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1. [{Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.

Author

Wolf S, Winter F, Pöttgen R, Middendorf N, Klopper W, and Feldmann C

Subjects
Crystallography, X-Ray, Ionic Liquids chemistry, Iron chemistry, Molecular Conformation, Spectroscopy, Fourier Transform Infrared, Spectroscopy, Mossbauer, Adamantane chemistry, Organometallic Compounds chemistry, Tin chemistry
Abstract

Show some metal: the first bimetallic adamantane-like cluster, [{Fe(CO)(3)}(4){SnI}(6)I(4)](2-), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations., (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Published
2012
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