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Prototypes of borehole-wall imager instruments were developed and tested at a desert riverbed in Morocco and at a lake’s salty flat in the Atacama desert, to support the drilling activity of ExoMars rover. The onsite recorded borehole images contain information on the context that are lost during the sample acquisition. Benefits of the borehole-wall imaging is the easier maximal energy estimation of a fluvial flow, the detailed information on sedimentation and layering, especially the former existence of liquid water and its temporal changes, including paleo-flow direction estimation from grain imbrication direction. Benefits of laboratory analysis of the acquired samples are the better identification of mineral types, determination of the level of maturity of granular sediment, and identification of the smallest, wet weathered grains. Based on the lessons learned during the comparison of field and laboratory results, we demonstrate that recording the borehole-wall with optical instrument during/after drilling on Mars supports the paleo-environment reconstruction with such data that would otherwise be lost during the sample acquisition. Because of the lack of plate tectonism and the low geothermal gradient on Mars, even Ga old sediments provide observable features that are especially important for targeting Mars sample return and later crewed Mars missions.

In the current research, surface-modified SiO2 nanoparticles were used upon immersion in an applied base fluid (ethylene glycol:water = 1:1). The atomic layer deposition method (ALD) was introduced to obtain a thin layer of TiO2 to cover the surface of SiO2 particles. After the ALD modification, the TiO2 content was monitored by energy dispersive X-ray spectroscopy (EDS). Transmission electron microscopy (TEM) and FT-IR spectroscopy were applied for the particle characterization. The nanofluids contained 0.5, 1.0, and 1.5 volume% solid particles and zeta potential measurements were examined in terms of colloid stability. A rotation viscosimeter and thermal conductivity analyzer were used to study the nanofluids' rheological properties and thermal conductivity. These two parameters were investigated in the temperature range of 20 °C and 60 °C. Based on the results, the thin TiO2 coating significant impacted these parameters. [ABSTRACT FROM AUTHOR]

In this paper, we present a study on thermal conductivity and viscosity of nanofluids containing novel atomic layer deposition surface-modified carbon nanosphere (ALD-CNS) and carbon nanopowder (ALD-CNP) core-shell nanocomposites. The nanocomposites were produced by atomic layer deposition of amorphous TiO2. The nanostructures were characterised by scanning (SEM) and transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, thermogravimetry/differential thermal analysis (TG/DTA) and X-ray powder diffraction (XRD). High-concentration, stable nanofluids were prepared with 1.5, 1.0 and 0.5 vol% nanoparticle content. The thermal conductivity and viscosity of the nanofluids were measured, and their stability was evaluated with Zeta potential measurements. The ALD-CNS enhanced the thermal conductivity of the 1:5 ethanol:water mixture by 4.6% with a 1.5 vol% concentration, and the viscosity increased by 37.5%. The ALD-CNS increased the thermal conductivity of ethylene–glycol by 10.8, whereas the viscosity increased by 15.9%. The use of a surfactant was unnecessary due to the ALD-deposited TiO2 layer. [ABSTRACT FROM AUTHOR]

Hydrogenation of CO 2 to hydrocarbons in fixed-bed and annular reactors (AR) can be limited via problems associated with high water production as the main by-product. Selective in-situ water removal using a hydrophilic membrane can be a promising solution for enhancing reactor performance. To this aim, a one-dimensional heterogeneous model comprising mass and heat transfers in the shell and tube of a membrane reactor (MR) is proposed. Firstly, the performance of different rector configurations exhibiting similar cross sectional areas and volumes are compared. Afterwards, influential factors affecting the MR performance such as shell/tube temperature, sweep ratio (θ) and pressure ratio (φ) are investigated thoroughly. Results show that increasing initial tube/shell temperature has positive effect on total hydrocarbons yield. However, sharp and sudden temperature elevation (hot spot) due to large extent of water removal, may have detrimental effects on catalyst performance. Moreover, it is observed that increasing θ and φ alter products distribution due to the equilibrium displacement and results in the lack of H 2 for further reactions. In addition, kinetic parameters corresponding to the inhibiting effect of water are indicated to have significant roles in hydrocarbons distribution. Therefore, water removal impose various changes, which cannot be considered independently in analyzing the MR performance. Image 1 • Modeling of CO 2 hydrogenation in membrane reactor is presented. • Effect of in-situ water removal on the reactor performance is analyzed. • Hydrocarbons distribution and reactor temperature are assessed in AR and MR. • Effect of sweep ratio and sweep pressure on products yield are studied. [ABSTRACT FROM AUTHOR]

