Search

This research aims to evaluate the hydrogen production and removal ability of impurity (e.g. tar and NH3) generated from sewage and textile sludge co-gasification using lab-scale fluidized-bed gasifier with an integrated hot-gas cleaning system. The gasification temperature and equivalence ratio (ER) were controlled at 850 °C and 0.2, as well as the hot gas cleaning system operated at 250 °C with the combination of zeolite, calcined dolomite, and activated carbon. Experimental results indicated that the H2 and CO yield in co-gasification of the tested sludge ranged from 2.12 to 2.45 mol/kg and from 2.83 to 3.98 mol/kg, respectively. The overall energy content of produced gas ranged between 2.40 and 2.63 MJ/kg, and cold gas efficiency (CGE) was nearly 15%. The impurities of produced gas were effectively mitigated by the hot-gas cleaning system, which could remove approximately 90% of the heavy fraction tar, up to 77% of total tar, and about 35% of ammonia. In summary, the combination of the fluidized-bed gasifier and the hot-gas cleaning system had been well developed for purifying the syngas produced from the tested sludge, and it could be applied to other organic wastes in the future.

The effect of environmental pollutants on living organisms can be assessed by studying the changes in the indigenous microbial community. Therefore, in this study, cultivatable bacterial community in nonpolluted as well as household sewage and industrially polluted water of Lai Nullah flowing through Islamabad and Rawalpindi, Pakistan was analyzed. Bacterial community composition and population present in the polluted water were significantly different from the nonpolluted water (P −1 at all the study sites. During plate assay, bacterial strains found at polluted sites showed resistance to selected heavy metals with highest minimum inhibitory concentration for lead (8 mmol·L−1) followed by copper (5 mmol·L−1), nickel (3 mmol·L−1), and cadmium (1 mmol·L−1). All the bacterial isolates also showed various levels of resistance against antibiotics ampicillin, tetracycline, ciprofloxacin, and vancomycin using broth microdilution method. Current research provides new insight into the effect of household sewage and the industrially polluted water of Lai Nullah on the indigenous bacteria.

Due to the frequent occurrence of oil spills and the large-scale production of oily wastewater, the treatment of oily sewage has become an important issue for sustainable development. Recently, materials prepared from lignocellulosic biomass (LCB) for oil-water separation have been found to be effective due to their high separation efficiency, good recyclability, and superior sustainability. However, few reviews have focused on the advantages and limitations of LCB for sewage treatment. This review summarizes the performance of modified LCB in oily wastewater treatment, in terms of the advanced modification methods applied and the structural dimensions of LCB materials according to the principle of superwetting oil-water separation. Research on the preparation technologies, separation mechanisms, and treatment efficiency of different LCB materials are briefly summarized, along with the characteristics of different LCB material types for oily wastewater treatment. Finally, the future prospects and challenges faced in the development of LCB materials are discussed.

The use of antidepressants is widespread in modern times. Thus, they present a potential risk for ecosystems due to occurrence in domestic sewage containing unaltered metabolites and structures, even after the treatment plants have processed the sewage. The current research investigated the sorption and desorption of antidepressants (citalopram, venlafaxine, fluoxetine, sertraline, and amitriptyline) and caffeine from freshwater sediment and sewage sludge. The samples of freshwater sediment were collected in a river spring in an area with few anthropogenic sources of pollution and samples of sewage sludge were taken from stabilization ponds of a sewage treatment. The matrices were mainly composed of organic fractions, sediment of humic nature, and aliphatic biomolecules in sludges. The presence of silt and clay in the sediment proved to be important for the sorption process when compared to the flocs and colloidal structure of the sludge. The kinetic study indicated pseudo-first order behavior. The Freundlich isotherm was satisfactorily used in the interpretation of sorption and desorption for all analytes and matrices. The high percentages obtained for desorption suggest analyte mobility, which is more intense in the sludge than in the sediment since each matrix has a different composition. It can be considered that the information obtained here reinforces the ecotoxicological concern with respect to pharmacological residues in the environment, as processes of retention by sorption in the sludge and the sediment have been confirmed, as well as the preferential partition of some analytes by the aqueous phase.

