1. Long-term efficient organic photovoltaics based on quaternary bulk heterojunctions
- Author
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Doo-Hyun Ko, Hyun Hwi Lee, Minwoo Nam, Il Ki Han, Minjeong Cha, S. Joon Kwon, Kahyun Hur, Kyu-Tae Lee, and Jaehong Yoo
- Subjects
Materials science ,Fullerene ,Organic solar cell ,Science ,General Physics and Astronomy ,Nanotechnology ,02 engineering and technology ,Conjugated system ,010402 general chemistry ,01 natural sciences ,Article ,General Biochemistry, Genetics and Molecular Biology ,Polymer solar cell ,chemistry.chemical_classification ,Multidisciplinary ,business.industry ,Heterojunction ,General Chemistry ,Polymer ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,chemistry ,Degradation (geology) ,Optoelectronics ,0210 nano-technology ,business - Abstract
A major impediment to the commercialization of organic photovoltaics (OPVs) is attaining long-term morphological stability of the bulk heterojunction (BHJ) layer. To secure the stability while pursuing optimized performance, multi-component BHJ-based OPVs have been strategically explored. Here we demonstrate the use of quaternary BHJs (q-BHJs) composed of two conjugated polymer donors and two fullerene acceptors as a novel platform to produce high-efficiency and long-term durable OPVs. A q-BHJ OPV (q-OPV) with an experimentally optimized composition exhibits an enhanced efficiency and extended operational lifetime than does the binary reference OPV. The q-OPV would retain more than 72% of its initial efficiency (for example, 8.42–6.06%) after a 1-year operation at an elevated temperature of 65 °C. This is superior to those of the state-of-the-art BHJ-based OPVs. We attribute the enhanced stability to the significant suppression of domain growth and phase separation between the components via kinetic trapping effect., Organic photovoltaics suffer from degradation. Here, Nam et al. develop a quaternary blend and fabricate devices which lose 28% of their initial efficiency after one year of operation at 65 °C.
- Published
- 2017
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