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Your search keyword '"Deven P. Estes"' showing total 1 results
Start Over Author "Deven P. Estes" Publisher royal society of chemistry (rsc)
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1. The reaction of HV(CO)4dppe with MoO3: a well-defined model of hydrogen spillover

Author

Joris van Slageren, Mario Winkler, Blazej Grabowski, Abdulhamid H. Almidani, Yuji Ikeda, Deven P. Estes, and Michael Benz

Subjects
Adsorption, Chemistry, Hydrogen spillover, Photochemistry, Catalysis
Abstract

Hydrogen spillover is mechanistically poorly understood, due to the H˙ donor complexity. We show that HV(CO)4dppe (1) transfers H˙ to MoO3 in separate H+ and e− transfer steps. This is analogous to hydrogen spillover from Pt to MoO3 and suggests that 1 is a good model for H˙ adsorbed on Pt.

Published
2021
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