The Water Quality Index is one of the most effective tools to communicate information on the quality of water to the people. An attempt was made to assess the annual and seasonal status of Surajkund and Rani Pond, Aurangabad, Bihar, India using the overall Index of Pollution and Water Quality Index from November 2017 to October 2019. The values of eleven parameters namely water temperature, pH, electrical conductivity, dissolved oxygen, biochemical oxygen demand, total alkalinity, hardness, total dissolved solids, chloride, nitrate and fluoride were calculated following standard methodology. A statistically significant difference was found among these parameters. The values were compared with the standard to determine the overall Index of Pollution and Water Quality Index. Results indicated that electrical conductivity, total alkalinity and total dissolved solid were higher than prescribed limits. The values 1.5–3.50 of the overall Index of Pollution estimated that the average status of water of Surajkund was acceptable (C2) but Rani Pond and Surajkund during the summer season were slightly polluted (C3). The values 74.18–233.89 of the Water Quality Index inferred that the average status of water of Surajkund and Rani Pond was slightly polluted (C3). However, on a seasonal basis, the water quality of Surajkund was acceptable (C2) but Rani Pond was slightly polluted (C3) to polluted (C4). The results revealed anthropogenic activity and entry of untreated sewage in these water bodies. The water quality felt the necessity to adopt proper management policy and conservation efforts to these water bodies.

The paper presents the results of a study of parameters used for determining the amount of organic pollutants in wastewater flowing into a collective wastewater treatment plant with a population equivalent of about 120 000 PE. The plant constituted part of a sewage system. Assays were performed for biochemical oxygen demand (BOD5), chemical oxygen demand (CODCr), permanganete index (CODMn) and total organic carbon (TOC). In addition, the pH of wastewater and its alkalinity were determined. Sampling of incoming wastewater and measurement of physicochemical parameters were performed once a week, in the spring. A total of 44 samples of wastewater were collected. The correlations between the individual parameters and the correlations between the ratios of these parameters were determined. It was found that it was possible to estimate, with suffi cient accuracy, the values of selected parameters for determining the concentrations of organic compounds in municipal wastewater, knowing the values of other parameters in this group. Moreover, it was shown that, knowing the relationship between the analyzed parameters, one can find multiple regression equations for a given type of wastewater, which allow one to calculate the remaining relationships with a good fit, i.e. a determination factor R2greater than 0.6

Urban black blooms that are primarily caused by organic carbon are deleterious environmental problems. However, detailed studies on the microbial characteristics that form urban black blooms are lacking. In this study, we observed the composition, diversity, and function of bacterial community in the overlying water and sediments during the occurrence and remediation of urban black blooms using high-throughput 16S rRNA gene amplicon sequencing analysis. First, we found that pivotal consortia in the overlying water increased significantly during the formation of black blooms, including the genera Acidovorax, Brevundimonas, Pusillimonas, and Burkholderiales involved in the degradation of refractory organics, as well as the genera Desulfovibrio, Dechloromonas, and Rhizobium related to the production of black and odorous substances. An RDA analysis revealed that chemical oxygen demand, dissolved oxygen, and oxidation reduction potential were related to the changes in microbial community composition. Furthermore, aeration was found to accelerate the removal of ammonia nitrogen and enhance the function of microbial community by stimulating the growth of order Planktomycetes during the remediation of black blooms, but aeration substantially damaged the microbial diversity and richness. Therefore, the health of the aquatic ecosystem should be comprehensively considered when aeration is applied to restore polluted waterbodies. Notably, we observed a large number of pathogenic bacteria in urban black blooms, which emphasizes the importance of treating domestic sewage so that it is harmless. Together, these findings provide new insights and a basis to prevent and manage urban black blooms.

While monitoring the presence of antibiotic resistance in municipal wastewater bacteria from Mexico City, five Escherichia coli isolates were found to be resistant to carbapenems, antibiotics of “last resort” used mostly in hospitals. Further analysis revealed that these carbapenem-resistant isolates carried the gene encoding a metallo-beta-lactamase, NDM-5. The gene was found to be beared by a large, ∼145 kb conjugative plasmid, which also carries putative genes encoding resistance to sulfonamides, trimethoprim, tetracycline, ciprofloxacin, and chloramphenicol (although no phenotypic chloramphenicol resistance was detected) and quaternary-ammonium compounds. The plasmid also carried gene mobility determinants, such as integron integrase and two transposases. In addition to the direct public health threat posed by the presence of such multi-resistant organisms in wastewater released into the environment and used for crop irrigation; it is particularly concerning that carbapenem-resistant E. coli is rather rare in Mexican hospitals (

Sewage released from lakeside development can introduce nutrients and micropollutants that can restructure aquatic ecosystems. Lake Baikal, the world's most ancient, biodiverse, and voluminous freshwater lake, has been experiencing localized sewage pollution from lakeside settlements. Nearby increasing filamentous algal abundance suggests benthic communities are responding to localized pollution. We surveyed 40‐km of Lake Baikal's southwestern shoreline from 19 to 23 August 2015 for sewage indicators, including pharmaceuticals, personal care products, and microplastics, with colocated periphyton, macroinvertebrate, stable isotope, and fatty acid samplings. The data are structured in a tidy format (a tabular arrangement familiar to limnologists) to encourage reuse. Unique identifiers corresponding to sampling locations are retained throughout all data files to facilitate interoperability among the dataset's 150+ variables. For Lake Baikal studies, these data can support continued monitoring and research efforts. For global studies of lakes, these data can help characterize sewage prevalence and ecological consequences of anthropogenic disturbance across spatial scales.

