Author: "Zhan, Yaling" / Publisher: royal society of chemistry - Searchworks@Jio Institute Digital Library Search Results

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Start Over Author "Zhan, Yaling" Publisher royal society of chemistry

Author: Huang, Xin, Zhang, Yage, Liang, Weijian, Zhang, Qifeng, Zhan, Yaling, Kong, Lichun, and Peng, Bo
Published: 2020
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Author: Huang, Xin, Zhao, Weizhao, Chen, De-Li, Zhan, Yaling, Zeng, Tingting, Jin, Huiquan, and Peng, Bo
Subjects: METHYLATION, ELECTROPHILES, OXAZOLINE
Abstract: A three-component reaction between benzyne, oxazolines and chloroform was developed for the synthesis of trichloromethylated chiral oxazolidines. Benzyne not only serves as an electrophile towards oxazolines but also acts as a base for the deprotonation of chloroform. The dual functions of benzyne enable the trichloromethylation of chiral oxazolines and thus construct chiral N,O-quaternary stereocenters. [ABSTRACT FROM AUTHOR]
Published: 2019
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