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Your search keyword '"Fenske, Dieter"' showing total 3 results
Start Over Author "Fenske, Dieter" Publisher academie des science, centre mersenne
3 results on '"Fenske, Dieter"'

2. A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O

Author

Izarova, Natalia V., Sokolov, Maxim N., Dolgushin, Fedor M., Antipin, Mikhail Yu., Fenske, Dieter, and Fedin, Vladimir P.

Subjects
*CHEMICAL reactions, *AMMONIUM salts, *COMPLEX compounds, *CHEMICAL structure, *PHYSICAL & theoretical chemistry
Abstract

Abstract: Reaction of the ammonium salt of keplerate, [{(MoVI)MoVI 5O21(H2O)6}12{MoV 2O4CH3COO)}30]42– with Gd(NO3)3 leads to complex transformations with [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O (1) as final product. According to X-ray structural data it contains anions [Mo36(NO)4O108(H2O)16]12–, cross-linked into a neutral 2D-framework by Gd3+ ions. To cite this article: N.V. Izarova et al., C. R. Chimie 8 (2005) . [Copyright &y& Elsevier]

Published
2005
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3. Synthesis and crystal structure of a new metal–organic coordination polymer [Fe(4,4′-bpy)3(H2O)2](PF6)2·2(4,4′-bpy)·5 H2O with nanosized channels clathrate large organic molecules

Author

Izarova, Natalia V., Sokolov, Maxim N., Rothenberger, Alexander, Ponikiewski, Lukasz, Fenske, Dieter, and Fedin, Vladimir P.

Subjects
*ORGANIC conductors, *POLYMERS, *IRON compounds, *X-ray crystallography, *MAGNETIC susceptibility
Abstract

Abstract: A new metal–organic coordination polymer [Fe(4,4′-bpy)3(H2O)2](PF6)2·2(4,4′-bpy)·5 H2O (1) (bpy = bipyridine) was prepared. X-ray structural analysis reveals that 1 is a three-dimensional network with nanosized channels constructed from one-dimensional coordination chains via non-covalent interactions between the pyridile rings. The channels clathrate large molecules of free 4,4′-bpy. Magnetic susceptibility measurement confirms the presence of isolated high-spin Fe(II) in 1. To cite this article: N. V. Izarova et al., C. R. Chimie 8 (2005). [Copyright &y& Elsevier]

Published
2005
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