1. Giant magnetocaloric effect in Mn1-x(Ti0.5V0.5)xAs: Experiments and calculations.
- Author
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Balli, M., Fruchart, D., Gignoux, D., Dupuis, C., Kedous-Lebouc, A., and Zach, R.
- Subjects
ENTROPY ,MAGNETOSTRICTION ,ADIABATIC demagnetization ,MAGNETIC fields ,MATHEMATICAL models ,CURIE temperature ,MAGNETIZATION - Abstract
In this paper, we present the giant magnetocaloric effect exhibited by the Mn
1-x (Ti0.5 V0.5 )x As compound with x=0.1. The ordering temperature decreases from 318 K in the case of MnAs (x=0) to 266 K in the case of Mn0.9 Ti0.05 V0.05 As (x=0.1). A large magnetic entropy change -ΔSm attributed to a first order magnetic transition has been observed. For Mn0.9 Ti0.05 V0.05 As, the maximum of -ΔSm occurs near TC =266 K and is about 30 J/kg K for an applied field change of 2 T, a value very close to that (∼31 J/kg K) measured in MnAs. For materials with a first order transition at TC , the observed magnetocaloric effect enhancement can be explained by magnetoelastic effects which are due to structural changes. A model based on the phenomenological approach of Bean and Rodbell [Phys. Rev. 126, 104 (1962)] has been developed in order to describe such a behavior. In this paper we apply this model to describe the giant magnetocaloric effect exhibited by Mn1-x (Ti0.5 V0.5 )x As (x=0, 0.1) materials. [ABSTRACT FROM AUTHOR]- Published
- 2008
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