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The spatial heterogeneity of trace element geochemical backgrounds in surface soils poses a significant challenge for accuratly assessing the anthropogenic contributions to soil pollution. To evaluate the natural variation in trace element abundance, the composition and spatial distribution of 50 trace elements across 153 sites in the Hoh Xil Nature Reserve, a pristine region in western China, were determined. While the contents of the rare earth elements and heavy metal(loid)s closely mirror the composition of continental crust, moderate to extremely high spatial heterogeneity was found for these elements. The coefficients of variation (CV) indicate that 46 of the 50 trace elements display moderate to high spatial heterogeneity (10% < CV < 100%), while the remaining ones show extreme spatial heterogeneity (CV > 100%). Notably, the chalcophile elements exhibit particularly high spatial heterogeneity, and the spatial heterogeneity in trace element abundance increased with the geospatial scale of assessment. Normalization of the contents of trace elements with those of rock-forming element, Ti, under different geospatial scales reveals that the intrinsic crustal heterogenity in elemental abundance and the preferential enrichment or depletion of elements due to regional geological processes are the primary factors shaping the spatial viariation in their distribution in the pristine surface soils. The significant spatial heterogeneity in the distribution of trace elements and its fractal characteristics have important implications for evaluating the pollution of surface soils by trace elements and apportioning the contribution of anthropgenic activities based on subtraction of the regional background values., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

Generally, herbicides used in Brazil follow manufacturer's recommendations, which often do not consider soil attributes. Statistical models that include the physicochemical properties of the soil involved in herbicide retention processes could enable greater precision in herbicide dose decision-making. This study evaluated the potential of artificial neural networks (ANNs) to predict the sorption and desorption of the herbicide linuron in Brazilian soils with different attributes. ANNs and multilayer perceptron (MLP) models were built to predict the sorption and desorption of the herbicide linuron. The inputs to the networks were pH, organic matter (OM), clay, cation exchange capacity (CEC), and base saturation (V); the outputs were sorption (Kfs and Qmax) and desorption (Kfd). The performance of the predictive model was assessed by the coefficient of determination (R 2 ), mean absolute relative error (RMSE), mean absolute error (MAE), mean estimation error (MBE), and Pearson's correlation coefficient (r). The best-performing ANNs for predicting Kfs and Kfd comprised the variables pH, OM, CEC, and clay; for predicting Qmax, the ANN comprised the variables pH, OM, and clay. Artificial neural network models have proved to be a valuable tool for predicting the sorption and desorption of the herbicide linuron in soil, helping to minimize environmental impacts by providing accurate estimates and promoting sustainable herbicide use based on soil attributes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

After the ban on polybrominated diphenyl ethers (PBDEs), the replacement of these compounds with organophosphorus flame retardants (OPFRs) has drawn widespread attention worldwide. In arid/semi-arid regions, characteristics such as low precipitation, frequent strong winds, and low soil organic carbon content potentially influence the environmental fate of OPFRs. In this study, we investigated the concentrations of nine OPFRs in water, sediment, soil, air, and dry deposition in Lanzhou, an arid/semi-arid region in China. The total concentration of OPFRs (Σ 9 OPFRs) were 54.8-334 ng/L in water, 37.3-484 ng/g (dry weight, dw) in sediment, 134-510 ng/g (dw) in urban soil, 1.53-6.22 ng/m 3 in urban air, and measured dry deposition fluxes were 119-681 ng/(m 2 ·d). TPrP, TDCPP and TCPP were the primary OPFR individuals in water and sediment, while TPrP, TDCPP and TPPO predominated in urban soil and air. The fugacity approach revealed the environmental fate of OPFRs were mainly: soil-to-air, air-to-water and sediment-to-water. Ulteriorly, intermediate exchange fluxes were calculated. This study reveals that in this climatic region, urban soil acts both as a "sink" for emissions and a "source" for re-emissions into the atmosphere, further emphasizing the significance of atmospheric transport as a critical pathway in this area., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

Pakistan's freshwater shortage and climate events have caused soil nutrient leaching, prompting cities to adopt wastewater irrigation. This study investigates wastewater as a potential source of microplastics (MPs) and heavy metals (HMs), assessing contaminant levels in wastewater-irrigated surface soils (WISS) in district Okara, Pakistan. It further explores potential ecological and human health risks associated with HMs in soil and the impact of MPs on HMs distribution and physicochemical properties. The concentrations of HMs in WISS were within permissible limits (Cd: 0.48, Cu: 17.99, Zn: 29.73, Pb: 19.65, Fe: 8559.5), except for Mn, which was 182.94 mg/kg. MPs abundance ranged from 1850 to 5300 particles/kg, with the most common physical characteristics being fragment shapes (49.6%); black color (40.1%), and small sizes (<500 μm) many physical properties depicted association with HMs and MPs sizes. The structural equation model (SEM) showed a significant impact of MPs on HMs distribution, risk index, and pollution load index, but no significant relationship with physicochemical properties. The pollution indices for HMs in WISS indicated low ecological risk and negligible non-carcinogenic health risks were predicted for both adults and children. However, regular monitoring, enforcement of management and implementation plans, and remediation strategies for HMs and MPs in WISS are highly recommended., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

In-situ stabilization technology offers a cost-effective solution for the remediation of heavy metal(loid) (HM) contaminated soils. However, the lack of a reliable method to assess the long-term effectiveness of HM stabilization significantly impedes the practical application of this technology. To address this gap, we have devised an innovative method that integrates acid rain leaching with dry-wet alternation to evaluate the long-term effectiveness of HM stabilization. We initiate the acid rain leaching process by adding 200 mL of a H 2 SO 4 and HNO 3 solution, with a pH of 3.20, to 20 g of tested soil and stirring at 30 ± 2 rpm for 2 h. After decanting the supernatant, we dried the soil in a water bath at 60 °C. Then repeat this leaching and drying cycle until HM in the leachate either exceed the preset thresholds or become stable. The time-dependent effectiveness of the stabilization is calculated based on the annual average rainfall, and the number of cycles. By using multiple types of soils contaminated with various HM, we demonstrated that this method is versatile and not limited by the types of soil or HM, and exhibits excellent multi-laboratory precision. The method exhibited excellent multi-laboratory precision, with over 82% of samples having a relative standard deviation (RSD) of less than 30%. This method is of significance for not only mitigating the risk of re-contamination from HM reactivation post-remediation, but also broadening the disposal options for remediated soils beyond landfill, thereby fostering environmentally sustainable practices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

Numerous unregulated organic compounds (UOCs) including pharmaceuticals, opioids, and personal care products (PCPs) end up in wastewater. UOC presence in biosolids (a wastewater treatment byproduct), which are applied to soil for different reasons raises environmental and health risk concerns. In this study, two multi-class extraction methods were developed and validated to target 111 UOCs from 8 different major families simultaneously in biosolids and biosolids-impacted soil. One method (M-SPE) is a modified version of EPA 1694, that uses triple solid-liquid extraction and solid phase extraction (SPE). The second method (EMR) is a super-fast method consisting in a single solvent extraction and EMR (enhanced matrix removal)-Lipid dispersive SPE. M-SPE performed better overall with 72 and 54 UOCs extracted with 50-130% recovery for soil and biosolids, respectively, compared to EMR for which only 49 and 43 UOCs achieved within the same range, respectively. EMR performed particularly well for the extraction of low concentration opioids from biosolids. The use of ENVI-Carb as an additional cleanup step and its potential to sorb analytes was also evaluated. Although >75% sorption of 27 UOCs occurred, ENVI-Carb (graphitized carbon) was needed to sufficiently clean extracts prior to injection to avoid precipitation and protect analytical systems. Application of these methods to environmental samples resulted in detection of some flame retardants, opioids, pharmaceuticals, PCPs and phthalates totaling 30 and 26 UOCs in biosolids and soil historically applied with biosolids, respectively. This methodology will be an asset to determining UOC concentrations in biosolids and biosolids-impacted soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

Soil microplastics (MPs) are a substantial threat to soil health, particularly by disrupting soil aggregation. Additionally, MPs undergo aging processes in the soil, which may significantly alter their long-term impacts on soil structure. To investigate these effects, we conducted an eight-month soil incubation experiment, examining the influence of MPs and their aging on soil aggregation. The experiment utilized a factorial design with various combinations of MPs and biochar additions: 1% by weight of 1000-mesh polyethylene and polypropylene MPs, and 5-mm biochar, resulting in six treatment groups: [CK], [PE], [PP], [Biochar], [PE + biochar], and [PP + biochar]. Our findings revealed that both MPs and biochar underwent aging throughout the incubation, evidenced by the formation of oxygen-containing functional groups on their surfaces. Microplastics, particularly polyethylene, primarily affected the 0.5-1 mm and >2 mm aggregate fractions, with average reductions of 21% and 77%, respectively. These adverse effects intensified with the aging of MPs. Contrary to expectations, the addition of biochar was found to exacerbate the negative impacts of MPs on the 0.25-0.5 mm aggregates, with a decrease of 11% associated with PE MPs. The influence of biochar on mitigating the damage caused by MPs to soil aggregation is dependent on aggregate size., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