Abstract Global warming, climate change, fossil fuel depletion and steep hikes in the price of environmentally friendly hydrocarbons motivate researchers to investigate CO 2 hydrogenation for hydrocarbons production. However, due to the reaction complexities and varieties of produced species, the process mechanism and subsequently estimation of the kinetic parameters have been controversial yet. Therefore, estimating the kinetic parameters using Artificial Bee Colony (ABC) and Differential Evolution (DE) optimization algorithms based on Langmuir-Hinshelwood-Hougen-Watson (LHHW) mechanism is proposed as a possible remedy to fulfil the requirements. To this end, a one-dimensional heterogeneous model comprising detailed reaction rates of reverse water gas shift (RWGS), Fisher-Tropsch (FT) reactions and direct hydrogenation (DH) of CO 2 is developed. It is observed that ABC exhibiting 6.3% error in predicting total hydrocarbons selectivity is superior to DE algorithm with 32.9% error. Therefore, the model employed the estimated kinetic parameters obtained via ABC algorithm, is exploited for products distribution analysis. Results reveal that maximum 73.21% hydrocarbons (C 1 C 4) selectivity can be achieved at 573 K and 1 MPa with 0.85% error compared to the experimental value of 72.59%. Accordingly, the proposed model can be exploited as a powerful tool for evaluating and predicting the performance of CO 2 hydrogenation to hydrocarbons process. Graphical abstract Image 1 Highlights • Studying kinetic parameters of CO 2 hydrogenation has remained controversial. • One-dimensional heterogeneous model including detailed reaction rates is developed. • Kinetic parameters are estimated via ABC and DE algorithms using experimental data. • Components distribution along reactor length are presented based on ABC algorithm. • Performance of the theoretical reactor is compared with available experimental data. [ABSTRACT FROM AUTHOR]

From both environmental and energy-saving points of view, solar heating and cooling systems have recently proven themselves in the commercial world as the environmentally friendly and sustainable energy systems which can replace the systems powered by conventional sources of energy such as fossil fuels and electricity. In the present paper, the research contributions conducted on solar absorption cooling systems, integrated with different auxiliary energy devices, are comprehensively reviewed and discussed. Also, various cooling systems integrated with solar technologies, i.e., flat-plate collector, evacuated tube collector, compound parabolic collector and parabolic trough collector, are reviewed. The survey and comparison are carried out in terms of some crucial parameters such as coefficient of performance, annual energy consumption and payback period. Further, this work briefly presents and discusses some possible opportunities for future works from the efficiency viewpoint. [ABSTRACT FROM AUTHOR]

Nanofluids are the most attractive mean to enhance the performance of heat transfer devices. Several types of nanoparticles were utilized as they have high thermal conductivity. Renewable energy makes use of these nanofluids special in solar collectors. Evacuated tube solar collector is one of the most utilized solar collectors in thermal applications. CeO 2 nanoparticles were used in the presented study. The mean diameter of CeO 2 was 25 nm. A stable CeO 2 /water was made. The stability was checked using Zeta potential machine. Experiments were carried out using three different volume concentration of CeO 2 nanoparticles of 0.015%, 0.025%, and 0.035%. The thermal performance of the evacuated tube solar collector was examined at different mass flux rates. Results showed that the temperature difference between inlet and outlet flow and absorbed energy increase when nanofluids are used. The volume fraction flow rate of 0.035% at the mass flux rate of 0.017 kg/s.m 2 had the maximum heat removable factor, the thermo-optical characteristic of the collector, and the thermal loss coefficient. The thermo-optical characteristic of the collector of tube solar corrector is raised up to 34%. [ABSTRACT FROM AUTHOR]

We report heat pulse experiments at room temperature that cannot be described by Fourier's law. The experimental data are modeled properly by the Guyer-Krumhansl equation, in its over-diffusion regime. The phenomenon may be due to conduction channels with differing conductivities and parallel to the direction of the heat flux. [ABSTRACT FROM AUTHOR]

A CFD model was performed with commercial software through the adoption of the finite volume method and a SIMPLE algorithm. SiO2-P25 particles were added to water/ethylene glycol as a base fluid. The result is considered a new hybrid nanofluid (HN) for investigating heat transfer (HT). The volume concentrations were 0.5, 1.0, and 1.5%. The Reynolds number was in the range of 5000–17,000. The heat flux (HF) was 7955 W/m2, and the wall temperature was 340.15 K. The numerical experiments were performed strictly following the rules that one should follow in HT experiments. This is important because many studies related to nanofluid HT overlook these details. The empirical correlations that contain the friction factor perform better with higher Reynolds numbers than the correlations based only on Reynolds and Prandtl numbers. When temperature differences are moderate, researchers may consider using constant properties to lower computational costs, as they may give results that are similar to temperature-dependent ones. Compared with previous research, our simulation results are in agreement with the experiments in real time. [ABSTRACT FROM AUTHOR]

