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High-temperature coal oxidation generates a substantial amount of CO and CO2, especially CO, rapidly, which is a primary factor leading to casualties. The oxygen concentration is the predominant factor affecting the high-temperature oxidation of coal, particularly in the generation of CO and CO2. Understanding the generation patterns and relationship characteristics of CO and CO2 under various oxygen concentrations is important for predicting high-temperature coal oxidation and ensuring personnel safety. The paper used TG–MS and FTIR to study the formation characteristics of isothermal oxidation of CO and CO2 in long-flame coal under different oxygen concentrations. The results indicate that there exists an optimal threshold for CO production when the oxygen concentration is about 9% during the isothermal temperature oxidation process at 200.00–350.00 °C. When the oxygen concentration is less than 13%, the influence of oxygen on CO2 production is weakened. As the temperature increases, the pattern of CO + CO2 production and CO/CO2 is reversed, with CO + CO2 increasing and CO/CO2 decreasing. The relationship between the total production of CO and CO2 and the loss of coal mass follows the function y = a + bx at the isothermal temperatures of 300.00 °C and 350.00 °C. An increase in oxygen concentration does not alter the linear relationship. In the isothermal oxidation process of coal, carbonyl and carboxyl groups are the key groups for CO and CO2 production. At 200.00 °C and 250.00 °C, carbonyl and carboxyl groups increase, and other groups are being converted to carbonyl and carboxyl groups while decomposing into CO and CO2. At 300.00 °C and 350.00 °C, the relative content of carboxyl groups decreases. The research findings play a fundamental role in coal mine disaster prevention and control. [ABSTRACT FROM AUTHOR]

Coal spontaneous combustion is a common problem faced by many coal mines. Spontaneous combustion in goaf releases a large amount of harmful gases, polluting the environment while causing a large amount of wasted resources, and even endangering the lives of workers. Due to the collapse of the interior of the mining area, it is impossible to measure the internal gas composition directly. In order to more accurately predict the spontaneous combustion state inside the mining airspace, this paper obtains the CO generation law and the main source of the working face through the combination of laboratory experiments and on-site monitoring. The CO concentration prediction model of the return corner is established with CO as the index gas. Finally, the safe concentration and warning concentration of the working face are calculated according to the example, which provides theoretical basis for the prediction of spontaneous combustion of coal. [ABSTRACT FROM AUTHOR]

The productivity of coal mines is seriously threatened by the combined disasters of gas and coal spontaneous combustion, which have become a common disaster mode. It is unclear how the gas and coal spontaneously combusted in the roof cutting along gob working face. The goal of this study is to identify the distinctive features of combined disasters in gob from two different types of roof cutting along working faces. In these two different types of roof cutting along gob working faces, the paper constructs the permeability model of the gob. The findings demonstrate that the data from the field experiment and the simulation results agree, which validates the simulation's reliability. In contrast to single sided roof cutting along gob working faces, double sided roof cutting along gob working faces clearly has a thinner oxidation zone. Moreover, the oxidation zone of the double side roof cutting along gob working faces is closer to the working face, which is located in the shallow area of the gob 50 m behind the working face. The gas explosion area and the coal spontaneous combustion area are divided by the double side roof cutting along gob working face, which reduces the risk of compound disasters. Important theoretical direction for the prevention and control of gob disasters in the roof cutting along gob working face is provided by the simulation results. [ABSTRACT FROM AUTHOR]

To accomplish various and efficient inhibitions of coal spontaneous combustion (CSC) and solve the safety hazards of CSC encountered in the production and operation of coal mining enterprises, inhibitors play an important role in the prevention and management of CSC. Herein, we report quercetin, which is selection as an antioxidant to prepare a composite solid lipid inhibitor. The concentration of the composite solid lipid inhibitor with the best inhibition effect on the active groups is selected by Fourier pressure infrared experiments, the change pattern of gas content and characteristic temperature released from coal samples during an oxidation process warming process was tested by using a programmed warming test system and simultaneous thermal analysis experiments, and finally, the inhibitory rate and combustion characteristic index were calculated. The results of the research showed that 10 mass% of quercetin had the most impact on the various groups, the highest inhibitor rate of the composite solid lipid inhibitor is 80.67% in the coal low-temperature oxidation process, compared to the raw coal, the heat release of coal treated with the composite solid lipid inhibitor was decreased by 507.65 J g−1, the maximum amount of heat emitted was lowered by 60%, and the flammability index was reduced by 56.4. A composite solid lipid inhibitor containing quercetin developed in this paper indicated high effectiveness in inhibiting CSC, which is vital for coping with the safety management of coal mine production. [ABSTRACT FROM AUTHOR]

Atmospheric dustfall is solid air pollutant, has a major impact on the environment and human health. The objective of this study was to investigate the microscopic characteristics and sources of atmospheric dustfall in open-pit mining coal resource-based city in the arid desert area of Northwest China. The characteristics of size and shape factors, variation of shape factors with size distribution, types of individual particles, and sources of atmospheric dustfall, which were collected in the open-pit mining area and surrounding areas, were analyzed by X-ray diffraction (XRD) and scanning electron microscopy coupled with an energy dispersive spectrometer (SEM–EDS) combined with graphical method and shape factors. The results showed that the atmospheric dustfall in all functional areas was dominated by coarse-grained particles. The shape of the atmospheric dustfall deviated from spherical shape, and with decreasing particle size, the difference in shape factors increased in each functional area. The EDS and XRD analyses indicated the presence of 13 types of particles. The sources were mainly local and included soil dust from each functional area; industrial dust, construction dust, biogenic impurities, fossil fuel combustion, wear products of motor vehicle parts, motor vehicle exhaust emissions, and emission and excreta from biological activities in each functional area except the desert area; emissions from a steel plant in the industrial area; coal-associated ore, coal dust, coal gangue emissions, and emissions from the spontaneous combustion of coal gangue in the open-pit mining area; secondary chemical crystallization products in the industrial area and the open-pit mining area; dust generated by vehicles abrading the surface of the off-mine coal road and in the open-pit mining area. [ABSTRACT FROM AUTHOR]