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The investigation in this article focused on the role of La2O3 on the optical, physical, and radiation protection performance of La2O3-based glasses in the form 21.5SiO2-58.5B2O3-(20−x)ZnO:xLa2O3, where x , ( 0 ≤ x ≤ 10 ) mol%. The melt-quenching process was used to synthesize the glasses under study. Density results increased from 3.174 to 4.754, the values of the ( E opt. indi ) increased from 2.996 to 3.313 and ( E opt. di) increased from 3.364 to 3.689. Several radiation shielding factors have been evaluated to study the attenuation abilities of the ZBSL glasses and for all of them, there is a positive correlation between the mean free path (MFP) values and the incoming photon energy. The effective atomic number, Zeff, values increased for all the energies when La2O3 was employed in place of ZnO. Therefore, of all the competing shielding glasses and regular concrete, ZBSL10 glass is an excellent choice for shielding applications from gamma rays and neutrons. This study should be very beneficial for the design of these glasses or for the fabrication of new glasses for radiation protection. [ABSTRACT FROM AUTHOR]

The current work discusses the radiation attenuation capability and different shielding characteristics of different mortar samples. The samples were prepared by replacing different percentages of fine aggregate with iron filling and replacing different percentages of hydrated lime with Bi2O3 (0–50 wt.%). The prepared mortar samples are coded as CHBFX where X = 0, 10, 30, and 50 wt.%. The mass and linear attenuation coefficient was determined experimentally using a narrow beam technique, where a high purity germanium detector, and different point gamma-ray sources (such as Am-241, Cs-137, and Co-60). The linear attenuation coefficient was also calculated using the Monte-Carlo simulation code and the online Phy-X/PSD software. The comparison of the three methods showed a good agreement in the results. The linear attenuation coefficient drops from 19.821 to 0.053 cm−1 for CHBF0, from 27.496 to 0.057 cm−1 for CHBF10, from 42.351 to 0.064 cm−1 for CHBF30, and from 55.068 to 0.071 cm−1 for CHBF50 at photon energy range from 0.015 to 15 MeV. The half-value layer thickness, tenth-value layer thickness, and mean free path of the prepared mortar composites were also calculated photon energy ranged from 0.015 to 15 MeV. The fast neutron removal cross-section of the prepared CHBFX mortar samples have values of 0.096 cm−1, 0.098 cm−1, 0.103 cm−1, and 0.107 cm−1 for the mortar samples CHBF0, CHBF10, CHBF30, and CHBF50, respectively. The results showed that the mortar sample with the highest iron filing concentration, CHBF50, provides the best protection against gamma rays and fast neutrons which could be used in the nuclear and medical fields. [ABSTRACT FROM AUTHOR]

Five glass samples with the following chemical formation: 21.5 SiO2-58.5B2O3-(20-x) ZnO- xLa2O3, where x = 0–10 mol% were fabricated utilizing melt quenching. With an increase in La2O3, the glasses' density increased from 3.174 to 4.754 g/cm3. Experimental data were used to evaluate the mechanical characteristics, and the Makishima and Mackenzie model's semi-empirical methods were used to analyze the elastic properties. As the amount of La2O3 increases, there's a noticeable rise in the velocity of ultrasonic waves. This heightened velocity is likely linked to the strengthening or increased rigidity of the glass network. Elastic moduli values of the glasses under investigation increase with an increase La2O3 content. Employing Phy-X/PSD code, the radiation attenuation behaviour of zinc borosilicate glasses with varying La2O3 concentrations were examined. With increased energy, the enhancement LAC decreases from 2.576 to 0.0375. The ZBSL10 glasses demonstrated strong mechanical and physical characteristics as well as radiation shielding capabilities. The features of the ZBSL glasses are particularly attractive for a variety of mechanical and shielding applications. [ABSTRACT FROM AUTHOR]

