waste heat. • Overviewed advancements in material properties and structural design of thermoelectric devices. • Studied on improved designs for wearable thermoelectric devices using fiber and fabric materials. • Future directions for wearable flexible thermoelectric devices. [ABSTRACT FROM AUTHOR]

Large ships are more utilized than ever before to facilitate transporting heavy goods and oils overseas. However, they rely on fossil fuels and cause severe environmental impacts. Utilizing alternative fuels and implementing new engine designs are considered promising methods to reduce greenhouse gas emissions and improve engine performance. This paper compares three developed, hybridized marine engines operated using five fuel blends of hydrogen, methanol, dimethyl ether, ethanol, and methane. In addition, the paper presents a multi-objective particle swarm optimization to increase the engine power and its exergetic efficiency and reduce the cost and environmental impact. A marine engine (SRC-GT-SOFC) containing a steam Rankine cycle, a gas turbine, and a solid oxide fuel cell is considered to weigh less and perform better. It is found that the optimized SRC-GT-SOFC engine power is increased by about 10 %, corresponding to 16269 kW with an increased exergetic efficiency of 70.6 %, respectively. Its specific fuel and product exergetic costs are found to be 12 $/GJ and 15.67 $/GJ, and its specific fuel and product environmental impacts are 7.4 Pt/GJ and 9.3 Pt/GJ, respectively. This results in a significant reduction in the relative cost difference and the relative environmental impact difference of the optimized SRC-GT-SOFC of 30 % and 25.4 %, respectively. • Three hybridized marine engines are compared and optimized to raise performance. • Optimized SRC-GT-SOFC engine has 16.3 MW power and 70.6 % exergetic efficiency. • Specific exergetic cost reduced to 12 $/GJ for fuel and 16 $/GJ for product. • Specific exergetic environmental impact for fuel and product becomes 7.4 and 9.3 Pt/GJ. • New operation conditions of SRC-GT-SOFC have low price and environmental impact. [ABSTRACT FROM AUTHOR]

The Near-Space Plasma Electromagnetic Science Experimental Research Apparatus is designed for ground-based simulation of plasma sheath and is capable of providing pure, high-enthalpy, and high-density plasma jets. The high enthalpy implies a high plasma state, which can achieve high Mach equivalent simulation in flight conditions. This paper takes this device as the research object and establishes a multi-physics coupling magnetohydrodynamics model to simulate the heat transfer process under high-power conditions. Through numerical simulation, the distribution rules of plasma temperature and enthalpy value under different power states considering the radiation source are obtained. By combining numerical simulation with experimental verification, the simulated enthalpy and energy conversion efficiency results are compared with experimental data, showing good consistency. The study finds that the enthalpy at the center of the jet outlet is higher, increasing from 5.4 MJ/kg to 9.5 MJ/kg when the high-frequency power increases from 150 kW to 426 kW, with an increase of 4.0 MJ/kg. The overall distribution of plasma jet enthalpy exhibits a central peak, gradually decreasing radially from the center to both sides. Meanwhile, during the axial jet injection process, there is a transition in the radial distribution of temperature and enthalpy, shifting from a saddle-shaped distribution at the coil position to an arch-shaped distribution at the nozzle outlet. In this power range, the energy conversion efficiency of the high-frequency power source ranges from 53% to 30%, with both calculated and measured efficiencies decreasing with increasing power. Additionally, the paper discusses the impact of radiation source terms on the distribution of enthalpy in high-power inductive-coupled plasma. In conclusion, the model proposed in this paper can be used to estimate the outlet enthalpy distribution and energy conversion efficiency of the Near-Space Plasma Electromagnetic Science Experimental Research Apparatus, providing data support for the design, control, and application of the device. • Develops model for simulating plasma heat transfer in high-power settings. • Enthalpy & efficiency simulation aligns well with experiments. • Model predicts device's outlet enthalpy distribution, aiding control and application. [ABSTRACT FROM AUTHOR]

Two-dimensional (2D) materials have driven great interest due to a large specific surface area to volume ratio and adjustable surface behaviors, which show huge potentials for enhancing the activity of energy conversion and property optimization. In order to regulate the physicochemical properties of photocatalyst for water splitting reaction, defect engineering on 2D materials have drawn great attention. Meanwhile, a widely used strategy to improve the H 2 evolution rate kinetics has been achieved. In this paper, we prepared AgBr/g-C 3 N 4 catalyst by chemical precipitation. The obtained photocatalyst shows a unique charge transfer pathway. In addition, a deep understanding of the proton shuttle during H 2 evolution reactions can offer profound opinion into heterostructure construction and property optimization. It is found that the enhanced performance is correlated to the superiority of the S-scheme heterojunction and defect engineering on graphitic carbon nitride 2D materials. This work offers a novel method for improving efficiency in terms of energy conversion and property optimization. [Display omitted] • Surface nitrogen vacancy is instrumental in the chemisorption and activation of H 2 O. • S-scheme band of AgBr/g-C 3 N 4 is conjectured by the experiments and DFT calculations. • The prolonged photocarrier lifetime has increased H 2 production. • The results of XPS are consistent with the mechanism of S-scheme heterojunction. [ABSTRACT FROM AUTHOR]