The adsorption of fluoride by soils influences its mobility and bioavailability. Therefore, the fluoride adsorption process in soils has garnered widespread attention. Yet research on assessing environmental risk based on the characteristics of fluoride adsorption in soil is still limited. Here, a suite of batch experiments were conducted using three soil types with distinct properties. The results demonstrate that soil organic matter (SOM) and pH are critical factors determining fluoride adsorption in soils. Paddy soil (PS) with its higher SOM content has a higher adsorption capacity compared with loessal soil (LS) and brown soil (BS). Under acidic conditions, BS and LS whose Ca 2+ content is higher exhibited a higher adsorption capacity. The fluoride adsorption process in soils may involve electrostatic adsorption, complexation, and precipitation. The desorption results showed stronger fluoride binding to PS and LS than BS, while the fluoride adsorbed onto BS was almost completely desorbed. This research demonstrates that a deeper understanding of regional differences in soil properties is crucial for better studying the migration and accumulation characteristics of fluoride and its bioavailability in various soils. This study provides a theoretical basis for evaluating the bioavailability, exposure risk, and groundwater pollution risk of fluoride in different soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Soil heavy metal (HM) contamination is a major concern in agricultural lands due to its potential to enter the food chain and its adverse health effects. Remediation materials such as biochar (BC) and zeolites (ZE) have been studied for their potential to mitigate risks associated with soil HM contamination. This meta-analysis evaluates changes in the availability of Cd, Cu, Pb, and Zn following the application of BC and ZE to soil, whether applied individually, in combination (BC + ZE), or with additives (BC + ZE + A). Individually, BC reduced the availability of Cd, Cu, Pb, and Zn in soil by 24.0%, 33.0%, 31.3% and 10.1%, respectively; and ZE reduced these levels by 32.4%, 18.8%, 20.3% and 38.9%. Results indicate that, on average, BC + ZE effectively decreases the availability of Cd, Cu, Pb, and Zn in soils by 32.6%, 54.3%, 35.4%, and 18.3%, respectively. The combination with additives, BC + ZE + A, reduced the Cd and Pb availability by 54.2% and 20.9%, respectively. Most studies were undertaken with Cd, representing 59% of observations, followed by Pb, Zn, and Cu, respectively, with 29%, 8%, and 5%. The small number of studies with Pb, Zn and Cu prevented the creation of subgroups involving these three HMs. Notably, the nature of the additive influences the variation in available Cd content in remediated soils. Inorganic additives combined with BC + ZE demonstrated greater effectiveness in Cd remediation, achieving reductions of available content by 86.8%, compared to those containing clay minerals or organic compounds, with reductions of 27.4% and 15.4%, respectively. These findings enhance our understanding of how BC and ZE can be utilized in soil HM remediation and their effectiveness against different metals., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In recent years, microplastic (MP) pollution has garnered significant attention owing to its ability to permeate various ecosystems, including soil. These particles can infiltrate the environment, either directly or through the degradation of larger plastic items. Despite growing concerns, standardized methods for quantification are still lacking. This study aimed to screen for the presence of MPs in agricultural soils while incorporating green analytical principles in the methodology. A density separation followed by centrifugation was employed, based on the principles of the QuEChERS extraction method. This approach minimized sample quantities, reagent consumption, and waste production, ensuring efficient extraction and analysis. Recovery tests using certified soils spiked with pristine MPs, specifically polystyrene, polypropylene (PP), and ethylene-vinyl acetate for larger MPs (3-5 mm), and low-density polyethylene, polyamide 6, and tire wear particles for smaller MPs (15-300 μm), achieved recovery levels exceeding 69% for smaller MPs and over 91% for larger particles. Spectroscopic analysis revealed slight alterations in the Raman spectra of MPs after extraction. Transitioning to agricultural soil analysis has revealed challenges, including spectral interferences. Nine mesoplastics (5-20 mm) were detected, predominantly consisting of PP and polyethylene (PE), along with seven MPs, three of which were individually identified as PE-based, while the remainder were inconclusive, including one fiber. The evaluation of the method's sustainability using the Analytical Eco-Scale and Analytical Greenness Calculator Metric (AGREE), with scores of 82 out of 100 and 0.66 out of 1, respectively, demonstrated its potential as a reliable approach to MP analysis in soils. This study highlights the potential of integrating green analytical chemistry principles into MP extraction methodologies and emphasizes the value of the proposed QuEChERs-based approach for improving the sustainability and efficiency of MP monitoring in agricultural soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

This study examines the contamination levels and sources of 32 metals and metalloids (MMs) in environmental compartments (roadside soil, road dust, and river suspended sediments) of a small urbanized river catchment located in Moscow megacity. MMs partitioning between particle size fractions (PM 1000 , PM 1-10 , and PM 1 ) was analyzed by ICP-MS and ICP-AES methods. The pollution level of particle size fractions with MMs decreases in the following series: road dust > suspended sediments > soils. Absolute principal component analysis with multiple linear regression (PCA/APCS-MLR) shows that in both relatively coarse (PM 1-10 ) and fine (PM 1 ) fractions, traffic emissions are the primary contributors to pollution, whereas natural sources are dominant providers of chemical elements in bulk samples (PM 1000 ). The predominance of fractions with a diameter over 10 μm in all three studied compartments indicates that the mineral matrix of all compartments is formed predominantly by natural material. Across all compartments and their fractions, Sb, Cd, Zn, Mo, W, Sn, Cu, Pb, and Bi are consistently accumulated. PM 1 and PM 1-10 particles of road dust and suspended sediments also absorb Ni and Cr, suspended sediments retain Mn and As, and soils additionally accumulate As. Anthropogenic influence is more pronounced in PM 1 and PM 1-10 particles compared to bulk samples due to a large impact of industrial sources, traffic, construction activities, and waste storage. Polluted soils are an additional source of MMs to PM 1 and PM 1-10 of road dust and PM 1-10 of suspended sediments, and road dust acts as a source of MMs to PM 1-10 of soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Biological soil crusts (BSCs) are the main landscape on the Qinghai-Tibetan Plateau and an ecological indicator of human disturbance. Information about antibiotic resistomes in BSCs on the Qinghai-Tibetan Plateau can provide baseline for the risk assessment and management of resistomes and yet to be explored. This work investigated the profiles and geographic patterns of antibiotic resistomes in BSCs along the Lhasa River and their response to anthropogenic activities for the first time. Various antibiotic resistance genes (ARGs) were widely distributed in BSCs, but had relatively lower detection frequency and abundance comparing to soils from human disturbed sites. ARGs profiles in BSCs were separated by altitude from 3860 to 3880 m, possibly attributing to the difference in anthropogenic activities. Above 3860 m, resistomes exhibited lower abundance including total ARGs, aadA, blaSFO and tnpA-04 owing to the rare human activities; at human disturbed sites with altitude <3860 m, the detection frequency and relative abundance of tetG02, oprJ, qacEdelta1-01, and ARGs with the mechanism of efflux pump were higher and viewed as potential indicators of human activities. Anthropogenic activities potentially promoted the horizontal gene transfer of ARGs in BSCs at human disturbed sites from co-occurrence network analysis. Our findings provided fundamental information of antibiotic resistomes in BSCs on the Qinghai-Tibetan Plateau, and unraveled possible mechanisms of human disturbance in shaping antibiotic resistomes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Dietary intake is a predominant pathway of human exposure to environmental Cadmium (Cd), but wheat (Triticum aestivum L.) has not received enough concerns for its risk of Cd contamination. A field survey of Cd-contaminated rice-wheat rotation farmlands in China provided detailed comparison of Cd accumulation capacity by rice and wheat grains. The results indicated that Cd-BCF of wheat grains (median values 0.42) were obviously higher than those of rice grains (median values 0.12) under wide soil Cd levels and pH ranges. Soil Cd levels rather than pH played a vital role on Cd accumulation by wheat grains, and high wheat grain Cd concentrations (0.12-0.13 mg kg⁻ 1 ) were even observed in mildly alkaline soil that normally have low Cd mobility. Dietary Cd exposure risks were assessed by the crop Cd exposure models considering different soil Cd content, pH and dietary structures of residents. The results indicated that the intake of wheat grains contributed 56.1-86.5% of total crop Cd exposure, with an increase in its contribution with the increase of soil pH. Residents favoring wheat would have a significant Cd exposure risk if consuming crops from soils with Cd levels above 0.41 mg kg⁻ 1 , which was considerably lower than the current soil Cd risk screening value for alkaline soils (0.6 mg kg -1 ). Our findings indicate a high Cd accumulation capacity of wheat grains and consequent risk of dietary Cd exposure, which deserves further exploration on the correlation among soil Cd screening value, grain Cd limit value and its dietary exposure risk., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Sludge landfilling is widely used in China, accounting for approximately 65% of total sludge disposal, due to its simplicity and cost-effectiveness. However, with increasing land scarcity and stricter environmental regulations, the Chinese government has emphasized reducing sludge landfilling. Despite these efforts, sludge historically disposed of in landfills continues to pose risks, including heavy metal leaching and contamination of groundwater and soil. Comprehensive risk assessments for multi-contaminant industrial sludge in long-term landfills remain limited. This study conducted a risk survey and pollution assessment at a long-term sludge landfill in a typical industrial city in China. The sludge at the site was found to be mildly alkaline (pH 7.30-8.29) and had a low calorific value (1.37E+03-1.61E+03 kcal/kg), with significant dewatering challenges (1.23 × 10 15  s 2 /g). The overall pollution load was relatively low, with a regional Pollution Load Index (PLI) of 0.65. However, due to extreme pollutants, the Nemerow Pollution Index (NPI) reached 9.49, indicating severe pollution. The single-factor index assessment indicates high pollution levels for Zn, Sb, BaP, and total petroleum hydrocarbons (TPHs). Ecological risk is primarily associated with Hg, Sb, BaP, InP, and TPHs. However, the weighted comprehensive risk assessment method proposed in the study identifies Zn, Pb, Sb, and TPHs as priority pollutants, with the main pollution hotspots being SZ4, SZ5, and SZ9. Some pollutants, such as Ni, antibiotics, polychlorinated biphenyls, and certain polycyclic aromatic hydrocarbons, were not detected in the sludge. Through principal component analysis and positive matrix factorization analysis, multiple sources of pollution at the landfill were identified, including the dyeing industry, electronics manufacturing, traffic emissions, fuel combustion, and urban runoff. This analysis highlights heavy metal pollution (Cr, Hg, Pb) and organic pollutants (PAHs, TPHs, DBA) resulting from industrial and urban activities. The results offer key insights to guide future sludge treatment and disposal at this landfill., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

