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To improve the accuracy of early warning on coal spontaneous combustion (CSC), this paper, on the basis of the principle of preferential selection of index gases in CSC process, carries out fitting analysis of the variation curve of index gas data with coal temperature by combining logistic fitting model, then establishes a CSC graded warning system based on positive pressure beam tube monitoring, and determines CO, O2, φ(CO)/φ(O2), C2H4, C2H6, φ(C2H4)/φ(C2H6) as the index gases for predicting and forecasting CSC, and accurately divides the CSC process into seven levels of early warning: safe, gray, blue, yellow, orange, red, and black. Applying the CSC positive pressure beam tube monitoring system to Dongtan coal mine and analyzing the error by manual sampling and sampling by positive pressure beam tube system, we find that the error is less than 0.1%. Monitoring of several working faces, we get that the CO and CH4 concentrations of 14,320 working face are higher than the normal level at the beginning of mining, and the 100 × CO/ΔO2 value is higher than the gray warning threshold of 0.1, and the warning level is gray warning. After taking timely preventive measures against coal oxidation and warming, the CO and CH4 concentrations return to the normal level and the warning level drops to the safe level. This paper improves the monitoring, identifying and early warning capabilities of underground CSC in its early stage. [ABSTRACT FROM AUTHOR]

High-temperature coal oxidation generates a substantial amount of CO and CO2, especially CO, rapidly, which is a primary factor leading to casualties. The oxygen concentration is the predominant factor affecting the high-temperature oxidation of coal, particularly in the generation of CO and CO2. Understanding the generation patterns and relationship characteristics of CO and CO2 under various oxygen concentrations is important for predicting high-temperature coal oxidation and ensuring personnel safety. The paper used TG–MS and FTIR to study the formation characteristics of isothermal oxidation of CO and CO2 in long-flame coal under different oxygen concentrations. The results indicate that there exists an optimal threshold for CO production when the oxygen concentration is about 9% during the isothermal temperature oxidation process at 200.00–350.00 °C. When the oxygen concentration is less than 13%, the influence of oxygen on CO2 production is weakened. As the temperature increases, the pattern of CO + CO2 production and CO/CO2 is reversed, with CO + CO2 increasing and CO/CO2 decreasing. The relationship between the total production of CO and CO2 and the loss of coal mass follows the function y = a + bx at the isothermal temperatures of 300.00 °C and 350.00 °C. An increase in oxygen concentration does not alter the linear relationship. In the isothermal oxidation process of coal, carbonyl and carboxyl groups are the key groups for CO and CO2 production. At 200.00 °C and 250.00 °C, carbonyl and carboxyl groups increase, and other groups are being converted to carbonyl and carboxyl groups while decomposing into CO and CO2. At 300.00 °C and 350.00 °C, the relative content of carboxyl groups decreases. The research findings play a fundamental role in coal mine disaster prevention and control. [ABSTRACT FROM AUTHOR]

Coal spontaneous combustion is a common problem faced by many coal mines. Spontaneous combustion in goaf releases a large amount of harmful gases, polluting the environment while causing a large amount of wasted resources, and even endangering the lives of workers. Due to the collapse of the interior of the mining area, it is impossible to measure the internal gas composition directly. In order to more accurately predict the spontaneous combustion state inside the mining airspace, this paper obtains the CO generation law and the main source of the working face through the combination of laboratory experiments and on-site monitoring. The CO concentration prediction model of the return corner is established with CO as the index gas. Finally, the safe concentration and warning concentration of the working face are calculated according to the example, which provides theoretical basis for the prediction of spontaneous combustion of coal. [ABSTRACT FROM AUTHOR]

The productivity of coal mines is seriously threatened by the combined disasters of gas and coal spontaneous combustion, which have become a common disaster mode. It is unclear how the gas and coal spontaneously combusted in the roof cutting along gob working face. The goal of this study is to identify the distinctive features of combined disasters in gob from two different types of roof cutting along working faces. In these two different types of roof cutting along gob working faces, the paper constructs the permeability model of the gob. The findings demonstrate that the data from the field experiment and the simulation results agree, which validates the simulation's reliability. In contrast to single sided roof cutting along gob working faces, double sided roof cutting along gob working faces clearly has a thinner oxidation zone. Moreover, the oxidation zone of the double side roof cutting along gob working faces is closer to the working face, which is located in the shallow area of the gob 50 m behind the working face. The gas explosion area and the coal spontaneous combustion area are divided by the double side roof cutting along gob working face, which reduces the risk of compound disasters. Important theoretical direction for the prevention and control of gob disasters in the roof cutting along gob working face is provided by the simulation results. [ABSTRACT FROM AUTHOR]