The action mechanism of pollutants in solar-water evaporation (SWE) is a crucial scientific issue in the utilization of sewage resources. A single-atom copper-carbon system (Cu/SA) was used for the first time in SWE for utilization of sewage resources. Experiments and theoretical calculations show that atomic-level dispersed Cu-N coordination promotes carrier orientation migration. Electron-rich Cu sites with high carrier concentrations can enhance the localized surface plasmon resonance (LSPR) and thus enhance the nonradiative relaxation energy release. The suitable adsorption energy of single-atom copper sites for H2O could effectively promote the evaporation of water. Benefiting from these effects, Cu/SA achieves a high water evaporation rate (3.325 kg/m2·h under 2 suns). The action mechanism of various pollutants in SWE is explored. The metal ions in sewage can be deposited by photogenerated electron reduction, which enhances the light absorption properties. Dyes with a visible light absorption capability can increase the light absorption performance. Electron-donating organics can facilitate water evaporation process by promoting photogenerated carrier separation. A variety of sewage can be effectively resourced to produce clean water. This study can provide a fundamental scientific understanding of the behavior mechanism of pollutants in SWE, thus providing viable technical support for wastewater resource utilization.

Group A rotavirus (RVA), an enteric virus, is a major cause of gastroenteric disease and it is known to cause mortality among children and infants. The applicability of coliforms and coliphages as indicators for RVA was evaluated in this study. The abundance of RVA, ‘SUSP2’, a novel ‘superspreader’ somatic coliphage, MS2, a male-specific coliphage, and coliforms were monitored in two lakes located in the neighboring cities of Mumbai and Thane, India. RVA was detected in 71% and 60% of the composite samples collected from Powai lake in Mumbai and Masunda lake in Thane, respectively. MS2 was detected in 81% and 79%, while SUSP2 was detected in 75% and 81% of the composite samples from Powai lake and Masunda lake, respectively. The maximum RVA, MS2, and SUSP2 concentrations in the composite samples from Powai lake were 5.47 × 105, 6.75 × 102, and 3.47 × 103 copies per 100 mL, respectively, while, the corresponding values for Masunda lake were 2.13 × 104, 2.61 × 104, and 2.21 × 104 copies per 100 mL, respectively. The viral counts were found to be lowest during the monsoon and highest during winter. For samples collected from these lakes, the seasonal correlation between RVA and the indicators was analyzed using Spearman's rank correlation. The coliphages showed a moderate to strong positive correlation with RVA particularly in winter and demonstrated a Spearman correlation coefficient (ρ) in the range of 0.59–0.87 (p < 0.05). However, in the summer and monsoon, a significant correlation between the coliphage, MS2, and RVA was observed only in Powai lake. Thus, coliphages are good indicators of RVA, especially in the winter months, when the occurrence of RVA in the lakes is highest. In the summer and monsoon, both coliphages and coliforms need to be monitored to predict the presence of RVA with a higher degree of confidence. Principal component analysis (PCA) and binary logistic regression (BLR) also confirmed MS2 as a better indicator of RVA. Pearson's correlation coefficient (r) ranged between 0.46–0.74 (p < 0.05). This is the first study reporting the viral load in surface water bodies in India across seasons and the correlation between RVA and coliphages.

The concentration efficiency with stirring outperformed that with aeration reaching 88.2% without additional chemicals. Magnetic seeds and magnetic field enhanced the capture and settling performance of sludge.

Due to the global trend of urbanization, the amount of sewage water is increasing in cities. This calls for efficient treatment of the resulting sewage sludge. To date, in the 27 European Union member countries (EU-27), the prevailing treatment method is application on arable land. Anaerobic digestion is one of the treatment methods being increasingly used nowadays. However, the resulting digestate requires further utilization. Therefore, in this study, the environmental performance of composting, combustion, and pyrolysis options for dewatered sewage sludge digestate is evaluated based on a life cycle assessment. The results show that digestate combustion and composting performed better than pyrolysis for most of the selected impact categories. However, pyrolysis of sewage sludge is still under development, and there are, to some degree, uncertainties in the data related to this technology; thus, more information for the performance assessment of pyrolysis is still required.

