1. Superhydrophobic fluorescent micro-/nano-composites from carbon dots encapsulated in CaCO3-SiO2.
- Author
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Wang, Yurong, Jiang, Lian, Li, Baohe, Ma, Yitong, Zeng, Yiwen, Yu, Donghong, and Wang, Nong
- Subjects
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FLUORESCENCE yield , *CARBON composites , *MICROSCOPY , *CONTACT angle , *COMPOSITE coating , *COMPOSITE materials , *NANOCAPSULES - Abstract
In this paper, polyamine-functionalized carbon dots (CDs) were synthesized by means of low temperature (<100°C) carbonization of citric acid at the presence of polyethylenimine (PEI), resulting spherical calcium carbonate micro-particles from inverse micro-emulsion system. Nanoscaled spherical silicas were prepared by Stöber method via deposition on the surface of micron calcium carbonate. Scanning- and transmission-electron microscopic analysis confirmed a micro-/nano-complex structure, enabling the composite material coating possessed coarser surface similar to those of 'lotus leaf'. After modification with 1 H, 1 H, 2 H, 2 H-perfluorodecanethiol, both good super hydrophobicity and good fluorescent performance were confirmed by the water contact angle of 154.1°±1.5°, their surface-free energy, and fluorescence quantum yield of 14.1%, which provides an inexpensive and easy way to fabricate superhydrophobic material with fluorescence characteristics and promotes high value application of inorganic materials. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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