The blade of a hydraulic turbine is the critical element of the energy conversion process in a hydroelectric plant; therefore, numerous blade reconstruction techniques are based on stacking cross-sections along the flow streamlines generated inside the runner passage. The uneven distribution along the spanwise direction causes surfaces with a lower degree of uniformity and continuity, especially in highly twisted and re-flexed blades. To solve this problem, the researchers often stack many cross-sections, causing a proportional increase in the number of parameters and points that define each section, which is detrimental when performing hydrodynamic optimization or numerical machining of the runner. In consequence, in this paper, we created the Smoothed Numerical Blade (SNB), a blade that is computationally cheap and defined with the lowest number of well-defined cross-sections placed orthogonality on a grid instead of following the fluid trajectory. The quantitative and qualitative analysis developed in the model test of the Francis GAMM turbine shows that the runner created by SNB achieves a high degree of smoothness and continuity on the blade surfaces, thereby maintaining the GAMM turbine performance of the original parameters. [ABSTRACT FROM AUTHOR]

As the world strives to achieve a sustainable future, the exploration of alternative and renewable raw materials for energy storage and energy conversion has gained significant attention. A growing trend on "Waste to Energy" approach has attained prominence. Accordingly, chicken eggshells, a residual from poultry industry, have emerged as a promising candidate due to their abundant availability, low cost, and unique physical and chemical properties. This review article presents an overview of recent advancements in utilizing eggshell waste for energy storage and energy conversion applications. It discusses the transformation of eggshells usage into functional materials, along with their performance in various energy-related applications. The potential of eggshell-based materials in improving energy efficiency and reducing environmental impact is highlighted, providing insights into the future prospects of this sustainable resource. [Display omitted] • Relevance to Sustainability: The review article addresses the global imperative of achieving a sustainable future, making it highly relevant to current environmental concerns. • Focus on Alternative Materials: The review explores the use of alternative and eco-friendly materials for energy storage and conversion. • Waste to Energy Trend: The "Waste to Energy" approach, which is gaining prominence worldwide, is at the core of this review paper, showcasing its relevance in addressing waste management and energy challenges simultaneously. • Diverse Energy Storage Applications: The review explores a wide range of energy storage applications, including capacitors, batteries, and other devices. • Promising Energy Conversion Applications: The paper discusses energy conversion applications such as fuel cells and hydrogen production. [ABSTRACT FROM AUTHOR]

[Display omitted] • Metal-organic framework (MOF) dispersion based fluids showed high potential for solar-thermal energy conversion (STEC). • Three different MOF dispersions (CuBTC, FeBTC, ZIF8 in ethylene glycol) were systematically explored for STEC application. • FeBTC showed the highest STEC efficiency with long-term dispersion stability, making it most promising for practical use. • This report marks a significant milestone in introducing the potential of MOF dispersion-based fluids for STEC application. • This research will pave the way for future explorations on various MOF dispersions in this field. This paper discusses the potential use of metal–organic framework (MOF) dispersion based fluids for solar-to-thermal energy conversion (STEC). For this, the optical and thermal characteristics of MOF dispersion were investigated, with MOFs dispersed in ethylene glycol (EG). This study is focused on three different MOF dispersions, namely ZIF8/EG, CuBTC/EG, and FeBTC/EG, each with varying concentrations of MOF particles. The results showed that FeBTC/EG at a concentration of 0.3 wt% is the optimal fluid for STEC, exhibiting the highest absorption and STEC efficiency compared to the other two fluids. The study also highlights the trade-off between STEC efficiency and cost, as increasing the concentration of MOF particles decreases the specific absorption rate (SAR). Additionally, the paper evaluates the dispersion stability of FeBTC/EG over time, which is critical for practical STEC applications. The novelty of the paper lies in the use of MOF dispersion based fluids for STEC application, which has not been extensively studied before. This study provides valuable insights into the potential use of MOF/EG for STEC and highlights the importance of optimizing the concentration of MOF particles for efficient and cost-effective performance. This study also introduces the novel application of MOF dispersion based fluids for enhanced STEC performance, showcasing FeBTC/EG as a standout for its high efficiency and stability. It marks a significant stride in utilizing MOF materials for sustainable energy, emphasizing practical considerations of dispersion stability and cost-effectiveness in STEC systems. [ABSTRACT FROM AUTHOR]

The exploitation of fossil fuels in various sectors, such as power and heat generation, and the transportation sector has been the primary source of greenhouse gas (GHG) emissions, which are the main contributors to global warming. Qatar's oil and gas sector notably contributes to CO 2 emissions, accounting for half of the total emissions. Globally, it is essential to transition into cleaner fossil fuel production to achieve carbon neutrality on a global scale. In this paper, we focus on clean hydrogen, considering carbon capture to make hydrogen a viable low carbon energy alternative for the transition to clean energy. This paper systematically reviews emerging technologies in carbon capture and conversion (CCC). First, the road map stated by the Intergovernmental Panel on Climate Change (IPCC) to reach carbon neutrality is discussed along with pathways to decarbonize the energy sector in Qatar. Next, emerging CO 2 removal technologies, including physical absorption using ionic liquids, chemical looping, and cryogenics, are explored and analyzed regarding their advancement and limitations, CO 2 purity, scalability, and prospects. The advantages, limitations, and efficiency of the CO 2 conversion technology to value-added products are grouped into chemical (plasma catalysis, electrochemical, and photochemical) and biological (photosynthetic and non-photosynthetic). The paper concludes by analyzing pathways to decarbonize the energy sector in Qatar via coupling CCC technologies for low-carbon hydrogen, highlighting the challenges and research gaps. [ABSTRACT FROM AUTHOR]