Water hyacinth (Eichhornia crassipes) is an aquatic weed that is causing numerous adverse effects on freshwater bodies. Developing countries are still battling on how to control the growth of this weed without damaging other aquatic lives important to man. Literatures have revealed that most developing countries are still discharging untreated sewage containing heavy metals into waterbodies due to economic and technical constraints in handling conventional methods of treating heavy metals. Hence, the research investigated the possibility of using water hyacinth to adsorb heavy metals (Ni2+ and Cr3+) from sewage before discharging into waterbodies in order to solve two major problems faced in the aquatic environment, at minimal cost. This was achieved by using the said weed (water hyacinth) to treat Ni2+ and Cr3+ solutions prepared in the lab. Results showed that the adsorption process for both ions occurred on heterogeneous surfaces while the mechanism of adsorption followed Pseudo 2nd–order kinetics. The Freundlich, Langmuir and Temkin adsorption capacities for Ni2+ are 19.6925 L/g, 0.7470 L/mg and 1.1093 L/mg respectively while for Cr3+ are 16.814 L/g, 0.7011 L/mg and 0.9623 L/mg respectively. However, the heat of sorption for Ni2+ is 96.906 KJ/mol while that of Cr3+ is 98.749 KJ/mol. Furthermore, FT-IR analysis identified seven functional groups involved in the binding sites with more of hydroxyl group (O–H) from alcohol and carboxylic acid. It was concluded that water hyacinth could be used as a potential bio-adsorbent of metal ions.

A distinctive feature of waste water of fi sh processing enterprises is the high content of organic substances: COD - 620-3500 mg/L, BOD-220-2860 mg/L. The ratio of BOD:COD=0.68-0.83 in the waste water of fi sh processing enterprises shows a high potential for the use of biological treatment methods. Further study requires the removal of biogenic elements, because, for example, for a fi sh cannery, the ratio of BOD:N:P=100:3.79:1.08 and 100:4.77:0.57. This article presents the experience of design, construction, start-up and adjustment of sewage treatment facilities of a fi sh processing enterprise. For wastewater treatment, the following scheme was developed and manufactured by the ECOLOS company: a receiving well with a basket, a drum grate, a horizontal grease trap, an homogenizer, a reagent pressure fl otation unit, a membrane bioreactor, and ultraviolet disinfection. The quality of waste water at the outlet of the treatment facilities meets the requirements of the Normative- permissible discharge provided by LLC «Russkaya Treska».

Anthropogenic and dynamic impacts on facilities of underground urban infrastructure increase at intensive development of megacities. The unique long-operating underground structures of sewage system require special protection against anthropogenic influence as their wear degree in difficult soil conditions reaches 70 % and more. Therefore, providing structural (mechanical) safety of underground structures of excessive level of danger and responsibility defines sustainable operation and future development of geotechnical infrastructure of the megacity in general. Long-term studying dynamics of changes of technical state of underground sewage structures of the megacity, long operating (for more than 70 years) in soft soils, allowed establishing regularities of influence of intensive anthropogenic and dynamic impacts on this process. For the first time, based on developed continuous models of defective structures potentially dangerous sections have been identified, they are subjected to manifestation of critical failures; ways of their correction are presented. Numerical simulation has defined borders of defectless joint operation of the system “target area - geomassif - underground structure". Scientific substantiation of boundaries of areas with potentially dangerous sections of underground sewage facilities with account of external anthropogenic and dynamic impacts constitutes the basis for elaborating regulations on safe development of geotechnical infrastructure of the historical area of St. Petersburg. The proposed methods of monitoring and protection of geotechnical infrastructure have been successfully used for many years by St. Petersburg Vodokanal in areas of influence of anthropogenic factors and objects under construction on underground structures, they ensure an optimal combination of sustainable operation and development of geotechnical infrastructures of megacities.

This study presents numerical simulations of fecal coliforms dynamics in Luruaco Lake, located in Atlantico Department, Colombia. The velocity field is obtained through a two-dimensional horizontal...

Modified maifanite (MMF) was prepared by the synthesized method with sulfuric acid treatment and high-temperature calcination and evaluated as an effective adsorption material to remove the nutrient salt in waste watery. Compared with the raw maifanite (RMF), the MMF exhibited a higher adsorption capacity and higher removal efficiency. The results showed that the adsorption rates of total phosphorus (TP), total nitrogen (TN), ammonia nitrogen (NH3-N), nitrate-nitrogen (NOx-N), and chemical oxygen demand (COD) by MMF were 86.7%, 44.9%, 29.1%, 19.8%, and 11.9%, respectively, and compared to RMF, the average adsorption capacity of these nutrients by MMF increased by 20.5 mg/kg, 126.2 mg/kg, 61.9 mg/kg, 117.18 mg/kg, and 86.9 mg/kg, respectively. MMF maintained the basic structure and composition of maifanite, while having a rougher and looser surface, more irregular pores, wider gaps, and more active materials such as oxidizing Fe. This study suggests that MMF can be further applied to treat domestic sewage and eutrophic water.