To accomplish various and efficient inhibitions of coal spontaneous combustion (CSC) and solve the safety hazards of CSC encountered in the production and operation of coal mining enterprises, inhibitors play an important role in the prevention and management of CSC. Herein, we report quercetin, which is selection as an antioxidant to prepare a composite solid lipid inhibitor. The concentration of the composite solid lipid inhibitor with the best inhibition effect on the active groups is selected by Fourier pressure infrared experiments, the change pattern of gas content and characteristic temperature released from coal samples during an oxidation process warming process was tested by using a programmed warming test system and simultaneous thermal analysis experiments, and finally, the inhibitory rate and combustion characteristic index were calculated. The results of the research showed that 10 mass% of quercetin had the most impact on the various groups, the highest inhibitor rate of the composite solid lipid inhibitor is 80.67% in the coal low-temperature oxidation process, compared to the raw coal, the heat release of coal treated with the composite solid lipid inhibitor was decreased by 507.65 J g−1, the maximum amount of heat emitted was lowered by 60%, and the flammability index was reduced by 56.4. A composite solid lipid inhibitor containing quercetin developed in this paper indicated high effectiveness in inhibiting CSC, which is vital for coping with the safety management of coal mine production. [ABSTRACT FROM AUTHOR]

Understanding the molecular structure characteristics of coal at the molecular level is of great significance to realize the rational utilization and efficient conversion of coal. This paper gives insights into the acquisition of characterization parameters of coal molecular microstructure by testing and analyzing the long flame coal from Qinggangping (QGP) Coal Mine through proximate analysis, ultimate analysis, vitrinite reflectance determination, fourier transform infrared Spectroscopy test (FTIR), X-ray photoelectron epectroscopy test (XPS), carbon nuclear magnetic resonance (13C-NMR) and X-ray diffraction (XRD). The results show that benzene rings in the QGP coal are mainly connected in a disubstituted way, accounting for 36.48%. Oxygen atoms mainly exist in the oxygen-containing functional groups such as the ether C–O, C=O and –COO. Aliphatic hydrocarbons in the aliphatic group are mainly of symmetrical -CHx stretching vibration. Hydroxyl groups are mainly composed of OH–OH and OH–O hydrogen bonds, accounting for 29.21% and 21.53%, respectively. Nitrogen atoms exist in the form of C4H5N. The coal molecular is mainly of aromatic carbon structure, where the ratio of bridge aromatic carbon to peripheral carbon is 0.198. There are benzene, naphthalene and anthracene in the coal molecular structure, and the former two chemicals play a dominating role. According to the analysis results, the molecular formula of the QGP coal is finally determined as C205H181O29N3S. On this basis, the two-dimensional and three-dimensional macromolecular models are constructed with the assistance of simulation software. In addition, the 13C-NMR spectra and densities of the constructed molecular models are calculated, which verifies the rationality of the models. The macromolecular structure model of bituminous coal constructed in this study provides a theoretical model basis for the optimal surfactant. [ABSTRACT FROM AUTHOR]

Residual coal in mine goafs will be oxidized in the presence of air leakage, which can be well tracked through the radical reaction. This study aimed to explore the changes in radical parameters and the reactivity and persistence of newly produced radicals of coal at different temperature stages. To this end, an in situ electron spin resonance (ESR) spectrometer was adopted to measure changes in radical parameters at the heating, maintaining and cooling stages in real time. The following conclusions were drawn. At the heating stage, the radical concentration first rises slowly and then surges; the g factor remains small initially and increases rapidly later; the linewidth falls continuously. At the maintaining stage (230 °C), the radical concentration keeps increasing, while the g factor and the linewidth remain stable. At the cooling stage, the radical concentration first decreases and then stabilizes at a relatively high level, and both the g factor and the linewidth nearly return to the initial values. Based on the changes in radical parameters at different oxidation stages, the radicals in coal are divided into transient radicals and persistent radicals according to their survival times. Transient radicals, which are strongly reactive, are quickly consumed, while persistent radicals, which is of weak reactivity, can exist in the system for a long time. That is, the active radicals in coal are transient, while the stable ones are persistent. In addition, this paper gives insight into the changes in contents of active radicals and stable radicals at these stages. Finally, the changes in indicator gas and oxygen concentrations at these stages were analyzed. The research finding further explains the mechanism of radical reactions during coal spontaneous combustion. [ABSTRACT FROM AUTHOR]

