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Among the input data of the watershed model for simulating changes of flowrate in the watershed, weather input data, especially input data related to rainfall, are the most important. Therefore, it is important to ensure the accuracy of rainfall input data to increase the accuracy of the watershed model results. Securing rainfall measurements with finer spatial and temporal resolutions is important in predicting flowrate variations at a sub-catchment, especially as they relate to global and local climate changes in weather conditions such as rainfall depth, rainfall intensity, etc. In this study, adjusted radar-rainfall estimates were suggested as alternative input data for watershed modeling. Through a statistical analysis of the representativeness of a ground rainfall measurement (10 km × 10 km grid), the necessity of radar-rainfall estimates (2 km × 2 km grid) was identified. By applying calibration factors to initial radar-rainfall estimates and comparing adjusted radar-rainfall estimates with ground rainfall measurements, it was proven that adjusted radar-rainfall estimates could be used as input data for watershed simulations (NSE > 0.92; n = 12). Adjusted radar-rainfall estimates and ground rainfall measurements were used as input data of the Soil and Water Assessment Tool model to predict flowrate variations at the outlets of a tributary and the entire watershed. As a result, the accuracies of the simulation results were improved for the outlets of a tributary and the entire watershed (NSE: 0.33 to 0.48 and 0.19 to 0.55, respectively). To obtain more reliable rainfall data, radar images easily accessible to users were applied, and the accuracy of the data was increased by applying simple equations to numerical data extracted from radar image processing. Additionally, the applicability of the adjusted radar-rainfall estimates was demonstrated by comparing the modeling results using the suggested rainfall data and existing ground-based rainfall data. The suggested methodologies are expected to contribute to more accurately predict the possibility of flood disasters in other regions and countries lacking infrastructure related to rainfall measurements and to establish appropriate countermeasures.

Utilizing carbon-based counter electrodes (CEs) in dye-sensitized solar cells (DSSCs) have received much attention in recent times, owing to their low cost, good electrochemical activity, natural abundance and eco-friendly nature. Herein, we have facilely prepared quince leaves derived porous carbon (QLPC) using fallen quince leaves (QLs) and it was used as a cost-effective CE for the fabrication of DSSCs. By means of alkali treatment and pyrolysis process (at different temperatures of 700, 800 and 900 °C), the QLs powder undergoes chemical activation and carbonization, which results in a honeycomb-like QLPC with abundant micro/mesopores and large surface area. Simple and straightforward coating of QLPC samples onto fluorine doped tin oxide glass substrates led to improved electrocatalytic activity and good tri-iodide reduction in DSSCs. When the DSSCs were illuminated under 1 sun condition (AM 1.5; 100 mW cm −2 ), the device assembled with QLPC-based CE (prepared at 800 °C) showed a higher current density of ∼14.99 mA/cm 2 and power conversion efficiency of ∼5.52% among the other QLPC-based CEs, which are comparable with the platinum-based CE in DSSCs. This facile process for the preparation of biomass derived carbon-based CE provides an alternative to the noble metal-free CE in DSSCs.

Honeycomb-like activated porous carbon (HPC) powder with meso/macropore structures was successfully prepared via chemical activation and pyrolysis processes under inert gas atmosphere. Herein, the naturally available pine cone flowers with abundant carbon contents were employed as a biomass to synthesize the HPC sample. The structure and morphology of the HPC powder were characterized by various physicochemical techniques. Moreover, the as-prepared HPC sample was uniformly coated on fluorine doped tin oxide glass using a smooth brush and used as a cost-effective counter electrode (CE) in dye-sensitized solar cells (DSSCs). Under AM1.5G illumination, the fabricated DSSCs with HPC-based CE exhibited a high short-circuit current density (JSC) of 13.51 mA/cm2 and an excellent power conversion efficiency (PCE) of 4.98%, which is attributed to the high specific surface area and hierarchical porous property of the HPC sample. The obtained results were improved compared to the commercially available activated carbon-based CE in DSSCs (JSC = 12.11 mA/cm2 and PCE = 4.45%). This facile fabrication of highly porous activated carbon-based materials from the biomass can be utilized as a high-performance electrode material in DSSCs and energy storage device applications.