Groundwater has a special significance in Akhmim area as it is used mainly in various purposes. However, groundwater is currently threatened by pollution from different sources. Therefore, detailed field investigations, in addition to Geographic Information Systems and remote sensing techniques are integrated to study the main sources of deterioration in groundwater quality and proposing practical solutions for mitigation and remediation. Based on the Modified Normalized Difference Water Index (MNDWI) and physicochemical analysis of groundwater samples, areas that contribute to groundwater deterioration have been identified. The results showed that the main causes of groundwater deterioration are the use of sewage rooms and injection wells to get rid of sewage especially in rural areas and scattered settlements, discharging liquid industrial wastes into the ground without proper treatment, the random exploitation of groundwater, and the use of wastewater in agriculture in a random manner. The results of the physicochemical analysis of groundwater samples confirmed the sources of deterioration identified by satellite images and field studies. To avoid groundwater degradation, strict restrictions need to be applied on the use of untreated or treated wastewater for irrigation, sewage networks have to be established in all residential areas, and factories must treat wastewater before discharging it.

In this chapter, different methods of disposal of radioactive waste adopted in nuclear medicine are elaborately discussed, namely, decay-in-storage, disposal into sewage, incineration, and transfer to authorized recipients. Sewer disposal and incineration are restricted by maximum permissible concentration limit allowed by the NRC in the sewer and the air. Transfer of radioactive waste to authorized recipients requires a manifest, which gives the details of shipment such as type and quantity of material, date, etc. Disposal of sealed sources and cadavers with radioactivity is mentioned.

Murray-Darling Freshwater Research CentreMDFRC item.A modular series of vertical flow wetland (VFW) systems was established in 1989/90 to treat up to 130,000 litres per day of primary settled sewage on the north coast of New South Wales, Australia as an experimental scale-up of wetland microcosms that had been developed with this hydrological format. Monitoring of inflow and outflow water quality was maintained on a weekly basis from January 1991 to February 1992. Some management parameters (e.g. flow rates) were varied during this period. Dye injection to examine hydraulic behaviour within the gravel bed was carried out on two occasions in one VFW. in general the removal of nutrients was lower than expected, with between 20% and 40% reduction in concentrations and removal of loads over the year. Suspended solids and BOD removals were excellent, with a surprisingly good reduction in faecal coliform counts as well. Reduction in flow rates improved performance markedly in all parameters.

The groundwater in Gaobeidian city is used for drinking, irrigation, industrial production, and other purposes. With the rapid development of the economy and urbanization, groundwater quality has been seriously affected. The main purposes of this paper are to evaluate the groundwater quality in the study area on the basis of understanding the hydrochemical characteristics of the study area and assess the possible health risks of groundwater to children and adults. In this paper, the entropy weight method was used to determine the weight of each evaluation parameter, and on this basis, groundwater quality evaluation was carried out, and the spatial distribution map of groundwater quality was drawn according to the evaluation results. The results show that the weight values of the five parameters of NO2–, Fe, As, Cr6+, and NO2–N are more than 0.1 among the total of fifteen parameters, and the concentration of these five parameters can be considered as the main influencing parameters of groundwater quality. The calculation results of the entropy weighted water quality index (EWQI) show that all the groundwater quality in the study area is class 1 water, which is Excellent Water. However, the EWQI value is the highest in the southwest of the study area, showing a trend of deterioration of groundwater water quality. Since all groundwater samples were evaluated as “excellent water,” it was speculated that the natural environment had more influence on groundwater chemical characteristics than human factors. The study found that 7.407% and 55.556% of the water samples posed a noncarcinogenic health risk to adults and children, respectively. The main responsible parameters for noncarcinogenic risk are F−, NO2−, NO3−, and Cr6+. The carcinogenic risk for adults ranged from 0 to 6.91E-04, with a mean of 1.00E-04. The carcinogenic risk for children ranged from 0 to 1.03E-03, with a mean of 1.55E-04. These toxic elements are mainly from industries. Therefore, the deterioration of groundwater quality can be prevented by strengthening the sewage management of various industries.