The progressive use of renewable energy sources to ensure a continuous and abundant energy supply is the significant target towards a sustainable and secure energy system. Previously, the countries that had relied on fossil fuel as a dominating energy source are now endorsing energy system transition towards renewable energy sources. In this study, a comparative assessment of the energy problems of South Asian countries is summarized. Nevertheless, there are many similarities and differences in the electricity supply system of these countries. Long-term planning for renewable energy development is suggested for a diverse population and dispersed geographical location considering all the significant challenges. However, appropriate schemes are imperative for integrating significant renewable energy sources. This study introduces a foresight plan of the electricity model according to the demand and supply balance for extensive technical analysis. The EnergyPLAN modeling tool was employed to work out a more ambitious VRE integration scenario than the official plans. The reference model was validated according to legitimate and authentic data, and then, the technically most feasible renewable energy-based alternate scenario was built. The additional grid integration cost of variable renewable energy was quantitatively investigated for comprehensive power system modeling for a real-time economic analysis. The results may be adapted and support developing more sustainable power generation serving 1787 million in South Asian countries. [ABSTRACT FROM AUTHOR]

Halloysite nanotube (HNT) which is cheap, natural, and easily accessible 1D clay, can be used in many applications, particularly heat transfer enhancement. The aim of this research is to study experimentally the pool boiling heat transfer (PBHT) performance of novel halloysite nanofluids at atmospheric pressure condition from typical horizontal heater. The nanofluids are prepared from halloysite nanotubes (HNTs) nanomaterials-based deionized water (DI water) with the presence of sodium hydroxide (NaOH) solution to control pH = 12 to obtain stable nanofluid. The nanofluids were prepared with dilute volume concentrations of 0.01–0.5 vol%. The performance of PBHT is studied via pool boiling curve and pool boiling heat transfer coefficient (PBHTC) from the typical heater which is the copper horizontal tube with a thickness of 1 mm and a diameter of 22 mm. The temperatures of the heated tube surface are measured to obtain the PBHTC. The results show an improvement of PBHTC for halloysite nanofluids compared to the base fluid. At 0.05 vol% concentration, HNT nanofluid has the best enhancement of 5.8% at moderate heat flux (HF). This indicates that HNT is a potential material in heat transfer applications. [ABSTRACT FROM AUTHOR]

Thermodynamics -- contrary to its name -- is not a dynamic theory. However, some relatively new developments, like finite time, endo-reversible or ordinary thermodynamics introduce time into thermostatics. In this framework the Second Law becomes a set of conditions ensuring the asymptotic stability of equilibrium. In this manuscript some examples are shown, how this basic conceptual change can lead to a profound understanding. [ABSTRACT FROM AUTHOR]

A comparative research on stability, viscosity (µ), and thermal conductivity (k) of carbon nanosphere (CNS) and carbon nanopowder (CNP) nanofluids was performed. CNS was synthesized by the hydrothermal method, while CNP was provided by the manufacturer. Stable nanofluids at high concentrations 0.5, 1.0, and 1.5 vol% were prepared successfully. The properties of CNS and CNP nanoparticles were analyzed with Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), specific surface area (SBET), X-ray powder diffraction (XRD), thermogravimetry/differential thermal analysis (TG/DTA), and energy dispersive X-ray analysis (EDX). The CNP nanofluids have the highest k enhancement of 10.61% for 1.5 vol% concentration compared to the base fluid, while the CNS does not make the thermal conductivity of nanofluids (knf) significantly higher. The studied nanofluids were Newtonian. The relative µ of CNS and CNP nanofluids was 1.04 and 1.07 at 0.5 vol% concentration and 30 °C. These results can be explained by the different sizes and crystallinity of the used nanoparticles. [ABSTRACT FROM AUTHOR]

Nanofluids obtained from halloysite and de-ionized water (DI) were prepared by using surfactants and changing pH for heat-transfer applications. The halloysite nanotubes (HNTs) nanofluids were studied for several volume fractions (0.5, 1.0, and 1.5 vol%) and temperatures (20, 30, 40, 50, and 60 °C). The properties of HNTs were studied with a scanning electron microscope (SEM), energy-dispersive X-ray analysis (EDX), Fourier-transform infrared (FT-IR) spectroscopy, X-ray powder diffraction (XRD), Raman spectroscopy and thermogravimetry/differential thermal analysis (TG/DTA). The stability of the nanofluids was proven by zeta potentials measurements and visual observation. With surfactants, the HNT nanofluids had the highest thermal conductivity increment of 18.30% for 1.5 vol% concentration in comparison with the base fluid. The thermal conductivity enhancement of nanofluids containing surfactant was slightly higher than nanofluids with pH = 12. The prepared nanofluids were Newtonian. The viscosity enhancements of the nanofluid were 11% and 12.8% at 30 °C for 0.5% volume concentration with surfactants and at pH = 12, respectively. Empirical correlations of viscosity and thermal conductivity for these nanofluids were proposed for practical applications. [ABSTRACT FROM AUTHOR]

