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Chiral organic fluorescent materials have attracted broad attention for their application in various chiroptical devices. Helicenes possess special helical structure and unique optical properties, and have been utilized to develop chiral organic fluorescent materials with excellent chiroptical performance. However, the low luminescence efficiency of helicene-based chiral fluorescent materials in solid state limits their practical applications. In this work, chiral organic fluorescent emitters with helicene moiety have been developed from binaphthanol structure. These BINOL [4]helicene compounds display aggregation-enhanced emission properties, and have strong blue emission in solid state with fluorescent quantum yield up to 0.67. The DFT calculation reveals that these compounds have highly twisted molecular structures. Thus, the excellent fluorescent properties in solid state could be aroused by the highly contorted molecular structures, which could limit the π-π stacking of adjacent molecules in solid state. The enantiomers of these compounds show strong Cotton effects in circular dichroism spectra, and the molecules with 4-methoxy phenyl moiety exhibit circularly polarized luminescence properties. Highly twisted BINOL- [4]helicene hybrids have been synthesized, which have strong fluorescent emission in solid state and chiral optical properties. [Display omitted] • Chiral binol-[4]helicene hybrids have been synthesized. • These molecules display aggregation-enhanced emission properties. • These molecules show strong fluorescent emission in solid state. • Compound 6 exhibits circularly polarized luminescence property. [ABSTRACT FROM AUTHOR]

A simple and convenient silver-catalyzed multicomponent strategy for the construction of highly functionalized γ-carbonyl-α-amino acid derivatives has been developed under mild conditions. • Multicomponent tandem reactions for synthesis of γ-carbonyl-α-amino acid derivatives. • Atom and step-economy. • Mild condition. • High reaction efficiency. Silver-catalyzed multicomponent strategy for the construction of highly functionalized γ-carbonyl-α-amino acid derivatives has been developed under mild conditions, in which various γ-carbonyl-α-amino acid derivatives were obtained in moderate to excellent yields. Preliminary mechanistic studies suggested that silver-catalyzed A 3 -coupling reaction and alkyne hydration process were accomplished in a simple operation. [ABSTRACT FROM AUTHOR]

The design and exploration of efficient organic fluorophores have attracted significant scientific interest for their various potential applications. As blue fluorescent materials are essential for the achievement of a full-color display and white emission, the development of new efficient organic blue-emitting materials is of great importance. In this work, we found that simple organic molecules 2-aryloxybenzo[d]oxazoles could act as novel organic fluorophores with special AIE properties and efficient blue fluorescent emission in the solid states. Compounds 3 and 4 possess moderately high quantum yields at 10.3% and 11.4%, respectively. The CIE coordinates indicate that most of these compounds are deep-blue emitters. The single crystal structure of compound 3 shows that it has a twisted V-shape molecular structure with J-type aggregation. Noncovalent interactions widely exist in the crystal structures, while π-π stacking interactions are not observed between adjacent aromatic rings. The special fluorescent properties of these new emitters could ascribe to the unique molecular packing mode in the crystal structure. This work provides a new strategy to access organic solid-state fluorophores with deep-blue emission. Simple organic molecules (2-aryloxybenzo[d]oxazoles) act as novel organic fluorophores with special AIE properties and efficient deep blue fluorescent emission in the solid states. Image 1 • 2-Aryloxybenzo[d]oxazoles derivatives are designed and synthesized. • These fluorophores show special AIE properties. • These compounds exhibit efficient deep blue emission in solid states. [ABSTRACT FROM AUTHOR]

Organic fluorescent materials have been widely used in various fields including visualization of latent fingerprints and imaging of lysosomes. High-performance organic fluorescent molecules based on simple molecular structures are still limited and highly demanded for high-definition and high-contrast imaging of latent fingerprints and lysosomes. In this work, two organic fluorescent molecules (DANPAN and DANBEN) were developed based on dimethylamino naphthalenyl phenylethene structure. These two molecules have quite different fluorescent properties, and the position of cyano group significantly affects the optical properties of these dimethylamino naphthalenyl phenylethene derivatives. Compound DANPAN shows strong yellow emission in solid state, while compound DANBEN has strong fluorescent emission in organic solutions. In addition to these differences, both compounds have large Stokes shifts and positive solvatochromic properties. Further studies showed that these compounds could be used to display latent fingerprints on various substrate surfaces. The obtained fingerprint images have excellent contrast and high resolution. It is also found that these molecules could specifically stain lysosomes in living cell within short incubation time. This work provides a series of new high-performance organic fluorescent materials with diverse applications. Highly emissive dimethylamino naphthalenyl phenylethene derivatives have been synthesized, which show large Stokes shifts and positive solvatochromic properties. These compounds could be applied for visualization of latent fingerprints and specific localization of lysosomes in living cell imaging. [Display omitted] • Two dimethylamino naphthalenyl phenylethene derivatives are synthesized. • These molecules show large Stokes shifts and positive solvatochromic properties. • These compounds could be applied for visualization of latent fingerprints on various substrate surfaces. • These molecules could be used for specific localization of lysosomes in living cell imaging. [ABSTRACT FROM AUTHOR]