Hierarchical copper oxide (CuO) nanostructures (NSs) with caterpillar-like morphologies were facilely integrated onto a highly flexible conductive woven textile substrate (CWTs) by a drop-casting approach. Initially, the CuO NSs were synthesized via a simple and green wet-chemical method in 30 min and the obtained colloidal solution of CuO was easily dropped onto well-cleaned CWTs. By virtue of their interesting structural features, the caterpillar-like CuO NSs on CWTs were employed as binder-free electrodes for supercapacitors and their electrochemical properties were investigated in 1 M KOH solution. Additionally, a small portion of redox-additive potassium ferricyanide (K3Fe(CN)6) was added to the 1 M KOH solution, which led to efficient enhancement of energy storage performance with superior cycling stability for the caterpillar-like CuO NSs on CWTs. Furthermore, the fabricated asymmetric supercapacitor (SC) with CuO NSs on CWTs and activated carbon with an operating potential window of 1.5 V simultaneously exhibited excellent energy density and power density values. Such a simple and low-cost approach to easily construct metal oxide nanomaterials on flexible textiles with redox-additive electrolyte may be useful for several potential applications in high-performance energy storage devices.

Coastal erosion, a worldwide social issue, has garnered substantial attention. Numerous methods have been implemented to control coastal erosion problems, however, the presence of rigid structures limits erosion mitigation, thereby causing various challenges. For instance, in the case of submerged breakwaters, local scour in front of the structure and scour caused by the flow occurring in open inlets affect the subsidence and stability of the structure and can also cause structural failure. To solve these problems, this paper proposes a hybrid method of using a submerged breakwater with an artificial coral reef installation, further, this study evaluates the attenuation of waves and mitigation of sediment transportation through large-scale 3D hydraulic experiments. We found that the hybrid method with an artificial coral reef installed in the open inlet shows excellent wave control and plays a clearly beneficial role in the advancement of the shoreline. The artificial coral reef method reduced the return flow generated by the drag force at the breakwater shoulder and open inlet. In addition, scour at the breakwater shoulder was inhibited by collecting the sand escaping offshore. Simultaneously, scour at the open inlet was also mitigated. The application of the hybrid method compensated for the problems caused by local scour and erosion in the submerged breakwater, thereby leading to the improvement of its function. Therefore, the hybrid method proposed in this paper was determined to be applicable not only for submerged breakwaters, but also for various structures for controlling coastal erosion.

Manganese dioxide nanosheet arrays with interconnected arrangements are easily synthesized on vapor grown carbon fibers (MnO2 NSAs@VCFs) by a simple wet-chemical method at low temperature. The conductive nature of the VCFs serves as a scaffold and easily reduces potassium permanganate species for the formation of hierarchical MnO2 NSAs@VCFs. When utilized as an electroactive material for pseudocapacitors, the sophisticated configuration of the nanocomposite provides an effective electrochemical activity and an electron pathway for higher electrochemical performance in 1 M Na2SO4 aqueous solution. The hierarchical MnO2 NSAs@VCFs exhibit a maximum specific capacitance of 115.3 F g−1 at a current density of 0.5 A g−1 with an excellent cycling stability of 85.6% after 2000 cycles at a current density of 5 A g−1. Such facile and cost-effective fabrication of a metal oxide nanocomposite with improved electrochemical performance allows it to be considered as a promising electroactive material for energy storage devices.

Amorphous nickel tungsten tetraoxide (NiWO4) nanostructures (NSs) were successfully synthesized on a flexible conductive fabric (CF) using a facile onestep electrochemical deposition (ED) method. With an applied external cathodic voltage (–1.8 V for 15 min), the amorphous NiWO4 NSs with burl-like morphologies adhered well on the seed-coated CF substrate. The burl-like amorphous NiWO4 NSs on CF (NiWO4 NSs/CF) are employed as a flexible and binder-free electrode for pseudocapacitors, which exhibit remarkable electrochemical properties with high specific capacitance (1,190.2 F/g at 2 A/g), excellent cyclic stability (92% at 10 A/g), and good rate capability (765.7 F/g at 20 A/g) in 1 M KOH electrolyte solution. The superior electrochemical properties can be ascribed to the hierarchical structure and large specific surface area of the burl-like amorphous NiWO4 NSs/CF. This cost-effective facile method for the synthesis of metal tungsten tetraoxide nanomaterials on a flexible CF could be promising for advanced electronic and energy storage device applications.

When stormwater runoff flows into a constructed wetland, the water level changes inside, and the volume of the wetland changes accordingly. In this study, the relationship between pollutant removal and water depth flowrate changes was analyzed with velocity phase analysis, using the concepts of horizontal velocity and vertical velocity. A constructed wetland located in an agricultural area was used for the velocity phase analysis. Analysis results revealed that all four ponds and Phases I and III accounted for over 90% of the pollutant load. In particular, Phase III, where vertical and horizontal velocities were reduced, was responsible for approximately twice the load on average. The reason for the highest load in Phase III was due to the inflow of contaminants into the constructed wetland through the first flush effect occurred at the time when the flow rate decreased due to the difference in runoff strength. Therefore, it is necessary to maximize Phases I and III in the velocity phase when designing multi-stage wetlands to make the flow of water more natural. Furthermore, considering pollutant load levels, a design review is needed to expand the size of downstream wetlands, so that they can optimize water quality management functions.