• Different carbon-based electrodes following a nature-inspired solution were tested by CV and EIS. • Glass-carbon electrodes (GCE) and carbon paper-based electrodes (CPE) with and without polytetrafluoroethylene (PTFE) were evaluated. • The electrodes' performance was assessed by employing the ferri/ferrocyanide ([Fe(CN) 6 ]3-/4−) electrochemical probe. • Surface properties of the commercial electrodes materials were evidenced from AFM and water contact angle measurements. • Best results were achieved with CPE without PTFE, given its hierarchical porous structure and absence of the insulating binder. Carbon electrodes are widely accepted as very versatile platforms, with applications ranging from electrocatalysis to sensors and other devices, like fuel cells and water electrolyzers. However, there are still difficulties given that over time, at high potentials, the oxidation of carbon materials (as a catalyst and/or catalyst support) can play a detrimental role, undermining the efficiency and stability of the electrochemical processes and devices performance. In this paper, it is reported the research work followed by resourcing to electrochemical analytical techniques, like cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), along with complementary atomic force microscopy (AFM) and water contact angle (WCA) measurements. These techniques were used to characterise glass-type and paper-based carbon electrodes. On a nature-inspired solution, we took advantage of the different interfacial carbon-support hierarchical porous structures to boost the carbon electrocatalytic effect towards sensing the ferri/ferrocyanide redox couple ([Fe(CN) 6 ]3-/4−) in aqueous solution. It is shown that the best results were achieved with carbon paper electrodes without wet proofing, given its hierarchical porous structure and absence of the insulating binder. This research endeavors to contribute to the ongoing advancements in the field of electrochemical green energy conversion by exploring innovative approaches and materials, with the ultimate aim of developing carbon substrates that not only enhance performance but also promote environmental sustainability. [Display omitted] [ABSTRACT FROM AUTHOR]

Reasonable and efficient utilization of low-grade thermal energy in nature is the choice for sustainable energy development. We demonstrate a bacterial cellulose (BC) hydrogel thermocell (TEC) based on BC electrolyte combined with carbon fiber paper and copper composite electrode sheets. The large specific surface area of carbon fiber paper provides a large number of active sites for thermoelectric ions, which drives the redox reaction inside the electrolyte and stimulates the chemical reaction between the electrolyte and the electrode. The combination of the two chemical reactions significantly improves the thermoelectric performance of the thermocell. The thermopower of the BC-TEC reaches 5.9 mV·K−1 at a temperature difference of 50 K. The TEC consisting of 6-units in series produces an open-circuit voltage of about 2 V and a peak power of 535 μW. The TEC shows new potential and prospects in ambient thermoelectric energy conversion by rationally designing the power generation principle. [Display omitted] [ABSTRACT FROM AUTHOR]

The oscillating-water-column (OWC) system is one of the most developed wave energy conversion technologies, and several prototypes have been deployed and tested on the sea. Noise emission is essential to this technology's long-term environmental impact assessment. The power take-off system of an OWC comprises a self-rectifying air turbine that directly drives an electrical generator. The paper compares the noise emission of a biradial turbine with that of a Wells turbine. The noise emission of the biradial turbine was measured at the Instituto Superior Técnico variable-flow test rig, while the Wells turbine data were collected in the literature. Acoustic measurement procedures followed the guidelines of the ISO 3746 Standard. A definition of specific noise level is used to compare the noise emission from geometrically similar air turbines or other air turbines performing the same duty. The results show that the noise levels of the biradial turbine are significantly lower than those of the Wells turbine at off-design conditions for the same pneumatic power. • Methodology for measuring noise emission from air turbines. • Experimental characterisation of the acoustic emission of a biradial turbine. • Use of a specific noise level to compare air turbines. • Comparison of noise emission of a biradial turbine with a Wells turbine. • Wells turbines are significantly noisier than biradial turbines at off-design conditions. [ABSTRACT FROM AUTHOR]

Achieving large-scale commercial exploitation of ocean wave energy inherently encompasses the design and deployment of arrays of wave energy converters (WECs), in an effort to reduce the associated levelised cost of energy. In this context, understanding the interactions between devices in a controlled WEC array is hence essential to achieve optimal layout configurations, as well as to provide guidance on the area required for array installation, reliability, life-time, and overall cost of the farm. Successful achievement of these vital objectives for the wave energy industry has been constantly aided by the use of appropriate numerical models. Regardless of the specific modelling approach adopted, model reliability is always a major concern: Numerical models need to able be to represent reality to be useful in supporting the different stages of development, hence providing significant results for decision making. To test reliability of a model, experimental results are an invaluable asset for validation. Recognising the striking absence of real-world data concerning arrays of WEC systems, and its inherent value for model validation and data-based modelling purposes, we present, in this paper, an experimental campaign fully conducted with the sole objective of generating and providing an open-access dataset on WEC farms: SWELL (Standardised Wave Energy converter array Learning Library). The generated dataset, included alongside this manuscript, comprises an approximate total of ∼ 3000 variables and more than ∼ 1 0 8 datapoints, for up to 5 devices in 9 diverse WEC array layouts with different levels of interaction, and 19 carefully selected operating conditions. Four different categories of tests are considered, providing measures of key variables required for model validation and data-based modelling tasks. As such, SWELL provides a crucial resource to achieve confidence in numerical modelling, helping towards creating reliable tools for decision making in the WEC field, hence effectively supporting the pathway towards effective commercialisation of ocean wave energy. • Current absence of real-world data concerning arrays of WEC systems. • Experimental campaign to generate an open-access dataset on WEC arrays. • Up to 5 devices in 9 diverse layouts, and 19 operating conditions. • Four different tests, ∼ 3000 variables, and more than ∼ 10 8 datapoints. [ABSTRACT FROM AUTHOR]