Per- and polyfluoroalkyl substances (PFAS) are widely distributed in paddy soils, and their multi-phase partitioning in soil fractions was proved to be strongly interact with soil microbial community composition and functions. Despite this, soil bacterial and fungal metabolic molecular effects on PFAS water-soil interface migration in waterlogged paddy fields still remain unclear. This study integrated soil untargeted metabolomics with microbial amplicon sequencing to elucidate soil metabolic modulations of 15 PFAS interface release. Inhibition of bacterial and fungal metabolic activity both significantly altered PFAS cross-media translocation (p < 0.05). Gemmatimonadota, Desulfobacterota, Acidobacteriota, Actinobacteriota, and Bacteroidota were vital bacterial taxa affecting PFAS transport, while Basidiobolomycota and Chytridiomycota were vital fungal taxa. Fungi regulated PFAS migration more (R 2  = 0.379-0.526) than bacteria (R 2  = 0.021-0.030) due to the higher metabolic stability of stochastic-dominated fungi than deterministic-dominated bacteria. At the water-soil interface, the amino acid-like dissolved organic matter (Tyrosine and Tryptophan) contributed most (48.5-58.6 %) to the PFAS multiphase distribution. Untargeted metabolomics further clarified that fungal amino acid-like metabolites, including Phosphoenolpyruvate and Methionine, were key triggers stimulating Tyrosine and Tryptophan biosynthesis (p < 0.001), which were vital in modulating PFAS interface translocation (p < 0.001). These results provide novel insights into soil microbial metabolites' participation in PFAS water-soil interface migration, benefiting PFAS pollution control and agricultural security risk assessment in waterlogged paddy ecosystems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The strong pest pressure on intensive banana cultivation in the French West Indies led to the intensive use of chlordecone (an organochlorine insecticide) between 1972 and 1993. Due to its high toxicity for the population and the environment, many studies were conducted on the transfer of chlordecone over the last 20 years. However, most studies focused on the dissolved fraction of chlordecone, while the particle-bound fraction was understudied. Therefore, this study reconstructs pluri-decadal erosion rates (i.e. 1980-2023) and associated chlordecone particle-bound transfers from soil and sediment cores sampled in a cultivated headwater catchment (Saint-Esprit, Martinique). Based on sediment accumulation analyses in an agricultural reservoir, high erosion rates (i.e. 10 t ha -1 yr -1 ) were found in the investigated catchment during the study period, with values exceeding the estimated tolerable soil loss rate in tropical contexts (i.e. 2.2 t ha -1 yr -1 ). Based on the analysis of soil cores sampled along a banana plantation hillslope, this study highlights the formation of colluvial deposits with high levels of chlordecone contamination. When these areas are affected by erosion processes, this leads to massive remobilization of particle-bound chlordecone to water bodies. Indeed, in sediment sampled in the downstream reservoir, we observed a drastic increase in these transfers since 2006, synchronous with changes in agricultural practices. This study therefore highlighted the occurrence of legacy contamination at toeslope positions, which was estimated to potentially persist for 4000 to 11,000 years. Such a residence time highlights the need to implement changes in land management to effectively reduce erosion of agricultural soils, particularly in areas identified as "temporary deposition zones" for chlordecone contamination, in order to protect downstream water bodies from chlordecone transfer. To achieve this, agricultural practices that may increase soil erosion, such as herbicide application or intensive ploughing, should be minimized. Overall, this study improved our understanding of erosion and associated chlordecone transfers in tropical environments., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Remi Bizeul reports financial support was provided by the Prefecture de Martinique. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

PAH extraction methods have been widely studied over the last decades. However, there is still no consistent method for contaminated soils. Here, for the first time, PAH source characteristics in soils were considered for the investigation of different pretreatment methods, extraction techniques and solvents in nine petrogenic to primarily pyrogenic urban soils. Sources were identified by macroscopic identification of source substrates and analysis of 71 PAH and alkylation patterns. The comparison of extraction solvents revealed that a combined sequential extraction using dichloromethane (for petrogenic PAH) and toluene:methanol (6:1) led to the highest extraction efficiencies for all samples and is therefore best suited for PAH analysis of unknown samples. Acetone:n-hexane led to the lowest extraction efficiencies for all samples and is not recommended as extraction solvent. The comparison of extraction techniques showed that Pressurized Solvent Extraction is more efficient than ultrasonic extraction especially for petrogenic PAH, but also for pyrogenic PAH. Grinding increased PAH extractability considerably but mainly for petrogenic PAH from bituminous coal particles. In mixed to primarily pyrogenic samples with a smaller proportion of coal, the enhanced extractability of coal leads to a more petrogenic PAH distribution and consequently a decrease in the source identifying PAH Alkylation Index. It is concluded that PAH contents in unknown (urban) soils, where pyrogenic and petrogenic PAH can be present, cannot generally be compared if different extraction techniques, different extraction solvents and grinding or no grinding are applied. As extraction efficiency increases with more effective methods and solvents for bituminous coals, it is recommended to define a specific extraction technique and solvent mixture for improved comparability in future PAH analyses., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Predicting the natural distribution of heavy metals (HMs) in soil is important to understand the potential risk of pollution. However, suitable technologies are still lacking for wide scale due to the large spatial heterogeneity. In this study, we developed machine learning models for predicting natural contents of five typical HMs in soil, including As, Cd, Cr, Hg and Pb. It was found that the optional random forest (RF) model had the best performance with the R 2 up to 0.64. Based on this model, potential distribution of the five HMs explored that elevated contents were mainly concentrated in the southwest and south central of China. Feature analysis illustrated that importance of natural factors followed the order of geological attributes > soil properties > climatic conditions > ecological functions. In particular, lithology of the parent material dominated the content of metals, with the contributions of 18-25%. Moreover, soil properties of pH, cation exchange capacity, profile depth of soil and vegetation coverage had different influences on HMs, due to the variability in the properties of different HMs. This study developed a mapping relationship between natural factors and soil HMs by data science method, which may provide instructive information for pollution control and planning decisions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The accuracy of soil heavy metal pollution mapping is heavily reliant on the sampling strategies utilized in both the preliminary and detailed survey stages of site investigations. This study introduces an entropy-informed multi-stage sampling design (EIMSD) method that leverages preliminary survey data as background information and utilizes relative entropy to progressively select sampling points in detailed surveys. Results indicate that the EIMSD method outperforms the grid sampling design (GSD) and conventional sampling design (CSD) methods across both hypothetical and real-world study areas. This superiority is evidenced by a notable rise in R 2 values, ranging from 6.4% to 60.4% and a decrease in RMSE values from 16.7% to 54.0% relative to GSD, and a similar trend with an increase in R 2 values from 6.7% to 44.1% and a reduction in RMSE values from 16.5% to 39.7% when compared to CSD. This study also investigates the optimal configurations for EIMSD, focusing on the number of detailed sampling points per stage (N add ) and the ratio of preliminary-to-detailed survey sample sizes (N p /N d ) when the sum of N p and N d is held constant. Our findings highlight that adding one detailed sampling point per stage (N add  = 1) is the most effective. For areas with strong spatial variability, a larger N p /N d value of approximately 3/2 is recommended, whereas a ratio close to 1 is apt for areas with moderate variability. Conversely, for areas with weak variability, a smaller N p /N d value of about 2/3 is advised. EIMSD provides a more detailed and accurate map of soil heavy metal contamination, facilitating more targeted and effective remediation strategies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The Arctic region, including Svalbard, faces unique environmental challenges from the presence and persistence of organochlorine pesticides (OCPs), pollutants known for their long-range atmospheric transport and potential local sources. In Svalbard, the melting of sea ice and glaciers due to climate change may release OCPs trapped over decades, while human activities in the area could contribute additional local contamination. This study aimed to identify and quantify different sources of OCPs in soil and marine sediments at Svalbard. Samples were collected from Kongsfjorden, Rijpfjorden, and in Ny-Ålesund. The concentrations of 23 OCPs in sediments sampled were in the range of 0.36-0.90 ng/g, which were lower than those in the soils from Ny-Ålesund (0.28 ng/g to 3.6 ng/g). The highest OCP levels were detected at locations near the research station in Ny-Ålesund, where local contamination from research activities, mining, and dumpsites could occur. Hexachlorobenzene (HCB) were the most prominent compound, followed by various DDTs and HCHs. Dignostic ratios and the Positive Matrix Factorization (PMF) model were employed to determine the primary sources of OCPs. The results from modeling showed that historically used pollutants were the primary contributor, accounting for 90% of OCPs present, while recently input OCPs were a minor contributor. However, newly input pollutants significantly contributed to HCHs (43%). It is suggested that the contribution of legacy OCPs mainly comes from the melting of sea ice and glaciers. This was especially true for Rijpfjorden (95%), while it was also significant for Kongsfjorden (55%). The local contamination and fresh inputs played a substantial role in the area near the research station in Ny-Ålesund. The study emphasizes the importance of secondly source, especially the role of melting sea ice and glaciers as well as local contaminations as sources of OCPs in Svalbard's marine sediment, which highlight the urgent need to address the impact of climate change on the Arctic environment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

