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1. Metal-free oxidative C(sp3)–H functionalization: a facile route to quinoline formaldehydes from methyl-azaheteroarenes

Author

Jiang-Shan Guo, Li-Qun Song, Tian-Qi Shao, Qing-Guo Meng, Yuan-Yuan Sun, Wei-Zhao Weng, Kai-Xuan Liu, and Yan-Ping Zhu

Subjects
chemistry.chemical_compound, Metal free, Chemistry, Organic Chemistry, Quinoline, Surface modification, General Chemistry, Oxidative phosphorylation, Combinatorial chemistry, Catalysis
Abstract

A facile protocol for the synthesis of quinoline formaldehydes via direct oxidative C–H bonds functionalization of methyl-azaheteroarenes in the presence of I2–DMSO has been described. This method is metal-free and easy to operate. This reaction provided a convenient route for the preparation of a range of important quinoline formaldehydes.

Published
2020
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