Attributed to its environmental friendliness, high theoretical energy density, and abundant sodium resource, rechargeable hybrid sodium-air batteries (HSABs) are expected to become a promising pioneer of the new-generation green energy storage device. However, HSABs suffer from the high voltage gap, low energy conversion efficiency, and poor cycle stability due to the low catalytic activity of catalysts caused by the degradation of polymer binders. Herein, hierarchical mesoporous NiO nanosheet arrays grown on carbon papers (CP) (NiO NA@CP) were synthesized by a facile and efficient hydrothermal route and calcination process, which acts as an integrated electrode for HSABs. Compared with traditional air electrodes that contain a polymer binder and conductive carbon, the integrated NiO NA@CP electrode prevents the aggregation of catalysts, improves the electronic conductivity by good electric contact and ensures its robust mechanical stability. In addition, NiO NA@CP electrode with the abundant porosity and large specific area offers plenty of active sites and shortens ion transfer length and rapid mass transport in ORR/OER process, leading to excellent oxygen catalytic activities. HSABs with NiO NA@CP electrode show a low overpotential of 0.65 V, a state-of-the-art power density (7.53 mW cm−2), as well as an excellent cyclability of 170 cycles (over 170 h) at a current density of 0.1 mA cm−2. [ABSTRACT FROM AUTHOR]

Dielectric elastomer actuators (DEAs) show broad application prospects in the area of soft robots since they offer merits of fast response, large deformation, light weight and high energy conversion efficiency. Practical soft robot applications would usually require the study on the modeling and control of the DEA. However, the DEA has a memory property, which results in a highly nonlinear characteristics, bringing difficulties to the subject. To address this issue, an effective strategy is the utilization of the fractional order model, which is a type of modeling approach that can accurately characterize the memory property of a material with a small amount of parameters. Meanwhile, the fractional order controller can better handler the memory property, and it owns a better flexibility than traditional integer order controllers. With the above considerations, this paper proposes a modeling strategy and a tracking control strategy for the DEA on the basis of the fractional calculus. In the proposed strategy, a fractional order model is established to characterize the complicated nonlinear characteristics of the DEA. Then, to facilitate the computer simulation, the Oustaloup filter is used to construct an integer order approximation model (IOAM) of the fractional order model. Since the IOAM is difficult to be employed in the system controller design due to its high order, the IOAM is further simplified into a reduced order model based on the square root balance truncation algorithm. To realize the high accuracy control of the DEA, a feedforward-feedback combined controller is devised, which is composed of a feedforward controller and a fractional order proportional integral feedback controller (FOPIFC). Among which, the feedforward controller is devised based on the analytical inverse of the reduced order model to compensate the complicated nonlinear characteristics of the DEA, and the FOPIFC is devised to handle the bad influence from the modeling error and uncertainties on the control performance. Based on the proposed strategy, control experiment was conducted, and the root-mean-square errors in experiment are all below 0.7%, indicating the superiority of the presented modeling and tracking control strategies. • Establish fractional order model to describe memory property. • Use Oustaloup filter to approximate fractional order model. • Construct reduced order model to facilitate controller design. • Design fractional order controller to realize tracking control. • Realize tracking control of dielectric elastomer actuator in actual experiments. [ABSTRACT FROM AUTHOR]

The development of accurate and efficient electrothermal models and simulations for power electronics semiconductors is essential to optimize power electronics circuits and systems. To achieve this goal, it is crucial to have electrothermal models that are precise but not overly complicated, which can be used in commonly accessible simulators of power electronic circuit like MATLAB/Simulink. In this research paper, a MOSFET transistor behavioral electrothermal modeling is performed using MATLAB/Simulink. The electrothermal MOSFET model was created using the nonlinear and linear electrical elements (resistors, capacitances, controlled current source ...) of SIMSCAPE library in MATLAB/Simulink circuit simulation platform. This used model encompassed both electrical and thermal elements, with the parameters derived from the manufacturer's data. Its precision reflected the MOSFET transistor's electrical and thermal characteristics. In order to verify the model's accuracy, simulation results were compared against the manufacturer's datasheet as well as experimental curves. The proposed model provided simulation results that were in good agreement with the datasheet results and measurements. • An electro-thermal model of power MOSFET that utilizes the same simulator (MATLAB/Simulink) to handle both thermal and electrical problems through a direct method frame using RC Foster circuit is introduced in this paper. • The MOSFET electrical and thermal behavior are described precisely in this model, and all necessary model parameters were extracted using the information provided in the constructor datasheet. • The presented model accuracy was verified by confronting the simulation results obtained from MATLAB/Simulink with the measurements presented in the datasheets. [ABSTRACT FROM AUTHOR]

