René Guinebretière, Nathalie Boudet, Stephan Arnaud, Nils Blanc, Elsa Thune, Olivier Castelnau, David Babonneau, IRCER - Axe 3 : organisation structurale multiéchelle des matériaux (IRCER-AXE3), Institut de Recherche sur les CERamiques (IRCER), Institut de Chimie du CNRS (INC)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Centre National de la Recherche Scientifique (CNRS), Université Grenoble Alpes, CNRS, Grenoble INP, Institut Néel (Institut Néel), Institut Pprime (PPRIME), Université de Poitiers-Centre National de la Recherche Scientifique (CNRS)-ENSMA, Laboratoire Procédés et Ingénierie en Mécanique et Matériaux (PIMM), Conservatoire National des Arts et Métiers [CNAM] (CNAM)-Arts et Métiers Sciences et Technologies, HESAM Université (HESAM)-HESAM Université (HESAM), The QMAX furnace has been designed and built as part of the QMAX Project No. ANR-09-NANO-031 funded by the French National Research Agency (ANR). Experiments on the bulk-zirconia-based samples were done in the frame of the ASZTECH research program funded by the ANR (ANR-12-RMNP-0007)., CRG et Grands Instruments (CRG), Institut Néel (NEEL), Centre National de la Recherche Scientifique (CNRS)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Physique et Propriétés des Nanostructures PPNa (PPNa), Département Physique et Mécanique des Matériaux (Département Physique et Mécanique des Matériaux), Université de Poitiers-ENSMA-Centre National de la Recherche Scientifique (CNRS)-Université de Poitiers-ENSMA-Centre National de la Recherche Scientifique (CNRS)-Institut Pprime (PPRIME), Université de Poitiers-ENSMA-Centre National de la Recherche Scientifique (CNRS)-Université de Poitiers-ENSMA-Centre National de la Recherche Scientifique (CNRS), Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Poitiers-ENSMA-Centre National de la Recherche Scientifique (CNRS), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), Université de Poitiers-Centre National de la Recherche Scientifique (CNRS)-ENSMA-Université de Poitiers-Centre National de la Recherche Scientifique (CNRS)-ENSMA-Institut Pprime (PPRIME), and Université de Poitiers-Centre National de la Recherche Scientifique (CNRS)-ENSMA-Université de Poitiers-Centre National de la Recherche Scientifique (CNRS)-ENSMA
We acknowledge the ESRF and the French Collaborating Research Group (F-CRG) for provision of synchrotron radiation facility beamtime. H. Song is thanked for his work on the preliminary thermomechanical calculations and the general sizing of the furnace. The building of the furnace has been realized under the technical supervision of D. de Barros. The experiments on the sapphire vicinal surfaces and on the IUCr zirconia powder were realized with the valuable help of C. Matringe (IRCER) and J. B. Marijon (PIMM), respectively. The authors are thankful to I. Cabodi and O. Bories (Saint-Gobain CREE) for the supply of the bulk-zirconia-based materials. M. Huger and F. Gouraud from the IRCER laboratory and T. O¨ rs and V. Michel from the PIMM labora-tory are strongly thanked for their involvement during these experiments. The oxidation experiments were realized in the frame of a research program funded by the CEA Paris–Saclay Centre in collaboration with R. Guillou, M. Lesaux, D. Menut and J. L. Bechade, who are also gratefully acknowledged. A furnace that covers the temperature range from room temperature up to 2000 K has been designed, built and implemented on the D2AM beamline at the ESRF. The QMAX furnace is devoted to the full exploration of the reciprocal hemispace located above the sample surface. It is well suited for symmetric and asymmetric 3D reciprocal space mapping. Owing to the hemispherical design of the furnace, 3D grazing-incidence small- and wide-angle scattering and diffraction measurements are possible. Inert and reactive experiments can be performed at atmospheric pressure under controlled gas flux. It is demonstrated that the QMAX furnace allows monitoring of structural phase transitions as well as microstructural evolution at the nanoscale, such as self-organization processes, crystal growth and strain relaxation. A time-resolved in situ oxidation experiment illustrates the capability to probe the high-temperature reactivity of materials. The QMAX furnace has been designed and built as part of the QMAX Project No. ANR-09-NANO-031 funded by the French National Research Agency (ANR). Experiments on the bulk-zirconia-based samples were done in the frame of the ASZTECH research program funded by the ANR (ANR-12-RMNP-0007).