The nationwide prevalence of brownfields, with often unknown types and quantities of subsurface chemical contaminants, highlights the need for rapid, cost-effective, and noninvasive methods to reduce routes of exposure. In post-industrial cities such as Detroit, Michigan, anthropogenic volatile organic compounds (VOCs), known to negatively impact human health, are typically detected at brownfields through conventional methods, e.g. screening soil, and groundwater. Recently, the method of phytoscreening-the chemical analysis of plant tissues to provide evidence for belowground contamination-has become a viable alternative to conventional methods. However, few studies have been designed to directly compare conventional and plant-based methods of detecting VOCs. To fill this knowledge gap, we sampled and compared the concentration of six VOCs including BTEX, PCE, and TCE detected in conventional media (soil, soil vapor, groundwater, sewer vapor) and different plant tissue (tree core, leaf, root, shoot) at two brownfields sites in Detroit: an abandoned gas station with a leaking underground storage tank, and a former dry cleaning facility. Our results suggest that the concentrations of VOCs detected in plants are similar to or in some cases greater than conventional methods and can differ across the growing season. For example, leaves and roots detected, on average, a higher concentration of VOCs compared to shoots and tree cores, however, TCE and PCE were generally in higher concentrations in soil and soil vapor. Moreover, the frequency at which conventional versus phytoscreening methods failed to detect VOCs was similar at one site and higher at another, suggesting that phytoscreening may yield fewer non-detects at known sites of contamination. While additional work is needed to understand the relationship between concentrations of VOCs detected in soil versus co-located plant samples, our results suggest that phytoscreening may be a viable and reliable method to detect belowground chemical contaminants while reducing screening times and cost, and increasing access to private property., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Despite extensive ecotoxicological evidence on the adverse effects of oil pollution on rodents, little is known about how rodents make decisions in oil-polluted environments (i.e., outside of lab settings). We investigated the foraging behavior of Allenby gerbils, Gerbillus andersoni allenbyi (GA), that were presented with feeding trays in a semi-natural environment. The trays contained seeds mixed into one of three types of soils - clean soil, and two different soil samples collected from two well-documented terrestrial oil spill sites in Israel. The oil spill disasters occurred in 1975 and 2014 and the spill sites are located within a few hundred meters of each other, in the 'Avrona Nature Reserve in the Arava hyper-arid region in Israel. Gerbils of both sexes avoided foraging in 2014-polluted soil, but surprisingly, they foraged more in 1975-polluted soil. Our results indicate that for the GA, the 1975-polluted soil is an advantageous substrate to forage on, probably because its texture facilitates more efficient foraging, leading to greater energetic gain, and creating a trade-off between energetic gain and perceived foraging cost due to its pollution. We also proceeded to investigate some physiological consequences of chronic exposure to the 2014-polluted soil in the laboratory. Chronic oil exposure did not lead to mortality or weight loss, but female gerbils exhibited heightened cortisol. We conclude that terrestrial oil pollution may have significant sublethal impacts on animal behavior, even when there is no obvious short-term physiological cost to the exposure., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Phytostabilization is an important way for the remediation of mine tailings, but the associated microbial processes and community succession remain largely unknown. In this study, we investigated the assembly mechanisms maintaining the core and satellite subcommunities diversity during phytostabilizaion of a mercury-rich mine tailings. The contents of total Hg and methylmercury decreased with a concomitant increase of total and available phosphorus content along the successive remediation stages. Microbial community composition, profiled by 16S rRNA gene sequencing, revealed amplicon sequence variants (ASVs) that were separated according to their abundance within either the core community or the satellite community. Community dynamics analysis showed that alpha diversity indices increased for the core community while decreased for the satellite community. Both satellite and core communities were mainly driven by stochastic drift process, and homogeneous selection was relatively higher in shaping the core community organization. The core community included ASVs affiliated to Proteobacteria, Crenarchaeota, Bacteroidota, Verrucomicrobiota, Acidobacteriota, and Myxococcota phyla, which were driven primarily by heterogeneous selection and drift. The satellite community included ASVs affiliated to Acidobacteriota, Ktedonobacteria, Anaerolineae and Verrucomicrobiota phyla, which were mainly influenced by heterogeneous selection. Nineteen taxa and one taxon were identified as keystone taxa for the satellite and core communities respectively. This study provides important insights on the assemble rules within the core and satellite communities, and theoretical guidance for further ecological restoration and management during microbial remediation of metal-mined derelict land., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The macroplastics (MaPs) and microplastics (MiPs) polluting agricultural soils raise great concerns. Unfortunately, scientists know little about the occurrence of MaPs/MiPs in soil among different farming systems. In this study, we analyzed MaPs/MiPs in soils (0-30 cm) collected from six different farming systems (wheat-maize rotations, cotton, vegetables, permanent orchards, greenhouses with and without mulching) in Quzhou county, the North China Plain, by using fluorescence microscope and micro-Fourier transform infrared spectroscopy. The results showed that the abundance of MaPs and MiPs ranged from 0.2 to 46.8 kg ha -1 , and 4.1 × 10 3 -3.7 × 10 4 items kg -1 , respectively. The prominent colors of the MaPs were white and black. The predominant shape, size and chemical composition of soil MiPs were fragments (45-62%), <1 mm (98-99%), and polyethylene (38-43%), respectively. MaPs were mainly detected in the 0-10 cm soil layer. MiP abundance in the 0-10 cm soil layer was significantly higher than that in the 20-30 cm soil layers among different farming systems, except for the fields with wheat-maize rotations and permanent orchards (p < 0.05). Overall, cotton fields showed the highest MaP and MiP abundance, followed by vegetable fields and orchards. Redundancy analysis revealed that tillage practices and plastic film management greatly influence the size distribution of MiPs. A strong negative correlation between large-sized plastic fractions (0.2-1 mm) and tillage frequency was tested while the years of application of plastic films and the abundance of plastic residues showed a strong positive correlation with small-sized plastic fractions (<0.2 mm). Our findings conclude that agricultural mulch films are an important source of MaPs and MiPs in agricultural soil and distributions are strongly influenced by agricultural management practices and farming systems. Further studies should take farming systems and farming practices into account, thereby exploring the potential mechanisms of plastic fragmentation and granularization in agricultural soil., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

A 90-day soil incubation study was performed to investigate impacts of four types (PE, PP, PVC and PET) of microplastics (MPs) on the physicochemical properties, nutrient contents, enzyme activities, and microbial community structure and diversity of agricultural soils. Effects of the four microplastic types and addition ratios on the microbiology of the agricultural soils were significant. With the addition of MPs, there was a positive correlation between physicochemical properties, nutrients (AN, AP, AK) and enzyme activities (CAT, Urease, ACP, SUC), which were all decreased to some extent. Overall PE and PVC surfaces were the roughest and had the greatest impact on soil physicochemical properties, nutrients and enzyme activities. The changes in soil microbial α-diversity were not significant (P > 0.05), but, PP and PVC led to an increase in community diversity and abundance. Clearly, the four types of the MPs reduced the physicochemical properties, nutrient content, enzyme activity and microbial community, and thus significantly affected the microbiology of the farmland soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