In the pursuit of sustainable energy solutions, the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources, hydrogen production, storage, and utilization, this system enables diverse applications across various sectors. By harnessing solar and/or wind energy, the Integrated Renewable Energy-Driven Hydrogen System optimizes energy generation, distribution, and storage. Employing a systematic methodology, the paper thoroughly examines the advantages of this integrated system over other alternatives, emphasizing its zero greenhouse gas emissions, versatility, energy resilience, and potential for large-scale hydrogen production. Thus, the proposed system sets our study apart, offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed, highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years, depending on the renewable energy configuration, emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable Energy-Driven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts. [Display omitted] • Integrating renewable energy and hydrogen for energy independence. • Advantages of Integrated Renewable Energy-Driven Hydrogen System: Zero emissions, resilient energy. • Economic viability: Payback period of 2.8–6.7 years. • Technological progress in hydrogen energy. • A novel and transferable system dynamics model for sustainable solutions is proposed. [ABSTRACT FROM AUTHOR]

Annular thermoelectric power generator has been increasingly considered in application of ambient energy harvesting owing to the advantages of simple structure and no pollution. To improve thermal stability and energy harvesting performance of this system, the latent heat of phase change materials to improve thermal management and the high thermal conductivity of the heat sink to enhance heat transfer with the ambient are harness to annular thermoelectric power generator. Motivated by this, a phase change material based annular thermoelectric energy harvester (PCM-ATEH) with fins is developed for ambient energy harvesting and its three-dimensional transient model is also built up through jointly with thermo-electric and phase change processes. This paper considers the influence of key parameters such as temperature fluctuation amplitude, temperature fluctuation period, height ratio of PCM and thermoelectric generator (TEG) and melting temperature on liquid fraction, temperature difference, voltage and power density. Moreover, the comparison of PCM-ATEH and PCM based thermoelectric energy harvester (PCM-TEH) with/without fins is further conducted in this study to explore thermal management and energy harvesting performance. The energy harvesting characteristics of PCM-ATEH with fins is developed concerning the combination of power generation of TEG and melting process of PCM. Based on the results, it is found that the temperature difference and power density of PCM-ATEH with fins vary periodically with the sinusoidal temperature boundary, and results show that increasing temperature fluctuation period is not always feasible. Additionally, the comparative results indicate that the peak power density and energy efficiency of PCM-ATEH with fins are increased by 0.126 W/m2 and 0.02 % compared with PCM-TEH with fins, and increased by 0.195 W/m2 and 0.041 % compared with PCM-ATEH without fins. The results of energy harvesting characteristics show that a maximum of 0.77$ per watt can be reached to power generation cost of PCM-ATEH with fins. This paper can provide theoretical guidance for thermal management and energy conversion of energy harvesting system. [ABSTRACT FROM AUTHOR]

Agricultural microgrid propounds a tailored and cost-effective platform for multi-energy supply in rural areas but also faces the challenge of supply outages because of the fragile grid structure. This paper proposes an electricity–heat–water based multi-energy hub (EHWbMEH) to enhance the resilience of agricultural microgrid, with the objectives of minimization of operation cost and maximization of resilience. To this end, the stochastic characteristics and coupling relationship of photovoltaic and solar thermal outputs are first investigated by introducing expected power not served and expected power curtailment. Subsequently, the EHWbMEH consisting of energy conversion, storage, and distribution devices is developed to ensure the resilience of the agricultural microgrid during supply outages. On this basis, a multi-objective resilience-economic operation model for EHWbMEH considering irradiation intensity uncertainty is presented, and the Pareto frontier is derived by applying the multiple preys based evolutionary predator and prey strategy. According to the simulation results, when the electricity, heat, and water supply are interrupted, the total operation cost of the optimal trade-off solution is $3740.141, while the electricity, heat, and water load resilience can reach 63.37%, 84.72%, and 80.55%, respectively. Case studies demonstrate the effectiveness and performance of the proposed method. • The concept of electricity–heat–water based multi-energy hub is proposed for agricultural microgrid. • The paper highlights the EHWbMEH's objectives of minimizing operation costs and maximizing resilience in rural areas. • The paper investigates stochastic characteristics and coupling relationship of photovoltaic and solar thermal system. • The paper develops a multi-objective optimization to balance resilience and cost. [ABSTRACT FROM AUTHOR]

