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1. Mechanism of the Hydroxycarbonylation of 1-Hexene Catalyzed by Immobilized Rhodium Complexes of Pyridine Ligands

Author

Alvaro J. Pardey, Gabriela C. Uzcátegui, Marisol C. Ortega, Clementina Longo, and Fernando Hung-Low

Subjects
Chemistry, Heptanoic acid, chemistry.chemical_element, General Medicine, Catalysis, Water-gas shift reaction, Pyridine ligand, Rhodium, 1-Hexene, chemistry.chemical_compound, Polymer chemistry, Pyridine, Organic chemistry, Amine gas treating, Physical and Theoretical Chemistry
Abstract

In this work, a mechanistic study of the hydroxycarbonylation of 1-hexene to heptanoic acid and the water gas shift reaction (WGSR) catalyzed by the rhodium(I) complexes, [Rh(COD)(amine)2](PF6) (COD = 1,5-cyclooctadiene, amine = 4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with water under CO is discussed. Catalytic cycles for these reactions bearing common Rh-H catalytic species are proposed.

Published
2007
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