The expanding use of chitosan in sewage and sludge treatment processes raises concerns about its potential environmental impacts. However, investigations of the impacts of chitosan on sewage sludge anaerobic digestion where chitosan is present at substantial levels are sparse. This study therefore aims to fill this knowledge gap through both long-term and batch tests. The results showed that 4 g/kg total suspended solid (TSS) chitosan had no acute effects on methane production, but chitosan at 8-32 g/kg TSS inhibited methane production by 7.2-30.3%. Mass balance and metabolism of organic analyses indicated that chitosan restrained the transfer of organic substrates from solid phase to liquid phase, macromolecules to micromolecules, and finally to methane. Further exploration revealed that chitosan suppressed the secretion of extracellular polymeric substances of anaerobes by occupying the connection sites of indigenous carbohydrates and increased the mass transfer resistance between anaerobes and substrates, which thereby lowered the metabolic activities of anaerobes. Although chitosan could be partly degraded by anaerobes, it is much more persistent to be degraded compared with indigenous organics in sludge. Microbial community and key enzyme encoding gene analyses further revealed that the inhibition of chitosan to CO2-dependent methanogenesis was much severer than that to acetate-dependent methanogenesis.

The deterioration of water ecology caused by the discharge of oil spill wastewater, industrial sewage, and municipal sewage has attracted wide attention worldwide. Thus, it is significant to design a simple, environmentally friendly approach to separate oil–water mixtures. In this work, three different fabrics with pH-induced wettability transition were prepared by a dip-coating process for oil and water separation. The dip-coating fabrics had the advantages of oil–water separation, photocatalytic degradation, and recycling. Polyethylene terephthalate/polyamide nonwoven fabric was used as the substrate materials of the fabric. The carboxylic acid-modified TiO2 endowed the fabric with hydrophilicity–hydrophobicity and photocatalytic properties. The Fe3O4 nanoparticles obtained by the coprecipitation method provided magnetism for the fabric, facilitating the recycling of the fabric and improving the hydrophobicity of the fabric. The fabrics coated with dipping solutions were superhydrophobic in a neutral environment and hydrophilic in an alkaline environment. Among the three coated fabrics, the fabric coated with stearic acid/TiO2-Fe3O4 (FST) had the most satisfying oil–water separation performance and durability. Under the neutral condition, the contact angle of the FST was 151° and the separation efficiency was 98%. Under the alkaline condition, the underwater oil contact angle of the FST was 150° and the separation efficiency was 95%. After 15 cycles, the oil–water separation rate of the FST was still higher than 90%. Due to the presence of TiO2, the coated fabric had an exceptional performance in the photodegradation of organic pollutants (69.9%). In addition, the fabrics can be quickly recovered due to magnetism.

Land application of organic wastes such as sewage effluent, biosolids, and animal wastes can introduce pharmaceuticals and personal care products (PPCPs) into soils. Food plants grown in soils receiving organic wastes may take up PPCP contaminants and accumulate them in the edible tissues. The purpose of this review is to summarize the latest findings on root uptake of PPCPs and their transfer in soil–plant systems, aiming to identify potential risks associated with organic waste application in crop production systems. The processes and mechanisms of root uptake of PPCPs and their subsequent transfer in plants are intensively discussed in the present review. Soil properties, PPCP physicochemical properties, and plant species are demonstrated as the most important factors influencing the uptake and transfer of PPCPs in soil–plant systems. The metabolism processes and mechanisms of PPCPs in plant tissues are further elucidated with exemplification of commonly used PPCPs. The estimated daily intake is employed to assess the potential risks of consuming PPCP-containing foods based on their accumulation in edible plant tissues. Two innovative treatment techniques are proposed as cost-effective practices to reduce PPCP transfer into plants from organic wastes. Accumulation of PPCPs in edible plant tissues is governed by the combined processes of their root uptake, translocation, and metabolism in plants. This paper reviews the latest research advances in understanding the transfer of PPCPs in soil–plant systems, proposes mitigation practices to minimize PPCP entry into food chains, and identifies research challenges.

Many advanced technologies have shown encouraging results in removing antibiotics from domestic wastewater. However, as activated sludge treatment is the most common sewage treatment system employed worldwide, improving its effect on antibiotic removal would be more desirable. Understanding the removal mechanisms, kinetics and factors that affect antibiotic removal in the activated sludge process is important as it would allow us to improve the treatment performance. Although these have been discussed in various literature covering different types of antibiotics and wastewater, a specific review on antibiotics and domestic wastewater is clearly missing. This review paper collates, discusses and analyses the removal of antibiotics from sewage in the activated sludge process along with the removal mechanisms and kinetics. The antibiotics are categorised into six classes: β-lactam, dihydrofolate reductase inhibitor, fluoroquinolone, macrolide, sulfonamides and tetracycline. Furthermore, the factors affecting the system performance with regard to antibiotic removal are examined.