Urban green spaces are increasingly recognized for their positive impact on well-being, quality of life, and public health. Researchers have explored how green space characteristics, such as size, theme, and convenience, influence urban movement. However, an important aspect that has received limited attention is the relative attractiveness of green spaces. When residents have access to similar green spaces nearby, their inclination to visit more distant ones decreases. This leads to the central research question: How does the relative attractiveness of urban green spaces affect urban movements? The existing literature lacks a comprehensive theory to address this question. To bridge this gap, this paper introduces the Potential to Kinetic Energy (PKE) framework, inspired by principles from physics. In this framework, potential energy represents the relative attractiveness of green spaces between the travel origin and destination, while kinetic energy signifies the urban movement resulting from the this attractiveness. To demonstrate the PKE framework's applicability, this paper analyzes green space data and smart card subway ridership records from Beijing. The results show that a unit increase in size, cultural, attraction, proximity, and location potential energy is associated with a 0.22%, 0.27%, 0.14%, 0.19%, and 0.02% increase in urban movement. The findings provide compelling evidence for the significant role of relative attractiveness in shaping urban movements and offer valuable insights for urban planning and policy development. The proposal of the PKE framework encourages interdisciplinary discussions among urban planners, environmental scientists, and transportation experts, fostering collaborative efforts to enhance the sustainability of cities. • A Potential to Kinetic Energy (PKE) framework is introduced to investigate the relationship between green space attractiveness and urban movements. • Potential energy contains five sub-concepts: size, culture, attraction, proximity and location. • Kinetic energy represents urban movement that characterizes the motion of objects resulting from potential energy conversion. • Empirical analysis of Beijing shows the significant role of relative green space attractiveness in shaping urban movement patterns. • The PKE framework supports urban planners to evaluate green space attractiveness, examine the impact of landscape change, and promote inclusive urban environments. [ABSTRACT FROM AUTHOR]

• The dynamic characteristics of heat pipe cooled reactor during the early startup period are discussed. • Power pulse phenomenon which can cause the obvious increase in fuel temperature should be deserved special attention. • Only until all heat pipes startup successful, can heat generated in reactor be efficiently transferred to the energy conversion system. Heat pipe cooled reactor has unique characteristics during reactor startup and power operation due to the design of solid reactor and heat pipes heat transportation. In this paper, numerical simulation of the early startup period of typical heat pipe cooled reactor is carried out. Based on the calculation, it can be found that it takes about 6000s to complete startup from the room temperature, and fuel temperature reaches about 730 K. Important phenomenon of power pulse is also discovered. For power pulse, reactor power can rapidly increase from 80 wt to 40kWt with about 220 s, leading to rapid increase in fuel temperature from 300 K to 420 K. It is also found that heat pipes may cool down again if reactor power is low enough. Studies carried out in this paper show the dynamic characteristics and point out the key issues that need to be focused on during the reactor early startup period. [ABSTRACT FROM AUTHOR]

Water electrolysis for green hydrogen production is gaining tremendous attention in the quest towards sustainable energy sources. At the heart of water splitting technology are the electrocatalysts, which facilitate the two half-cell reactions, i.e., the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), with the latter being the most thermodynamically uphill. Herein, we managed to fabricate Ni 1-x Fe x O microflowers (μFs) with varying % of Fe doping (0 < x < 0.36) via an easy chemical bath deposition (CBD) method. The as-synthesized μFs drop-casted on graphene paper (GP) are then applied as electrocatalysts for OER. Compared to contrast catalysts, the electrocatalyst with x Fe = 0.1 exhibits a lower overpotential of 297 mV at a current density of 10 mA cm−2, Tafel slope of 44 mV dec−1 and unprecedented turnover frequency of 4.6 s−1 at 300 mV. It is believed that this remarkable electrochemical performance mainly stems from the synergistic effects of Ni and Fe species, working in harmony to enhance charge transfer kinetics and intrinsic activity of the catalyst. This work provides a promising avenue for developing cost-effective and highly active electrocatalysts as advanced electrodes for energy related applications. [Display omitted] • Highly active NiFe-based electrocatalysts synthesized by a simple chemical route. • Effect of Fe doping concentration on oxygen evolution reaction of NiO. • Exceptional turnover frequency of Fe-doped NiO electrodes in alkaline conditions. [ABSTRACT FROM AUTHOR]

Recently-developed twisted multifilament artificial muscles are an intelligent material or device storing energy and outputing work under external stimuli. These muscles are fabricated by a twist-insertion procedure and share a two-step process in triggering rotation or contraction, that is volumetric expansion and tension-torsion coupling. The energy conversion efficiency of thermal actuation for the artificial muscles made of carbon nanotubes has attracted increasing attention due to the giant tensile stroke, record energy density, and easy controllability. In the present paper, the thermal actuation processes of artificial muscles are modeled by numerical simulations, in which the energy conversion efficiency is expressed as the ratio of work output to heat input. The Cosserat curve theory is introduced to analyze the geometric effect of cross-sectional shapes on the tensile TMFAM. The abilities of axial elastic deformation and stretching stable for the CNTBs with typical shapes are quantified. The work output and energy conversion efficiency are then evaluated, offering the opportunity to elevate the mechanical properties of artificial muscles. The strategy to improve the muscle performance is also outlined through their dependence on the geometrical and material parameters. [ABSTRACT FROM AUTHOR]