In this study, we introduced a novel hybrid artificial intelligence approach of rotation forest (RF) as a Meta/ensemble classifier based on alternating decision tree (ADTree) as a base classifier called RF-ADTree in order to spatially predict gully erosion at Klocheh watershed of Kurdistan province, Iran. A total of 915 gully erosion locations along with 22 gully conditioning factors were used to construct a database. Some soft computing benchmark models (SCBM) including the ADTree, the Support Vector Machine by two kernel functions such as Polynomial and Radial Base Function (SVM-Polynomial and SVM-RBF), the Logistic Regression (LR), and the Naïve Bayes Multinomial Updatable (NBMU) models were used for comparison of the designed model. Results indicated that 19 conditioning factors were effective among which distance to river, geomorphology, land use, hydrological group, lithology and slope angle were the most remarkable factors for gully modeling process. Additionally, results of modeling concluded the RF-ADTree ensemble model could significantly improve (area under the curve (AUC) = 0.906) the prediction accuracy of the ADTree model (AUC = 0.882). The new proposed model had also the highest performance (AUC = 0.913) in comparison to the SVM-Polynomial model (AUC = 0.879), the SVM-RBF model (AUC = 0.867), the LR model (AUC = 0.75), the ADTree model (AUC = 0.861) and the NBMU model (AUC = 0.811). [ABSTRACT FROM AUTHOR]

We used a novel hybrid functional machine learning algorithm to predict the spatial distribution of landslides in the Sarkhoon watershed, Iran. We developed a new ensemble model which is a combination of a functional algorithm, stochastic gradient descent (SGD) and an AdaBoost (AB) Meta classifier namely ABSGD model to predict the landslides. The model incorporates 20 landslide conditioning factors, which we ranked using the least-square support vector machine (LSSVM) technique. For the modeling, we considered 98 landslide locations, of which 70% (79) were used for training and 30% (19) for validation processes. Model validation was performed using sensitivity, specificity, accuracy, the root mean square error (RMSE) and the area under the receiver operatic characteristic (AUC) curve. We also used soft computing benchmark models, including SGD, logistic regression (LR), logistic model tree (LMT) and functional tree (FT) algorithms for model validation and comparison. The selected conditioning factors were significant in landslide occurrence but distance to road was found to be the most important factor. The ABSGD model (AUC= 0.860) outperformed the LR (0.797), SGD (0.776), LMT (0.740) and FT (0.734) models. Our results confirm that the combined use of a functional algorithm and a Meta classifier prevents over-fitting, reduces noise and enhances the power prediction of the individual SGD algorithm for the spatial prediction of landslides. [ABSTRACT FROM AUTHOR]

The non-Fourier heat conduction phenomenon on room temperature is analyzed from various aspects. The first one shows its experimental side, in what form it occurs, and how we treated it. It is demonstrated that the Guyer-Krumhansl equation can be the next appropriate extension of Fourier's law for room-temperature phenomena in modeling of heterogeneous materials. The second approach provides an interpretation of generalized heat conduction equations using a simple thermo-mechanical background. Here, Fourier heat conduction is coupled to elasticity via thermal expansion, resulting in a particular generalized heat equation for the temperature field. Both aforementioned approaches show the size dependency of non-Fourier heat conduction. Finally, a third approach is presented, called pseudo-temperature modeling. It is shown that non-Fourier temperature history can be produced by mixing different solutions of Fourier's law. That kind of explanation indicates the interpretation of underlying heat conduction mechanics behind non-Fourier phenomena. [ABSTRACT FROM AUTHOR]

A new evaluation method for a transient measurement of thermophysical properties is presented in this paper. The aim of the research was to couple a new automatic evaluation procedure to the BICOND thermophysical property measurement method to enhance the simultaneous determination of the temperature dependent thermal conductivity and volumetric heat capacity. The thermophysical properties of two different polymers were measured and compared with the literature data and with the measurement results that were done by well-known, traditional methods. The BICOND method involves a step-down cooling, recording the temperature histories of the inner and the outer surfaces of a hollow cylindrical sample and the thermophysical properties are evaluated from the solution of the corresponding inverse heat conduction using a genetic algorithm-based method (BIGEN) developed by the authors. The BIGEN is able to find the material properties with any kind of temperature dependency, that is illustrated through the measurement results of poly(tetrafluoroethylene) (PTFE) and polyamide (PA) samples. [ABSTRACT FROM AUTHOR]