The analysis of drugs in wastewater for forensic purposes has been constantly increasing and the investigation of the potential interaction between drugs or metabolites and sewage microbiota is important. The results demonstrated that cocaine esterase genes were widely distributed in 1142 global wastewater samples collected from 64 countries and linked to several bacterial species. In addition, in silico predictions indicated that carfentanil, 4F-MDMB-BINACA, 5F-MDMB-PICA, MDMB-4en-PINACA and mitragynine might also undergo microbial hydrolysis, in a similar fashion of cocaine degradation by cocaine esterase. In conclusion, it was demonstrated the microbial potential to hydrolyze drugs of abuse in wastewater environments, contributing to the critical evaluation of potential metabolites as biomarkers for microbial and human transformation of drugs in wastewater.

Recent research in many parts of the world has pointed towards evidence of SARS-CoV-2 RNA in both treated and raw municipal wastewater discharged by communities. Therefore, concerns regarding it being a possible enteric virus are abundant. Past history of SARS-CoV-1 outbreaks and viral survival information helps in establishing information regarding possible viral infectivity and survival of SARS-CoV-2. The paper examines the existing strategies and techniques including the efficacy of laboratory-based RT-qPCR technique for tracking environmental persistence and community transmission of COVID-19. Analysis of studies targeting untreated and treated wastewater as source of samples is carried out. The analysis shows that untreated samples were mostly positive for SARS-CoV-2 RNA in the target studies. Infectivity estimation from viral load data was found to be about two orders of magnitude higher than actual case data in one of the studies. Additionally, relevant research on environmental survivability of SARS-CoV-2 and possible gaps are examined. Biosensors and excretion metabolite tracking in viral detection are also examined, which hold tremendous importance for future research. Wastewater-based epidemiology (WBE) shows incredible promise in the near future for tracking environmental persistence and community transmission of highly infectious diseases such as SARS-CoV-2. With limited research available on SARS-CoV-2 with regard to WBE, it is imperative that focus be established on the evidence-based targeted studies.

The physicochemical and microbial qualities of septic tank effluent samples from households within the study area were evaluated. Three replicate samples from Locations A, B, and C representing Agbor, Benin City, and Sapele regions of Delta and Edo States, Nigeria were collected from both the inlet tank (raw sewage) and the outlet chamber (semi-treated sewage) for physicochemical and microbiological analyses using standard methods. Results of the physicochemical analyses showed that pH values ranged from 6.5 – 7.7 across locations and in both the raw and semi-treated samples. Electrical conductivity (EC), Total suspended solid (TSS) and BOD was significantly higher (p>0.05) in the raw sewage (RS) than in the semi-treated (SS), while DO was higher (p>0.05) in the SS in all three locations sampled. Microbial analysis shows that total heterotrophic bacteria (THB) was highest in the RS in two locations. Microbial isolates from wastewater samples included Staphylococcus aureus, Proteus mirabilis, Escherichia coli, Pseudomonas aeruginosa, and Aspergillus niger. DO was low at an average of 3.20 and 3.73 mg/L in both chambers of the septic tank. Average BOD5 of 59.4 and 42.8 mg/L and COD average of 206.8 and 153.2 mg/L were reported for the RS and SS chambers. 0.3 was the value of the ratio of BOD5/COD for the RS and SS in the study. This infers that biodegradation was slow and inefficient in the septic tank system, and that modification of the design is recommended to increase retention time in the RS chamber

Pharmaceutical chemicals represent one of the major contaminants in the aquatic environment. Several studies have revealed their negative effects on non-target organisms. Pharmaceutical chemicals are constantly released into the environments and their chronic exposure at lower concentrations may impose a threat to the aquatic environment and human health. Pharmaceuticals have been reported in surface water as well as in groundwater which is the ultimate source of drinking water. Mostly antibiotics, anti-depressant, β-blocker, synthetic hormones, non-steroidal anti-inflammatory drugs, and analgesics have been detected in aquatic environments. Major sources of pharmaceuticals in the aquatic environment are sewage and WWTPs effluents, hospital discharge, and the effluents of pharmaceutical industries. Pharmaceuticals and their metabolites have been detected in fishes collected from different aquatic environments. Pharmaceutical chemicals disrupt the thyroid, reproductive, and neuroendocrine systems of fishes. The present study reviews the concentrations of pharmaceuticals in the aquatic environment and bioaccumulation in the fish body, and their toxicological impacts on the endocrine system to identify the knowledge gaps. This study suggests more extensive case studies for controlling pharmaceutical release into the environment and evaluating the ecological risks of emerging EDCs.