One of the emerging solid-state refrigeration technologies to replace classic compression refrigeration is electrocaloric refrigeration, which has the advantages of high energy conversion efficiency, easy miniaturization, eco-friendliness, and low cost. In this paper, Ba(Ti 1− x Sn x)O 3 (BTSn) ceramics with x = 0.02–0.08 were prepared by a solid-state reaction route. The structural, dielectric, ferroelectric, electrocaloric as well as electrostrictive characteristics were thoroughly examined. Our results show that the dielectric peaks correlated to the maximal permittivity move towards to low temperature direction when the Sn4+ concentration gradually increases, and a phase diagram of BTSn based on the dielectric characteristics is given. More importantly, in the x = 0.04 ceramic sample synthesized by the viscous polymer process, a giant adiabatic temperature change (Δ T) of 6.36 K with a temperature range of 25 °C at 200 kV/cm is achieved. Typically flare shape electrostrain curves accompanying with small hysteresis are observed in all studied compositions. The average electrostrictive coefficient Q 33 varies within 0.0257–0.0306 m4/C2 at a temperature region from 30 to 160 °C, indicating temperature-insensitive and composition-insensitive characteristics. This research shows that a significant electrocaloric effect can be achieved in BTSn ceramics through high electric field, and would provide a strategy for boosting the electrocaloric effect in other systems. [ABSTRACT FROM AUTHOR]

Wave energy converters (WEC) use indirect drive hydraulic or turbine-type power take-off (PTO) mechanisms which consist of many moving parts, creating mechanical complexity and increasing the installation and maintenance costs. Linear generator-based direct drive wave energy converters could be a solution to overcome this problem, but the efficiency of the single conventional linear generator is not high enough, and it cannot work satisfactorily in the low-frequency range. In this paper, a novel dumbbell-shaped flux-switching linear generator has been proposed and studied as a power take-off unit for ocean wave energy conversion. The linear generator has a dumbbell-shaped stator, and the design is ameliorated by placing the permanent magnet rings of longitudinally alternating magnetic pole directions in the slots of its stator outer surface and is separated by thin wall steel ring shoulders. The linear generator also has a dumbbell-shaped translator. The stator is hollow where the translator slides inside axially inducing current in the coil. A long permanent magnet is inserted inside the hollow steel dumbbell core of the translator and a copper coil is wound around the outer surface of the moving translator core. The addition of permanent magnets on the outer slots of the stator is found to increase the output power significantly. To facilitate the investigation, the modified generator design has been compared to the conventional linear permanent magnet generator for their performances using the finite element method, as both machines are different in their structures. The results show that the double dumbbell-shaped flux-switching linear generator gives higher power output, magnetic flux density, branch current, and induced voltage. The double dumbbell-shaped flux-switching linear generator is then placed in a cylindrical buoy and investigated in a wave energy converter in the ocean environment. The hydrodynamic response of the cylindrical buoy has been investigated through ANSYS AQWA. The dynamic differential equations of the wave energy converter have been developed and solved for regular waves using Matlab codes. The peak output voltage, power, and the relative displacement of the linear generator translator with respect to the stator fixed with the buoy have been calculated through the Fourier Transform in the frequency domain using a Matlab code and through numerical integrations in the time domain using a Matlab Simulink code. The results in the time and frequency domains are compared and verified with each other. The relative displacement between the translator and stator buoy has been used as motion input of the ANSYS Maxwell simulation model, and the output voltage results of the ANSYS Maxwell simulation model have been compared and verified with those of the Matlab simulation models. The linear generator design in the wave energy converter under the regular wave excitation is further optimized for the maximum ratio of the peak output power to peak cogging force using the central composite design-based response surface method (RSM). The ANOVA analysis is used to validate the response surface model where its R 2 coefficient of 99.93% has indicated an excellent fit. The methods and results differ from those presented in previous studies. [ABSTRACT FROM AUTHOR]

Harvesting energy from the sun is a promising technology to resolve the ongoing energy crisis. Solar photovoltaic (PV) and photovoltaic/thermal (PV/T) systems are mainstream solar energy conversion technologies that enable duple functions to obtain both electrical and thermal energy. However, in practice, emerging problems (uneven temperature distribution, limited cooling effect, freezing issues, high initial costs, etc.) have hindered the development and progress of these technologies. To overcome the aforementioned barriers, a heat pipe was introduced as an effective heat transfer device with passive operation characteristics. The assimilation of cutting-edge thermoelectric (TE), phase change material (PCM) and the development of integrated photovoltaic (BIPV), heat pump, and nanotechnologies have also been explored to achieve higher overall efficiency. This paper focuses on the integration of various heat pipes with solar PV systems and innovative technologies from historical development and recent advancements. In addition, the major observations and challenges are highlighted, and the prospects for future development are corroborated. This work is dedicated to opening new horizons and providing suggestions in this research field, enabling in-depth and broad exploration. • Heat pipes based solar photovoltaic and photovoltaic/thermal systems are reviewed. • The combination of innovative technologies in these systems is summarized. • Using heat pipes in these systems leads to enhanced performance. • Challenges and future suggestions of such technologies are discussed. [ABSTRACT FROM AUTHOR]

