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Your search keyword '"Duclairoir, Florence"' showing total 2 results
Start Over Author "Duclairoir, Florence" Topic hydrogen bonding Publisher elsevier b.v.
2 results on '"Duclairoir, Florence"'

1. Ferrocene incorporating host–guest dyads with electrochemically controlled three-pole hydrogen bonding properties

Author

Cooke, Graeme, de Cremiers, Hugues A., Duclairoir, Florence M.A., Leonardi, Julie, Rosair, Georgina, and Rotello, Vincent M.

Subjects
*FERROCENE, *ELECTROCHEMISTRY, *HYDROGEN bonding
Abstract

We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2·5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4·6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH2Cl2 for 2·5) or polar (DMF for 4·6) organic solvents between three distinct states. [Copyright &y& Elsevier]

Published
2003
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2. An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

Author

Boyd, Alan S. F., Cooke, Graeme, Duclairoir, Florence M. A., and Rotello, Vincent M.

Subjects
*HYDROGEN bonding, *MOLECULAR recognition
Abstract

We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+⋅ state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. [Copyright &y& Elsevier]

Published
2003
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