The reuse of treated wastewater (TWW) for irrigation is widely applied to alleviate pressure on freshwater resources. However, TWW contains antibiotics that once in soils, can exert selective pressure, promoting the emergence and spread of antimicrobial resistance (AMR) in the environment. Current environmental risk assessments for antibiotic residues rely on indicators such as Predicted No Effect Concentrations (PNECs), usually determined in liquid media. These PNECs aim to predict antibiotic concentrations that may promote resistance in the environment. Given the complexity of soil matrices, few studies have established PNEC values for soil, which likely differ significantly from aquatic environments. To address this gap, we developed a simplified experimental model using soil microcosms irrigated with TWW and the antibiotic sulfamethoxazole (SMX) to estimate threshold concentrations favouring resistance transfer or/and emergence within the soil microbiome. We identified SMX concentrations between 0.01 and 0.1 mg/kg dry soil that likely increased the abundance of sulfonamide resistance genes in soil. A time window of 1-7 days post-exposure showed a temporary rise in sul1 and intl1 gene abundance (over 1 log/soil 16S rDNA), the appearance of SMX transformation products, and an increase in some Rhodocyclaceae. After 1.5 months of incubation and complete SMX transformation, the relative abundance of sul1 and intl1 remained about 0.5 log higher than in SMX-free controls and soils with SMX levels below 0.1 mg/kg dry soil . A persistent transformation product, 4-N-glucuronide-SMX, was also observed. Here, the estimated PNEC for SMX in soil, between 0.01 and 0.1 mg/kg, exceeds typical SMX concentrations found in soils exposed to TWW. This may suggest low impact on resistance selection for this compound in the context of TWW exposure. However further studies on other soils, water, and antibiotics need to be conducted to expand our knowledge on soil PNECs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

An in-depth investigation of the maximum environmental load is crucial for soil security and pollution prevention. This research focused on soil environmental carrying capacity (SECC) for different risk receptors in a Chinese industrial city. By determining risk threshold for various land use types, we integrated mass balance and iterative models to capture dynamic net input fluxes with spatial heterogeneity. This enabled quantitative characterization of Benzo(a)pyrene (BaP) SECC through top-down and bottom-up approaches (corresponding to duration (D) and rate of regional emission, respectively). The thresholds were in the order of agricultural land < residential land < forest < industrial land < park. The top-down analysis showed D increased ∼1.5x with a 5% input flux decline until 2031. The bottom-up analysis suggested industrial emissions decreased by approximately 10% as the pollution control period was extended from 20 to 50 years. Both methods showed that at maximum background values (C 0 ), D was ∼4x and the industrial emission rate was ∼10% higher than at minimum C 0 . SECC values near industrial areas significantly decreased, even reaching negative values, signifying complete carrying capacity loss. This study provided an approach to the dynamics of SECC under diverse scenarios, aiding informed decision-making for sustainable land management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Chlorfenapyr is a frequently used insecticide in vegetables, and understanding its translocation and distribution are important for determining the residues and dietary safety in these crops. In this paper, we studied the translocation, subcellular distribution, and dissipation of chlorfenapyr and tralopyril in soil-cultivated cherry radish. Both upward and downward translocations were observed for the analytes, although the extent was limited, as indicated by the bioconcentration and translocation factors (both <1). The analytes were primarily accumulated in the cell walls. Chlorfenapyr dissipated rapidly with half-lives of 5.90-7.10 d. Tralopyril can prolonged the dissipation rate of chlorfenapyr due to the total chlorfenapyr's half-lives of 7.20-9.46 d. The dietary risk for consumers can be neglected, when the sampling interval was 10 d. This study provided additional information on the translocation, distribution, and application method of chlorfenapyr in cherry radish and assessed the potential threats of chlorfenapyr to human health., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025 Elsevier Ltd. All rights reserved.)