The composition of the pentagonal glass system, which is composed of 57B2O3-16SiO2-11BeO- (16-x) MgO-xLa2O3, x = (0 ≤ x ≤ 16 mol %), has been synthesized by the melt quench process. XRD diffractograms' wide haloes testified to the materials' amorphous state. It was discovered that, density increased in response to La2O3 concentration, whereas molar volume decreased. Additionally, the ranges of longitudinal and shear velocities are 4730 to 5085 m/s and 2685–2895 m/s, respectively. The elastic moduli for longitudinal range between 71.9–154.3 GPa, shear range between 23.2–50 GPa, bulk range between 23.2–50 GPa, and Young's range between 58.5–126 GPa, respectively. The study employed Phy-X/PSD code to examine the radiation attenuation behaviour of magnesium beryllia-borosilicate, also known as (BMBSLa) glasses, at varying concentrations of La2O3. We examined the relationship among the half value layer (HVL) and density. HVL values at a density of 3.213 g/cm3 range from 0.0087 to 11.746 cm and at density of 5.967 g/cm3 range from 0.02 to 5.727 cm at (0.015–15 MeV). Tenth value layer (TVL) and mean free path (MFP) are evaluation and comparison between HVL, TVL and MFP for the same glass at specific energy were also conducted. The glass samples under investigation are excellent candidates for usage in the field of shielding radiation because they are more transparent. [ABSTRACT FROM AUTHOR]

With the use of multilayer materials such as concrete, mortar and ceramics that were fortified with PbO, WO3 and Bi2O3 nanoparticles, our study's objective was to produce a an effective photon shielding system. Experimental evaluation of the radiation shielding efficiency of two sets of samples with various thicknesses was conducted. The elemental content and morphology of the samples were corroborated by SEM and EDX studies, with ceramic samples exhibiting superior particle distribution and fewer voids than concrete and mortar specimens. The linear attenuation coefficient (LAC) was studied both experimentally and numerically using the Phy-X program, and it was found that the two sets of values were in satisfactory agreement. The values of LAC were consistently greater for samples with 30% of the selected heavy metal oxides than for those with 10%. The LAC for Cer-1 was 5.003 cm−1 at 0.059 MeV, whereas the corresponding LAC for Cer-2 was 2.123 cm−1. The LAC values were as follows: ceramics (5.003 cm−1), mortar (2.999 cm−1), concrete (2.733 cm−1), and the transmission factor (TF) examination of the multiple-layer specimens showed that the TF of the 3 cm thick multilayer sample was lower than that of the 2 cm thick sample and that both multilayer samples displayed better attenuation efficiency in comparison to single-layer specimens. The results show the possibility for employing multilayer structures with different densities, thicknesses, and sizes in suitable radiation shielding applications. [ABSTRACT FROM AUTHOR]

We developed new composites for photons shielding applications. The composite were prepared with epoxy resin, red clay and bismuth oxide nanoparticles (Bi2O3 NPs). In order to establish which ratio of red clay to Bi2O3 NPs provides the best shielding capabilities, several different ratios of red clay to Bi2O3 NPs were tested. The transmission factor (TF) was calculated for two different thicknesses of each sample. From the TF data, we found that epoxy resin materials have a high attenuation capacity at low energy. For ERB-10 sample (40%Epoxy + 50% Red clay + 10% Bi2O3 NPs), the TF values are 52.3% and 14.3% for thicknesses of 0.5 and 1.5 cm (at 0.06 MeV). The composite which contains the maximum amount of Bi2O3 nanoparticles (40%Epoxy + 50% Red clay + 10% Bi2O3 NPs, coded as ERB-30) has lower TF than the other composites. The TF data demonstrated that ERB-30 is capable of producing more effective attenuation from gamma rays. We also determined the linear attenuation coefficient (LAC) for the prepared composites and we found that the LAC increases for a given energy in proportion to the Bi2O3 NPs ratio. For the ERB-0 (free Bi2O3 NPs), the LAC at 0.662 MeV is 0.143 cm−1, and it increases to 0.805 cm−1 when 10% of Bi2O3 NPs is added to the epoxy resin composite. The half value layer (HVL) results showed that the thickness necessary to shield that photons to its half intensity can be significantly lowered by increasing the weight fraction of the Bi2O3 NPs in the epoxy resin composite from 0 to 30%. The HVL for ERB-20 and ERB-30 were compared with other materials such as (Epoxy as a matrix material and Al2O3, Fe2O3, MgO and ZrO2 as filler oxides in the matrix at 0.662 MeV. The HVL values for ERB-20 and ERB-30 are 4.385 and 3.988 cm and this is lower than all the selected epoxy polymers. [ABSTRACT FROM AUTHOR]