Three-dimensional hierarchical honeycomb-like activated porous carbon pillared ultrathin Ni(OH)2 nanosheets (Ni(OH)2 NSs@HAPC) for use as supercapacitor materials were facilely synthesized. With an aid of pine cone flowers as a biomass source, HAPC conducting scaffolds were prepared by the alkali treatment and pyrolysis methods under an inert gas atmosphere. Subsequently, the Ni(OH)2 NSs were synthesized evenly on the surface of HAPC via a solvothermal method. The resulting HAPC and Ni(OH)2 NSs@HAPC composite materials offered free pathways for effective diffusion of electrolyte ions and fast transportation of electrons when employed as an electrode material. The Ni(OH)2 NSs@HAPC composite electrode exhibited excellent electrochemical properties including a relatively high specific capacitance (Csp) value of ~ 916.4 F/g at 1 A/g with good cycling stability compared to the pristine HAPC and Ni(OH)2 NSs electrodes. Such bio-friendly derived carbon-based materials with transition metal hydroxide/oxide composite materials could be a promising approach for high-performance energy storage devices because of their advantageous properties of cost effectiveness and easy availability.

As a representative urban stream in Korea, the Gwangju (GJ) stream suffers from chronic fecal contamination. In this study, to characterize levels of fecal pollution in the GJ stream, the monthly monitoring data for seven years (from 2001 to 2007) and the hourly monitoring data from two field experiments were examined with respect to seasonal/daily variations and spatial distribution under wet and dry weather conditions. This research revealed that concentrations of fecal indicator bacteria strongly varied depending on the prevalent meteorological conditions. That is, during the dry daytime, fecal indicator bacteria concentrations decreased due to inactivation from solar irradiation, but rapidly increased in the absence of sunlight, suggesting external source inputs. In addition, bacterial concentrations substantially increased during rainfall events, due probably to a major contribution from combined sewer overflow. The observations in this study can be useful for implementing fecal pollution management strategies and for predicting fecal contamination as a function of meteorological conditions.

The present study proposes a methodology for determining the effective dispersion coefficient based on the field measurements performed in Gwangju (GJ) Creek in South Korea which is environmentally degraded by the artificial interferences such as weirs and culverts. Many previous works determining the dispersion coefficient were limited in application due to the complexity and artificial interferences in natural stream. Therefore, the sequential combination of N-Tank-In-Series (NTIS) model and Advection-Dispersion-Reaction (ADR) model was proposed for evaluating dispersion process in complex stream channel in this study. The series of water quality data were intensively monitored in the field to determine the effective dispersion coefficient of E. coli in rainy day. As a result, the suggested methodology reasonably estimates the dispersion coefficient for GJ Creek with 1.25 m2/s. Also, the sequential combined method provided Number of tank-Velocity-Dispersion coefficient (NVD) curves for convenient evaluation of dispersion coefficient of other rivers or streams. Comparing the previous studies, the present methodology is quite general and simple for determining the effective dispersion coefficients which are applicable for other rivers and streams.

To characterize fluorescent dissolved organic matter (FDOM) in Yeongsan River in Korea, 110 water samples were acquired from March 2008 to November 2009 around the watershed. Excitation emission matrix data of fluorescence was obtained using spectrophotometric analysis and parallel factor (PARAFAC) model was used to characterize FDOM. The spatiotemporal variation and effect on FDOM were studied using an exploratory analysis and analysis of variance (ANOVA). According to the spatial and seasonal characteristics, we used post hoc analysis to identify significantly different sites and season. The PARAFAC results identified three most important PARAFAC components explaining 95.32% of total variance of original data-set. Seasons and sites had a significant effect on PARAFAC Components I and II (p ≤ 0.05), whereas season had a significant effect on Component III (p ≤ 0.05). There was no significant interaction between seasons and sites for all the three PARAFAC components (p > 0.05). For Components I and II, summer season was significantly different from other seasons (p ≤ 0.05), whereas for Component III, the fall season was significantly different from winter and summer seasons (p ≤ 0.05). These results indicate that ANOVA and post hoc analysis in our study not only confirmed the results of previous studies, but also revealed differences in seasons and sites for identified FDOMs as a new information. The methodology proposed in this paper can be a useful tool for finding sources and sinks of FDOMs in a riverine system influenced by natural organic matter impairment.