Microplastics (MPs) pollution has become a vital global environmental issue. However, comprehensive understanding of the ecological risks of MPs in soils of Northeast Tibetan Plateau still requires further study. In this study, we used the Agilent 8700 Laser Direct Infrared (LDIR) spectroscopy to analyze the characteristics of 10-1000 μm MPs in soils of different vegetation types throughout the Qilian Mountains basin, and to comprehensively explore the ecological risks of MPs in various ecological environments. The results indicate that MPs abundance is highest in soil of shrub areas (26,369 ± 32,147 items kg -1 -dry weight (dw)), followed by woodland (22,215 ± 22,544 items kg -1 -dw), desert (17,769 ± 9,040 items kg -1 -dw), grassland (16,462 ± 12,872 items kg -1 -dw), and forest (15,662 ± 13,857 items kg -1 -dw). MPs in soils of different vegetation types show similar physical and chemical characteristics, with the shape dominated by fragments (93%-96%), followed by fibers and a few beads, with dominant sizes of 10-30 μm (63%-76%), and polymers dominated by polyamide (PA) and polyethylene terephthalate (PET). Additionally, the environmental risks posed by the fundamental characteristics of MPs have been quantified through the Pollution Load Index (PLI), Pollution Hazard Index (PHI), and Potential Ecological Risk Index (PERI) models. According to the PLI assessment, the current levels of MPs in the environment have not yet imposed significant burdens on the ecosystem. However, the results of PHI and PERI indicate a higher risk of MPs pollution in the Qilian Mountains. This study offers vital information for MPs pollution in the whole Qilian Mountains regions and their potential environmental risks in remote areas' soil., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Hexachlorocyclohexane (HCH) is an organochlorine synthetic substance composed of different isomers (α-, β-, γ-, δ-, and ε-HCH), but only γ-HCH isomer or lindane has insecticidal properties. From 1984 to 1992, INQUINOSA Company dumped HCH wastes in the Bailín landfill (Sabiñánigo, Spain), and in 2014 these HCH residuals were transferred to a secure landfill, dispersing a small amount of HCH-isomers in the surrounding area. To explore the spatial distribution of this pollution, we evaluated HCH concentration in the soil-vegetation system around the Bailín landfill site. Physicochemical properties showed a greater percentage of organic matter, cation exchange capacity, carbon content, and conductivity in soil samples, while only pH increased in subsoil samples. Our findings also revealed that the concentration of HCH-isomers is very heterogeneous in topsoil samples from <1 μg/kg to 780 μg/kg, whereas in subsoil samples fluctuated from <1 μg/kg to 70 μg/kg. Moreover, the accumulated HCH-isomers among species and plant tissues displayed large variations, with pine needles showing the greatest values. Interestingly, spatial distribution of HCH contamination was mainly concentrated close to the old landfill and secure landfill, suggesting that the removal processes largely influence soil contamination. Correlation of HCH levels in soil and plant material suggests that HCH uptake onto plants was accomplished either by translocation from soil via the root system or by deposition from air into the above-ground parts of the plants. As HCH-isomers are hydrophobic compounds that tend to be adsorbed by soil organic matter, HCH probably do not leach into groundwater, and the main sinks are surface runoff, volatilization, and degradation. However, more studies would be required to assess the potential sinks of HCH wastes in the Bailín landfill site., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Numerous studies have been conducted to investigate the impact of microplastics on soil eco-system, yet little attention has been given to the specific effects of mulch microplastics and the leaching of plastic additives from mulch films. This review inspects the propensity of commonly used plastic additives in mulch films, such as Di(2-ethylhexyl) phthalate (DEHP), bisphenol A (BPA), and benzophenones (BPs), to migrate into soils and pose potential risks to soil biota. Further, we highlight the degradation of non-biodegradable plastic mulch films over time, which leads to an increase in the release of plastic additives and microplastics into agricultural soils. DEHP has been detected in high concentrations for example 25.2 mg/kg in agricultural soils, indicating a potential risk of uptake, translocation and accumulation in plants, ultimately altering soil physicochemical properties and affecting soil microflora and invertebrates. The review also explores how exposure to ultraviolet (UV) radiation and microbial activities accelerates the weathering of mulch films. Moreover, the resultant plastic additives and mulch microplastics can lead to genotoxicity and growth inhibition in earthworms (Eisenia fetida) and negatively impact the soil microbiome. Despite the significant implications, there has been a lack of comprehensive reviews comparing the effects of non-biodegradable mulch film additives on agricultural soil flora and fauna. Therefore, this review addresses the knowledge gaps providing a bibliometric analysis and eco-toxicological evaluation, discussing the challenges and future perspectives regarding mulch plastic additives and microplastics, thus offering a comprehensive understanding of their impact., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Fluoride (F) pollution in soils, which can be caused by long-term application of phosphate fertilizers, has serious socio-economic and ecological impacts. Therefore, it is important to find economically viable and environmentally friendly remediation technologies that mitigating the potential hazards of F-contaminated soil while maintaining crop yields. In this study, a soil incubation experiment was carried out to investigate the effects of two different organic manures at various amounts on soil F content and soil properties. We demonstrated that organic manure application at a rate of 5% was optimal to control the content of available fluoride (AE-F) in soil. Organic manure decreased the AE-F content and increased the residual or organically bound content. Furthermore, organic manure application also increased the contents of carbohydrates, proteins, and amides, which can anchor AE-F to the dissolved organic matter (DOM) in soil through physicochemical reactions, thereby reducing the migration of F. Moreover, after organic manure application, complex humus compounds were formed through microbial action, thus reducing the bioavailability of soil F. In summary, the application of organic manures can reduce the accumulation of soil AE-F, thereby reducing the absorption of F by crops in F-contaminated soil and alleviating the potential risk of F contamination., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The widespread and extensive use of pesticides in European crop production to reduce losses from weeds, diseases, and insects may have serious consequences on the ecosystem and human health. This study aimed to identify 20 active substances of high health risk, based on their detection frequency within and across the environmental matrices (soil, crop, water, and sediment) and to identify their associated hazardous effects. A sampling campaign was conducted across 10 case study sites in Europe and 1 in Argentina and included conventional and organic farming systems. In 31% of cases, the detected substances were found at a higher concentration in the soil than in the corresponding crops, 93% of the compounds were fungicides, and the remainder were insecticides. 43% of the substances, 57% of which were insecticides, were detected only in soil. There was a clear relationship between soils and crops in terms of contamination, but not between water and sediment. Portuguese soil (wine grapes) had the highest number of substances (12) with average concentrations (AC) varying between 1 and 162 μg/kg, followed by French (11 substances in wine grapes) (1≤AC≤64 μg/kg) and Spanish soils (9 substances in vegetables) (3≤AC≤59 μg/kg). The crops corresponding to these soils contained a relatively high number of detected substances and several in high average concentrations (AC). The risk quotient was consistently higher for conventional farms than for organic farms. For the soils from conventional farms, 5 active substances (chlorpyrifos, glyphosate, boscalid, difenoconazole, lambda-cyhalothrin, and one metabolite: AMPA) were considered high risk. For water samples, 2 substances (dieldrin and terbuthylazine) found were high risk, and for sediment, there were 3 substances (metalaxyl-M, spiroxamine, and lambda-cyhalothrin). There were 6 substances detected in crops that are suspected to cause human health effects. Uncontaminated soil is a prerequisite for the adoption of sustainable alternatives to pesticides. Efforts are needed to elucidate the unknown effects of mixtures, including biocides and banned compounds in addition to the substances used in agriculture., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Plastic pollution, a global threat to environmental and human health, is now ubiquitous in the environment, including agricultural soils receiving urban compost amendments. Yet, the accumulation pattern of microplastics in soils are still to be disentangled, with regards to their sources and/or their physical properties such as morphotypes. The aim of this study was to identify the accumulation patterns of coarse microplastics (CMP) resulting from the long-term amendment of soil with urban waste composts. To this end, we used a field experiment receiving three different urban composts derived from municipal solid waste, biowaste, and a mixture of sewage sludge and green waste. We isolated 1417 coarse microplastic particles from a 21-year archive of soil and compost samples, using density fractionation followed by oxidation, and used Py-GC/MS for polymer identification. Different compost types led to different coarse microplastics accumulation levels. The accumulation pattern showed increasing CMP contents in soils over time. After 21 years of experiment, the calculated number of CMP was in accordance with the estimated values for all three compost types but it was not the case for the CMP mass. No difference of evolution pattern was found between films and fragments. We proposed that biotic transport or abiotic weathering and fragmentation could explain such differences in CMP evolution pattern., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The environmental contamination of ultraviolet absorbents (UVAs) has attracted global attention for the persistence, bioaccumulation and ecotoxicity. However, little is known about the content and distribution characteristics of UVAs in agricultural soils, especially in facility agricultural soils. In this study, the contents and distribution characteristics of 16 UVAs were surveyed in agricultural facility soils (N = 61) and field soil samples (N = 61) from 27 provinces in China. The total content of 16 UVAs (Σ 16 UVAs) in facility soils (mean 64.2 ± 55.4 ng/g) was higher than that in field soils (mean 9.66 ± 7.66 ng/g), suggesting that UVAs in facility soils are associated with mulch film. The Σ 16 UVAs content in the soil mulched with biodegradable (PBAT) film was higher than that in the soil mulched with polyethylene (PE) film, which indicated that the UVA pollution in the soil mulched with biodegradable film was more serious. With the continuous promotion of the use of biodegradable films may pose a threat to soil and ecological health. Therefore, studies on the content and distribution characteristics of UVAs in facility soils are needed to provide scientific basis for the controlling and monitoring of novel pollutants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Volatile per- and polyfluoroalkyl substances (PFAS) are prone to transport among various environmental media, with the soil-air interfacial migration process being an important pathway that significantly influences their environmental fate. To assess the migration and transformations of target volatile PFAS at contaminated site using compound-specific stable isotope analysis (CSIA), it is necessary to understand the isotopic fractionation that occurs during their transfer from soil to air. We have established methods for pre-treatment and GC/CSIA analysis methods of target volatile PFAS in soil and air samples and ensured the accuracy of carbon isotope analysis. GC/IRMS δ 13 C measurements showed optimal precision at instrumental response above 1.35-2.75 Vs, with recommended minimum on-column C levels of 1.67-5.00 nmol for target volatile PFAS. Stable carbon isotope fractionation factors related to the soil-air interfacial migration process for target volatile PFAS were determined by performing laboratory simulations. The observed ε soil-air values are all negative, suggesting that the soil-air interfacial migration process for target volatile PFAS is kinetic fractionation, the removal of molecules containing lighter isotopes. By comparing the simulated and experimentally observed δ 13 C (‰) values of target volatile PFAS, we found consistent trends in the soil and inverse trends in the air. These δ 13 C (‰) values and the related isotope fractionation model provide valuable insights into the isotopic behavior of target volatile PFAS during soil-air interfacial migration process, aiding in the assessment of their environmental fate., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

