1. Multistep kinetic study of magnetite reduction by hydrogen based on thermogravimetric analysis.
- Author
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Lu, Xuyang, Xu, Qiang, Kang, Haopeng, Shi, Jian, Cao, Zeshui, Chen, Bin, and Guo, Liejin
- Subjects
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IRON oxides , *MAGNETITE , *THERMOGRAVIMETRY , *HYDROGEN as fuel , *CHEMICAL models - Abstract
The utilization of hydrogen-based direct reduction methods for magnetite ore smelting is an important way to achieve the goal of reducing carbon emissions. At present, the coupling mechanism of the multi-step reaction during the reduction process is unclear, which restricts the understanding of the rate-limiting steps and the accurate description of kinetic parameters. In this paper, the reaction characteristics and multi-step kinetics of isothermal reduction of magnetite by hydrogen with varying concentrations are investigated at 600–900 °C. Results indicate that the coupling relationship between Fe 3 O 4 →FeO and FeO→Fe two steps is temperature-dependent. In the low-temperature range (600–700 °C), the coupling relationship between the two steps can be described by the parallel model. In the high-temperature range (750–900 °C), the coupling relationship can be described by the series model. Meanwhile, the first-step reaction Fe 3 O 4 →FeO is controlled by the nucleation or chemical reaction model, and the apparent activation energies are determined to range from 27.25 to 48.59 kJ/mol. The second-step reaction FeO→Fe is controlled by the combination of nucleation and diffusion models, and the apparent activation energies are determined to range from 30.70 to 45.14 kJ/mol. • Multistep kinetics of isothermal reduction of magnetite by hydrogen are studied by TGA. • The coupling relationship of two-step reduction is found to be temperature-dependent. • The parallel model and series model are used to decouple the two-step reactions in two temperature ranges respectively. • The relationship between activation energy and hydrogen concentration is obtained. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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