Elevated levels of antibiotic-resistant (AR) bacteria are routinely detected in surface water, whereas the dissemination of such bacteria across tributaries, rivers, or watersheds is often unknown. In a present study, one year of water quality monitoring was conducted to assess the sources, occurrence, and distribution of AR bacteria in a typical urban watershed, the Gwangju Watershed, Korea. For this study, a total of 828 Escherichia coli (E. coli) isolates obtained from 8 sites in stream water were tested for their resistance against 15 different antibiotics. Results revealed that while antibiotic resistance of the E. coli isolates showed no significant difference among sites, resistance rates to one and more antibiotics were always higher than those of non-antibiotic (below 50%), representing a high incidence of antibiotic resistance in the surface water. Among the antibiotics tested, the isolates were most resistant to tetracycline (50%), followed by carbenicillin (33%) and ampicillin (32%). However, the resistance rates showed no measurable difference between the isolates from the wastewater treatment plants and those from downstream sites, except for streptomycin (p < 0.05), indicating that untreated sewage discharge was not a primary source of the resistance. In addition, no significant difference in resistance rates was observed between summer and winter seasons. When the relationship between resistance rates in 828 E. coli isolates to antibiotics and those of multiple antibiotic resistance was further examined, a high correlation was found in streptomycin, carbenicillin, piperacillin, tetracycline, and ampicillin, thus suggesting that these antibiotics could be used as potential indicators for representing the resistance rate of E. coli isolates in surface water.

This paper describes a management scheme to control river water quality using additional water discharges from upstream dams, which results in an increase environmental flow (EF) followed by an enhancement of water quality in a target river. To suggest a creditable management plan among a suite of ideal scenarios, the monthly averaged water quality monitoring data from 2001 to 2006 at the Yeongsan (YS) River, Korea were investigated with respect to seasonal variation and spatial distribution. From the analysis, it was found that while biochemical oxygen demand (BOD5) level in the YS River was extremely high during the dry/drought season (April, May, and June; AMJ), the level was subsequently decreased during the monsoon season (July, August, and September; JAS) due mainly to the dilution effect of rainfall. To improve the water quality in AMJ, we here suggested a scenario of increasing EF using surplus water discharges from upstream dams, which was examined by one dimensional riverine water quality model, QUAL2E model. Simulation result showed that additional discharge from the upstream dams could lead, on average, to a 36% of water quality improvement in mainstream with respect to BOD5. Model coefficients were validated by comparing the six year monitoring data to minimize a sum of squares error, and showed a good agreement with the observed data. Overall, the methodology developed in this paper appears to be quite clear and straightforward, and thus, can be applied to a wide range of the flow managements or water quality controls in a stream with artificial structures.

Greater efforts to provide alternative scenarios are key to successful urban stream restoration planning. In this study, we discuss two different aspects of water quality management schemes, biodegradation and human health, which are incorporated in the restoration project of original, pristine condition of urban stream at the Gwangju (GJ) Stream, Korea. For this study, monthly monitoring of biochemical oxygen demand (BOD5) and fecal indicator bacteria (FIB) data were obtained from 2003 to 2008 and for 2008, respectively, and these were evaluated to explore pollutant magnitude and variation with respect to space and time window. Ideal scenarios to reduce target pollutants were determined based on their seasonal characteristics and correlations between the concentrations at a water intake and discharge point, where we suggested an increase of environmental flow and wetland as pollutants reduction drawing for BOD5 and FIB, respectively. The scenarios were separately examined by the Qual2E model and hypothetically (but planned) constructed wetland, respectively. The results revealed that while controlling of the water quality at the intake point guaranteed the lower pollution level of BOD5 in the GJ Stream, a wetland constructed at the discharge point may be a promising strategy to mitigate mass loads of FIB. Overall, this study suggests that a combination of the two can be plausible scenarios not only to support sustainable urban water resources management, but to enhance a quality of urban stream restoration assignment.

We report the efficiency enhancement in dye-sensitized solar cells (DSSCs) using Er3+/Yb3+-co-doped Y2O3 (i.e., Y2O3:Er3+/Yb3+) phosphor nanoparticles, prepared by a simple and cost-effective urea-based homogeneous precipitation method, for efficient near-infrared (NIR) sunlight harvesting. Under the light excitation at a wavelength of 980 nm, the as-prepared samples exhibited strong upconversion emissions at green and red visible wavelengths. To investigate the influence of Y2O3:Er3+/Yb3+ nanoparticles on the photovoltaic performance of DSSCs, the phosphor nanoparticles were incorporated into titanium dioxide films to form a composite photoelectrode. For the resulting DSSCs, the increased power conversion efficiency (PCE) of 6.68 % was obtained mainly by the increased photocurrent of J SC = 13.68 mA/cm2 due to the light harvesting enhancement via the NIR-to-visible upconversion process (cf., PCE = 5.94 %, J SC = 12.74 mA/cm2 for the reference DSSCs without phosphor nanoparticles), thus, indicating the PCE increment ratio of ~12.4 %.