A method utilizing liquid-liquid extraction (LLE) coupled with liquid chromatography-tandem mass spectrometry (LC-MS/MS) was developed and validated according to the Commission Implementing Regulation (CIR) EU 2021/808 for quantifying four tetracyclines (TCs) in potatoes and soil. The method demonstrated recovery values ranging from 70 to 121% and precision (repeatability and within-laboratory reproducibility), with coefficient of variation (CV) values below 18% for all TCs in both matrices. The limits of quantification (LOQs) for the TCs ranged from 0.90 to 1.87 μg/kg in potatoes and from 0.68 to 1.25 μg/kg in soil. The decision limit (CCα) and detection capability (CCβ) ranged from 10.4 to 12.3 μg/kg and 11.9 to 14.3 μg/kg, respectively. Analysis of 538 potato and soil samples from Egyptian farms revealed a 13.2% occurrence of TC residues, with a higher frequency in soil (19.33%) than in potatoes (7.06%). Target hazard quotient (THQ) values indicated that TC residues in potatoes do not pose a health risk to Egyptian consumers., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Freeze-thaw (FT) cycle would greatly influence the fate of plastic particles (one of emerging contaminants with great concerns) in soils, yet its impacts and mechanisms remain unclear. The vertical migration/release behaviors of plastic particles (with diameters of 0.2 μm and 1 μm) in two natural soils and one model soil (i.e. quartz sand) without/with FT treatments (1 and 3 cycles) were examined. Owing to the presence of Fe/Al oxide minerals, finer pore structure, and uneven surfaces of natural soils, the breakthrough ratio of plastics in two natural soils was over 25% lower than in quartz sand. However, regardless of porous media type, FT processes (increasing cycles) significantly promoted the remobilization of plastics initially retained in three media during the subsequent water flushing processes. Via theoretical calculation, tracer experiments, and visible chamber experiments, the mechanisms driving plastics release from natural soils subjected to FT treatments during the water elution processes were determined to be different from those from pure quartz sand. The change of sand local configuration (the rearrangement of local sand pore spaces) during FT process mainly drove to plastics released from quartz sand columns. While the alteration in local soil configuration, the formation of preferential pathways, and increased release of soil particles contributed to plastics remobilization from soil columns subjected to FT. Clearly, FT processes significantly increased the vertical migration of plastics in soils potentially to groundwater, enhancing environmental risks of plastics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Cadmium (Cd) pollution in rice paddies, attributable to high geological Cd backgrounds, has emerged as a global concern. This study leverages the passivation mechanism of bioavailable Cd by iron-organic matter associations (Fe-OM) to explore a novel strategy for Cd immobilization. We examined the adsorptive capacity and removal efficiency of Cd by laccase-mediated Fe-OM association and assessed their natural stability using 57 Fe isotopic tracing. Additionally, we conducted in-situ remediation trials in a Cd-enriched paddy soil. Our results indicate that the theoretical maximum adsorption capacity for Cd by the laccase-mediated Fe-OM is 100.0 mg/g, which is a 15% improvement over the common Fe-OM and a 150% enhancement over inorganic iron oxides (ferrihydrite). The 57 Fe isotope tracing test showed that the affinity of laccase-modified organic matter for iron increased by 55.6%, and it exhibited better stability than common Fe-OM under anaerobic conditions. The field-scale remediation, predicated on the in situ synthesis of Fe-OM association, effectively reduced the bioavailable Cd concentration in the soil from 0.91 mg/kg to 0.40 mg/kg. Concurrently, the Cd concentration in rice grains was lowered from 0.63 mg/kg to 0.15 mg/kg, thus falling beneath the national safety threshold. This study represents a significant advancement in the safe reclamation and utilization of agricultural soils with elevated geological Cd burdens., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Microplastics (MPs) are widely detected in the soil of the Qinghai-Tibet Plateau with increasing economic activities. However, studies concerning the driving factors affecting the presence of these surface soil MPs for the typical regions with different geographic conditions are still lacking. Here we chose three representative regions (Ali, Yushu, and Haixi) from east to west across the plateau to investigate the distribution and further explore the contributing factors of surface soil MPs. The Spearman rank correlation, Geodetector, Random Forest Regression and Principal Component Analysis were used to unveil how the driving factors influence MPs distribution across the plateau. The results revealed that the MPs abundance, type, size, color and polymer across the Ali, Yushu, and Haixi were different. Microplastic abundance was inversely correlated with the distance from roads and residential areas, but was positively related to precipitation. Moreover, traffic elements were the primary source of MPs pollution in the Ali and Yushu but residential activities were the leading source of MPs contamination in the Haixi. Besides, backward trajectory simulations suggested that atmospheric transport may also contribute to the presence of soil MPs in the representative regions. These results further indicated that different regions may require different measures for controlling MPs pollution in surface soil. This study provides new insights into the distribution and source of MPs and further offers valuable methodology for future research aimed at uncover driving factors contributing MPs pollution across different regions with various geographical conditions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Electronic waste (e-waste) dismantling and dumpsite processes are major sources of organophosphate flame retardant and plasticiser emissions and may pose potentially adverse effects on environment and human health. In 20 outdoor dust and 49 soil samples collected from four e-waste dismantling and three e-waste dumpsites in two States of Nigeria (Lagos and Ogun), we identified 13 alternative plasticisers (APs), 7 legacy phthalate plasticisers (LPs), and 17 organophosphorus flame retardants (OPFRs) for the first time in African e-waste streams. In the samples from dismantling sites, the range (median) concentrations of ∑ 13 APs, ∑ 7 LPs, and ∑ 17 OPFRs were 11-2747 μg/g (144 μg/g), 11-396 μg/g (125 μg/g), and 0.2-68 μg/g (5.5 μg), in dust respectively and 1.8-297 μg/g (55 μg/g), 1.3-274 μg/g (48.5 μg/g), and 1.6-62 μg/g (1.6 μg/g), in soil respectively. Results for soil samples from e-waste dumpsites were (6.6-195 μg/g (23.7 μg/g), 6.0-295 μg/g (54.8), and 0.4-42.3 μg/g (9.0 μg/g) for ∑ 13 APs, ∑ 7 LPs, and ∑ 17 OPFRs respectively. Overall, concentrations of APs were significantly higher at the dismantling sites (p = 0.005) compared to dumpsites, levels of LPs were higher at dismantling sites but not significant, while OPFR concentrations were significantly higher in dumpsite samples (p = 0.005). Plasticisers were found to be major contributors to pollution at e-waste dismantling sites, while OPFRs were associated with both automobile dismantling and e-waste dumpsite processes. Following particle size fractionation of selected soil samples, higher concentrations of targeted compounds were observed in the smaller mesh (180 μm) soil sieve fraction. For dust, the total median estimated daily intake via ingestion and dermal adsorption (EDI ing and EDI derm ) ranged from 43 to 74 ng/kg bw/day and 0.4-0.7 ng/kg bw/day, respectively. Correspondingly, 4.6-45 ng/kg bw/day and 0.015-0.57 ng/kg bw/day were the values found for soil, respectively. According to these results, the targeted chemicals do not appear to pose a non-carcinogenic risk to e-waste workers through ingestion or dermal contact of bio-accessible fractions of the chemicals. Human biomonitoring campaigns are recommended in the Nigerian e-waste environment considering the elevated concentration levels found for the majority of targeted compounds and that risk parameters required for exposure assessment were only available for a limited number of compounds., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Large quantities of chlordecone-based insecticides were produced and used throughout the world. One of its most important uses was to control the damage caused by Cosmopolites sordidus in banana-growing regions. In the islands of Martinique and Guadeloupe, 18,000 ha of farmland are potentially contaminated. Despite the key role played by soil macrofauna in agroecosystems, there are currently no data on their contamination. The aim of this study was to explore the fate of chlordecone (CLD) and its transfer to different organisms of the soil food web. Seven species of invertebrates representing different taxonomic groups and trophic levels of the soil communities of Martinique were targeted and collected in six experimental banana fields, with a level of contamination within a range of values classically observed. Soil samples and macrofauna from the study sites were analysed for CLD and chlordecol (CLDOH) its main transformation product. The contamination of the soil fauna were related to δ 15 N (trophic level), proportion of soil ingestion (diet) and types of epidermis (mucus or exoskeleton) in order to study the different mechanisms of macrofauna contamination. Presence of CLD and CLDOH could be quantified in all the soil organisms from contaminated fields. Results showed a significant relationship between the CLD contamination of detritivorous and the ash content of their faeces, suggesting that soil ingestion was the main contamination pathway. In contrast, the exoskeleton-bearing diplopod Trigoniulus coralinus and the soft-bodied earthworm Eudrilus eugeniae, both detritivores with a comparable diet, had similar contamination levels, suggesting that the type of tegument has little influence on bioaccumulation. At the scale of the entire trophic network, a significant relationship was uncovered between δ 15 N values and CLD contamination of the fauna, therefore providing some in situ evidence for a bioamplification process along the soil food chain., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:Mathieu coulis reports financial support was provided by the BANABIO project funding obtained under DEPHY EXPE program of the Ecophyto II plan. Julien PARINET reports financial support was provided by French National Research Agency (ANR-19-CE21-0002). Lai Ting pak reports financial support was provided by The French Ministry of the Overseas for this study that was part of the Territoires Durables project carried out in Martinique. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Culinary spices and herbs, renowned for their flavor, aroma, and medicinal properties, contain essential nutrients but also may pose health concerns due to heavy metal contamination. This systematic review, in accordance with PRISMA guidelines, investigates the global concentrations of heavy metals in culinary spices and herbs, and evaluates associated health risks. Fifty peer-reviewed studies from Scopus, PubMed, and Web of Science were examined and findings revealed variations in heavy metal content based on country of origin and spice type. In the MENA region, caraway and green cardamom from Bahrain had high levels of Pb (2.2 μg/g) and Cd (0.9 μg/g). Indian spices like cloves and Ajwain seeds exhibited high levels of iron (17.87 ± 8 mg/kg) and calcium (1353 ± 10 mg/kg). African and European spices showed regional disparities, with some exceeding permissible Pb and Cd limits. Non-carcinogenic human health risk assessments via oral exposure pathway conducted on reported Cd, Ni, and Cu concentrations throughout the reviewed global studies revealed no risks across all regions and for all spices and herbs under study except in Turkey for Cd levels found in chamomile with hazard quotients ranging between 1.26 and 1.47. On the other hand, carcinogenic risks varied based on reported Pb concentrations, ranging from 8.5 × 10 -8 to a maximum of 4.96 × 10 -3 . These findings underscore the need for global vigilance in food safety practices and future research in countries with less stringent policies. Recommendations include improved agricultural practices, enhanced soil management, and stringent post-harvest procedures to mitigate contamination., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Biochar and compost are effective ways to improve soil quality and reduce pesticide pollution. However, the effects of them on the abundant and rare microbial communities in freeze‒thaw soil need to be further clarified. Therefore, this study took biochar, compost, and their combination as examples to explore their effects on the abundant and rare microbial communities and multifunctionality in glyphosate, imidacloprid and pyraclostrobin contaminated soil under freeze‒thaw cycles. We found that freeze‒thaw cycles enhanced the functional groups and surface aromaticity of biochar and compost, thereby improving the adsorption capacity. Biochar and compost reduced the concentration and half-life of three pesticides and enhanced the degradation function of rare taxa in soil. Biochar and compost improved the structure composition and co-occurrence relationship of abundant and rare taxa. Meanwhile, the assembly processes of abundant and rare sub-communities were mainly driven by stochastic processes and the Combined treatment promoted the transition from dispersal limitation to homogenizing dispersal and homogeneous selection. Moreover, the Combined treatment significantly improved the multifunctionality before and after freezing and thawing by increasing the diversity of rare taxa and assembly processes. The results provide new insights for farmland soil remediation in seasonal frozen areas, especially the soil functional cycle of abundant and rare microorganisms., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Pesticide contamination has emerged as a global threat to humans. Here, we investigate the soil distribution pattern of organic phosphorus pesticide contamination at a pesticide manufacturing site in northern China, exploring their relationships with soil properties and microbial communities. The concentrations of four organic phosphorus pesticides (i.e., phorate, terbuthion, fenitrothion, and parathion) decreased substantially with soil depths from the surface down to 2 m. However, terbuthion, fenitrothion, and parathion had second-peak concentrations at a depth of 8 m. The concentrations of those organic phosphorus pesticides were negatively correlated with soil water content, but positively correlated with sulfide, pH, and total phosphorus. The distribution patterns of organic phosphorus pesticides closely aligned with that of soil organic matter and clay minerals, especially in the presence of montmorillonite, kaolinite, and chlorite. Various bacterial genera known to degrade organic phosphorus pesticides, such as Flavobacterium, Bacillus, Acinetobacter, Lactobacillus, Pseudomonas, Sphingomonas, and Thiobacillus, were correlated with these pesticides. Since these genera were among the top 50 abundant genera in our samples, they might play a significant role in the degradation of organic phosphorus pesticides. Together, this study unveils previously unrecognized pesticide-soil-microbe interactions, thus providing an important knowledge basis for environmental remediation strategies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Utilizing plant extracts for soil washing is a promising and cost-efficient strategy to permanently remove toxic metals from farmland soils. However, the efficiency of current plant extracts in heavy metals removal is constrained by the need of excessively high liquid-solid ratios (>10:1), which limits their practical application in the farmland soils. To address this challenge, we developed a novel binary washing agent consisting of Fructus mume residue extract (RPM) and methylglycinediacetate acid (MGDA). Through optimization experiments, we determined an optimal composition of 50 g L -1 RPM and 0.34 g L -1 MGDA (RPMG3), which exhibited a remarkable synergistic effect on the removal of Cd and Cu from two polluted farmland soils. Compared to the single use of RPM or MGDA, RPMG3 increased metal removal efficiency by 44.6%-303.8% in the alkaline dryland soil and 55.8%-141.9% in the slightly acidic paddy soil, at an optimum liquid-solid ratio of 2:1. The contents of soil Cd and Cu can be reduced to below the risk screening values via acid activation, metal ion exchange, and complexation of functional groups. Moreover, the potential ecological risks associated with Cd in the soils were significantly mitigated due to the decrease in exchangeable and reducible Cd fractions following RPMG3 washing. Additionally, RPM and RPMG3 washing led to enhancements in soil organic carbon and nutrient concentrations, as well as increased activities of soil enzymes including catalase, urease, and β-glucosidase. Notably, RPMG3 washing exhibited the most pronounced promotion effect on wheat seed germination and growth. Taken together, the binary complex of RPMG3 demonstrates potential as an environmentally friendly green washing agent capable of in reducing heavy metals from farmland soil with great efficiency, even at low liquid-solid ratios., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Microplastics (MPs), an emerging pollutant of global concern, have been studied in the Hongyingzi sorghum production base. In this study, we investigated MPs in the surface soil (0-10 cm) and deeper soil (10-20 cm) in the Hongyingzi sorghum production base. Pollution characterization and ecological risk evaluation were conducted. The results revealed that the MP abundance ranged from 1.31 × 10 2 to 4.27 × 10 3 particles/kg, with an average of 1.42 ± 1.22 × 10 3 particles/kg. There was no clear correlation between the MP abundance and soil depth, and the ordinary kriging method predicted a range of 1.26 × 10 3 -1.28 × 10 3 particles/kg in most of the study area, indicating a relatively uniform distribution. Among the 12 types of MPs detected, acrylates copolymer (ACR), polypropylene (PP), polyurethane (PU), and polymethyl methacrylate (PMMA) were the most frequently detected. These MPs primarily originated from packaging and advertising materials made from polyurethane and polyester used by Sauce Wine enterprises, as well as plastic products made from polyolefin used in daily life and agricultural activities. The particle size of MPs was primarily 20-100 μm. Overall, the proportion of the 20-100 μm MP was 95.1% in the surface soil layer and 86.7% in the deeper soil layer. Based on the pollution load index, the MP pollution level in the study area was classified as class I. Polymer hazard index evaluation revealed that the risk levels at all of the sampling sites ranged from IV to V, and ACR, PU, and PMMA were identified as significant sources of polymer hazard. Potential ecological index evaluation revealed that most of the soil samples collected from the study area were dangerous or extremely dangerous, and the surface soil posed a greater ecological risk than the deeper soil. These findings provide a scientific foundation for the prevention, control, and management of MP pollution in the Hongyingzi sorghum production base., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The study presented here elucidate the concentrations of radionuclides and potentially toxic elements in the soil samples around the Novaya Zemlya in the Russian Arctic zone, determined using HPGe gamma spectrometry, inductively coupled plasma optical emission spectrometry and direct mercury analyzer. The average detected concentrations for 226 Ra, 232 Th, 40 K, 235 U and 137 Cs were 36.40, 46.06, 768, 2.06 and 4.71 Bq/kg, respectively. At many sampling sites, the concentrations of potentially toxic elements (Zn, Cu, Pb, Cd, Ni, and Cr) were higher than the natural levels. Positive Matrix Factorization analysis revealed the contribution of oil dumps (32%), natural sources (16%), bird colonies (32%) and atmospheric deposition (20%) for elevated elements content. In the case of radionuclides, the natural occurring contamination (38%) was primary source followed by dumped material (32%) and bird colonies (30%). The radiological risk from radionuclides was relatively high, yet still under permissible levels. For potentially toxic elements, Fe was predominant non-carcinogenic pollutant and Ni emerged as major carcinogenic contaminant. Keeping in view the high content of some elements, future studies are required to keep the human and ecological risk low, and to establish scientific grounds for the contribution of settled bird species. The findings of the study advance the present knowledge about the contamination of the study area and lays the path for further effort., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Palm oil is a high value crop widely grown in the tropics. The management of palm oil is characterised by widespread agrochemical use. Here we report the results of a screening level risk assessment conducted from the available literature on the environmental concentration of agrochemicals in surface waters and soils in palm oil growing areas. To date, only a small number of published studies have measured pollutant concentrations in and around palm oil plantations. To identify potential high-risk contaminants, a standard SSD based risk assessment, establishing risk quotients for detected contaminants, was conducted in relation to available species sensitivity distributions. A probabilistic SSD based risk assessment, calculating potential risk distributions, was also conducted for contaminants with the required number of data points available. Metals were the most commonly detected (and measured) substances and also presented the greatest risk, especially copper and zinc, but also nickel, lead and cadmium. For these metals, environmental concentrations overlapped levels found to cause effects in toxicity studies, indicating the potential for adverse outcomes from exposure. To fully understand the extent of this risk, more detailed studies are needed that assess metal speciation states and bioavailability under the prevailing soil and water chemistry conditions in palm oil plots. Limited studies have measured pesticide concentrations in palm oil systems. In these few cases, only a few active substances have been measured. From the limited information available, potential risks are indicated due to the presence of some insecticides. However, fungicides are also widely used for palm oil disease management, but little data studies are available to assess both exposure and potential effects. To further assess the potential chemical footprint of different palm oil management practices, studies are needed that systematically assess pollutant levels across a range of chemical groups to consider effects within a mixture context., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

