1. Dimensional-transformation of hexagonal antimonene nanosheets through the manipulation of reduction kinetics
- Author
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Haibin Sun, Wenrui Zheng, Congcong Liu, Xiangdong Li, Xinyu Chu, Shiran Wang, Shenghong Liu, and Wenhe Xie
- Subjects
antimonene ,hexagonal nanosheets ,hydrothermal method ,lithiumion batteries ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Chemical technology ,TP1-1185 - Abstract
Antimonene (Sb) has been widely studied owing to its high carrier mobility, high thermal conductivity, and tunable electronic properties. Conventional synthetic methods for antimonene nanosheets (Sb-NSs) are more complex and multi-step reactions, mainly including the epitaxial growth method, mechanical peeling method, electrochemical separation method, and liquid-phase separation method. Here, we report a simple method for the synthesis of Sb-NSs on Ni foam from two-dimensional (2D) nanosheets to one-dimensional (1D) nanowires via hydrothermal method. The fabricated hexagonal Sb-NSs exhibit a transverse scale of 400 nm and a thickness of approximately 50 nm. When evaluated as anode materials for lithium storage, hexagonal Sb-NSs deliver a high reversible capacity of 870.3 mAh g ^−1 at 0.2 A g ^−1 and a reversible capacity of 375 mAh g ^−1 at 0.2 A g ^−1 after 60 cycles. As a result, the successful preparation of dimensional-switching Sb-NMs provides a new class of 2D materials for LIBs.
- Published
- 2023
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