This paper seeks to identify promising sites and technologies, in Portugal, for co-located wave energy conversion and offshore aquaculture, whilst providing benchmark implementation references and guidelines to researchers. Accordingly, two case study sites are considered for deployment of five wave energy devices and up to six aquaculture species. A thorough analysis in terms of power ratios, efficiency, redundancy, species viability, device survivability and costs is performed, seeking to find viable co-located solutions. It is found that the Wave Dragon device yields the most promising energy demand coverage and energy output (5 226 to 6 817 MWh/year). Nevertheless, it may require rescaling towards optimal operation, while the OCECO 4 excels in terms of capacity factor (0.24–0.29) and default adaptation to the deployment sites. The WaveRoller® has the lowest single-unit cost (125 €/MWh) but requires up to nine units to cover all the energy demand targets. Larger wave farms are required for the BBDB and AquaBuOY, albeit with potentially greater economies of scale and single-unit redundancy. These sites also enable cultivation of most of the considered species, even under ideal conditions. Lastly, it is recommended that the devices enter survivability mode at a significant wave height threshold of 5.5 m. • Co-located potential of wave energy harvesting and offshore aquaculture in Portugal. • 5 WECs co-located with 3 + 3 aquaculture species in two deployment sites. • Estimation of energy/power ratios, efficiency, redundancy and species viability. • Wave Dragon stands-out on energy coverage, WaveRoller® on costs and OCECO on capacity factor. • 6/6 and 4/6 viable species for Figueira da Foz (2 ideal) and Sines (3 ideal) sites. [ABSTRACT FROM AUTHOR]

[Display omitted] • Electro permanent magnet is proposed for magnetocaloric refrigeration. • Electro permanent magnet is numerically and experimentally evaluated. • Its energy efficiency above 80% is reached with magnetic energy recovery. • Magnetic field can be switched between min and max up to 50 times per second. • Fast switching of magnetic field can be used with thermal switches. Magnetocaloric energy conversion represents an alternative to existing refrigeration, heat pump and energy harvesting technologies. A crucial part of a magnetocaloric device concerns the magnetic field source. It uses mainly rare-earth materials and consists of moving parts and a drive system while displaying a limited energy efficiency and unavailability of fast and variable control of the magnetic field. Recent advances in efficient heat transfer for high-frequency magnetic cooling call for new developments of magnetic field sources that can operate with high efficiency at high frequencies. We report the concept of an electro-permanent magnetic (EPM) field source that efficiently recovers magnetic energy. In contrast to existing magnets, it allows very well-controlled operation without any moving parts. The main objective of this paper is to present a numerical and experimental study in which such an EPM was designed, built and tested. An extensive numerical investigation of the proposed design was carried out in terms of various geometrical and operating parameters. One of the design variations was built and experimentally evaluated for its energy efficiency and temperature increase at various operating frequencies. We demonstrate an energy efficiency of these magnets of over 80% and operation with frequencies up to 50 Hz, which is crucial for future high-power-density and high-frequency magnetocaloric devices. Considering high energy efficiency at high operating frequencies, such EPMs would allow for miniaturization, making them a viable option for future compact magnetocaloric devices. [ABSTRACT FROM AUTHOR]

Information self-destruction modules (ISDMs) play a vital role in the information security area. In this paper, an ISDM based on the integration of a micro-thermoelectric generation mechanism (M-TEGM) with energetic materials (EMs) is proposed. On the basis of energy conversion relationship, an open-loop electromotive force is induced, and this energy will drive the EMs to release the detonation wave and realize information storage module self-destruction. During the tests, under the temperature difference (100 K), the open-loop electromotive force (3.86 V) is induced by the M-TEGM and can drive the EMs (0.37 mg copper azide) to generate a detonation wave (GPa) in 3.4 μ s, which can physically destroy the information storage modules. This ISDM has advantages that include rapid response times, low drive energy compared with traditional information security technology. • This module has the ability of low driving energy and response time (microseconds) for information storage module(ISM) self-destruction. • The array M-TEGMs can provide energy for EMs to drive ISM physical self-destruction in temperature difference (100 K). • Micro detonation wave is generated by EMs to realize ISM physical self-destruction to prevent information leakage through reverse theft. [ABSTRACT FROM AUTHOR]

The concept of "more- and all-electric aircraft" has become increasingly popular over the last two decades, leading to a boost in the extensive utilization of airborne electromagnetic actuators such as permanent magnet synchronous machines (PMSMs). Inevitably, considerable waste heat is generated during operation due to the incomplete energy conversion, which is a great challenge for conventional onboard thermal control systems. If the huge generated heat cannot be removed efficiently there will be a sharp temperature rise in thermal-sensitive components of the onboard devices. This overheating will cause operational failures which are intolerable in aerospace applications. Aiming to improve the current thermal protection system and gain greater compatibility with the current PMSM system, this paper proposes a phase change material-based (PCM-based) thermal protection strategy using commercial wax in two equivalent PMSMs. A comparative investigation shows that the machine temperature with PCM-based cooling strategy can be reduced under most operating conditions (the maximum temperature drop is 13.7 °C), demonstrating the advantages of deploying the proposed PCM-based cooling scheme. Further data processing towards the heat absorption-dissipation matching between the utilized PCM and the working mode of the cooling object is conducted. A dimensionless correlation of dimensionless temperature peak difference (DTPD) as a function of the pulsed factor, presented in Eq. (17), reveals an average relative error of ±4.5%. Based on the correlation, an optimal pulsed factor of ∼1.764 is calculated to reach a matching condition. Such a method can be promoted to wider applications using PCM as a cooling medium beyond the currently-utilized two types of machines in this paper. • Phase-change-material-based cooling for electromagnetic machines is proposed. • Optimal intermittent operating conditions were identified experimentally. • Two different machine types were considered for a broad application. • Based on experimental data, a correlation was developed for a universal guide. [ABSTRACT FROM AUTHOR]