The effectiveness of bioretention cells for heavy metals (HMs) and microplastics (MPs) removal from stormwater runoff has been demonstrated. Knowledge of the mechanisms that dictate the interactions between MPs and HMs would be helpful in pollution control. In this study, the performances of different water-soil-plant bioretention cells for HMs removal through the interception of polyethylene MPs (PE-MPs) were investigated. The results showed that PE-MPs bound to HMs and preferentially tended to bind to Pb (32%-44%) in the complex HMs (Cu, Zn, Cd, and Pb). This could be the reason that the concentration of Pb significantly increased in the effluent under low-intensity simulated rainfall events over a long duration. The accumulation of 1.49 g/kg PE-MPs caused a significant soil pH value decrease and a notable soil zeta potential increase in the bioretention cell, while the low sand/silt ratio media buffered this process. The retention of PE-MPs increased 138.5% in the 0-10 cm soil surface layer when the sand/silt ratio reduced from 2:1 to 1:1 and planted with Canna indica. Meanwhile, PE-MPs amplified the instability of Zn removal in bioretention cells under low-intensity rainfall events in long-duration, high silt percentage substrate and vegetation coverage. The study would contribute to developing a long-term management program for PE-MPs and HMs trapped in bioretention cells to reduce the risk of pollution transport., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)