In view of the complexity and concealment of goafs, numerical simulations have become an important means for studying the coupling disasters of spontaneous coal combustion and gas. Porosity is an important parameter in the numerical simulation, but this is difficult to detect directly on site, as the current porosity model does not fully reflect the characteristics of "three horizontal areas" and "three vertical zones" in the goaf. To establish a more accurate porosity model which is based on a theory of overlying strata movement, the Sigmoid function was introduced to reflect the distribution characteristics of the "three horizontal areas" in the goaf, and subsidence models of the main roof and overlying strata were established. A model that measures the porosity of the goaf was formulated, which reflects its O-shaped circle characteristics. The accuracy of the theoretical model was verified by obtaining experimental data. The results showed that the main roof subsidence in the natural accumulation area was approximately zero, there was an exponential decrease in the load-affected area, and the maximum subsidence appeared in the compacted area. The descending displacement was very small around the impacted area along the roadway wall. The movement of overlying strata in the fractured zone was controlled by the main roof, and the subsidence of the strata near the roadway wall and the working face was very small. In the vertical direction, the subsidence of the overlying strata decreased as the distance from the mining coal seam increased. The distribution of porosity in the goaf was shaped like a dustpan. In the horizontal direction, the porosity of the natural accumulation area and the impacted area of the roadway wall was the largest. Deep within the goaf, the porosity gradually decreased. The porosity in the fractured zone decreased in the vertical direction in a logarithmic manner. The porosity model proposed in this paper fully reflects the characteristics of the goaf, and provides a more accurate porosity model for the numerical simulation of spontaneous coal combustion and gas coupling disasters in the goaf. [ABSTRACT FROM AUTHOR]

Spontaneous combustion of oxidized coal was one of the serious hazards during coal mining and utilization. However, spontaneous combustibility of oxidized coal affected by the first oxidation of coal was still unclear. In this paper, the influence of pre-heating with different oxygen concentrations on coal secondary spontaneous combustion behaviors was studied. Temperature-programmed heating experiments were carried out to prepare pre-heated coal samples by heating at the preset temperature of 80 °C in mixture atmosphere of N2 and O2 with different oxygen proportions of 0%, 5%, 10%, 15%, 20%. Pre-heated and raw coals were heated programmatically in an air atmosphere of 120 mL min−1 with a heating rate of 0.33 °C min−1. The gaseous compounds of O2, CO and CO2 were analyzed to identify spontaneous combustion behaviors of pre-heated and raw coals. The results showed that pre-heating at 80 °C promoted oxygen physisorption at low temperatures and lowered oxidability at high temperatures in the coal secondary oxidation process. Pre-heating at 80 °C with higher oxygen content reduced oxidability and exothermicity of coal secondary spontaneous combustion, but had no obvious effect on oxygen physisorption of coal low-temperature oxidation. [ABSTRACT FROM AUTHOR]

Spontaneous coal combustion is a serious hazard that affects mining safety. Since the coal seams are thin and their resistivity dramatically changes during spontaneous combustion, locating the burned cavities or caving zones using electromagnetic (EM) methods is challenging. The conventional transient electromagnetic (TEM) method with a loop transmitter is ineffective, as the main targets are mostly horizontal and resistive. We propose in this paper to apply TEM with an electrical source to detect the resistive targets of spontaneous coal combustion. Considering that its areas generally have very complex geometry, we adopt the unstructured finite-element method for accurate EM forward modeling. For the time discretization, we choose the unconditionally stable backward Euler scheme. Numerical experiments for typical spontaneous combustion models show the high sensitivity of TEM for an electrical source to the burned cavities, and based on this we further use the limited-memory BFGS method to do 3D inversions. To obtain high-resolution imaging results, we bound the resistivity based on the measurements to the coal mine. The inversion results show that the 3D TEM inversions can effectively recover the locations and resistivities of the burned cavities, implying TEM is a valid tool for detecting spontaneous coal combustion. [ABSTRACT FROM AUTHOR]