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1. One-pot synthesis of GABA amides via the nucleophilic addition of amines to 3,3-disubstituted cyclopropenes.

Author

Maslivetc VA, Rubina M, and Rubin M

Subjects
Molecular Structure, Stereoisomerism, Amides chemical synthesis, Amines chemistry, Cyclopropanes chemistry, gamma-Aminobutyric Acid chemistry
Abstract

A one-pot synthesis of various GABA amides has been demostrated, employing the nucleophilic addition of primary and secondary amines across the double bond of cyclopropene-3-carboxamides, followed by ring-opening of the resulting donor-acceptor cyclopropanes and subsequent in situ reduction of enamine (imine) intermediates.

Published
2015
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