Background Antimicrobial resistance (AMR) has become an emerging threat worldwide, and developing countries such as Bangladesh are considered to be at greater risk of disseminating the resistant bacteria between human–animal interfaces. Objectives The present study was carried out to determine the prevalence and AMR profile of Escherichia coli isolated from broiler chickens, the environment, and farmworkers. This study also aimed to identify the risk factors associated with multidrug‐resistant (MDR) E. coli infection in broiler chickens. In addition, the presence of carbapenem resistance gene (NDM‐1) was assessed. Methods A total of 114 E. coli isolates, recovered from 150 samples (cloacal swabs = 50, farm sewage = 50, and hand washed water of farmworkers = 50) collected from 50 broiler farms, were identified by biochemical examination and polymerase chain reaction (PCR) assay. Antimicrobial susceptibility test was performed for 10 antibiotics by disk diffusion test. Carbapenem resistance gene (NDM‐1) was detected by PCR. Risk factors were identified through multivariable logistic regression. Results The highest prevalence of E. coli was recorded in broiler chickens (86%) and the lowest in farmworkers (66%). For MDR E. coli infection, ‘winter season’, ‘absence of specific shoes for staff’, and ‘use of antibiotics without veterinarian's prescription’ were the significant risk factors. High resistance of the E. coli isolates was observed against levofloxacin (81.6%), doxycycline (78.1%), cefotaxime (78.1%), and ciprofloxacin (70.2%). About 76% of the isolates demonstrated MDR. None of the isolates were positive for the NDM‐1 gene. Conclusions The high level and similar pattern of antibiotic resistance in E. coli isolates from broiler chickens, farmworkers, and sewage in poultry farms indicates a good possibility of spreading the antibiotic‐resistant E. coli in such settings., Winter season, absence of specific shoes for staff, and use of antibiotics without veterinarian's prescription were the significant risk factors of MDR‐E. coli infection in broiler chickens. A very high resistance of the E. coli isolates against levofloxacin (81.6%), doxycycline (78.1%), cefotaxime (78.1%), and ciprofloxacin (70.2%) was observed. Similar pattern of resistance phenotype of E. coli was observed among broiler chickens, farm workers, and farm sewage, and about 76% of the isolates demonstrated multidrug resistance.

Bioremediation employs the use of naturally occurring organisms to break down hazardous substances into less toxic or non-toxic substances. The conventional treatment method of domestic sewage water is expensive and generates waste sludge that requires further handling and the problem of disposal of sludge into the environment is risky as it has a high potential to pollute the environment. The development of a simple and cost effective process allows the implementation of bioremediation in a safer and effortless manner. Therefore in this investigation microbiological and chemical analyses were very useful to suggest the best ways to improve bioremediation limits in domestic sewage water. In the study indigenous anoxygenic phototrophic bacteria were isolated from domestic sewage water to treat domestic sewage waste water, to develop a costeffective process for bioremediation. Domestic sewage water was analyzed for different physico-chemical parameters such as pH, Temperature, TDS, TSS, TS, DO, BOD, COD, total sulphate and chlorides using bio inoculants of anoxygenic phototrophic bacteria isolated and domestic sewage water in an suitable light, pH and temperature conditions. The results showed that among the 3 anoxygenic phototrophic bacteria isolated; isolate RP2 (Rhodopseudomonas palustris) could grow well at pH 8, temperature 30°C and also reduce more pollutant parameters in domestic sewage water during bioremediation in the period of four consecutive weeks at the rate of 80%.

Rainwater harvesting and treatment systems (RHTS) are used in many places around the world as a part of sustainable water management. They decrease the risk of overloading the sewage network and environmental pollution. The efficiency and reasonableness of using such solutions in specific erosive conditions are not sufficiently understood. The aim of the study was to evaluate the operation of RHTS, receiving effluents from the wholesale market and fuel station (twenty years of observations). The studied system is located in an area endangered by water erosion. In the study period, due to the accumulation of erosive phenomena, it was necessary to optimise the system (including the installation of new devices and increasing the capacity of reservoirs). The analyses referred to the stability and work safety of the most important equipment and water treatment efficiency. The quality of water in the reservoirs was measured before and after the modernisation of the system. Selected physical, oxygen, biogenic and salinity indicators were determined in the water. During the study, RHTS had a positive effect on the quality of rainwater runoff – the values of many contaminants were reduced (RHTS 1: suspended solids, nitrogen, iron, potassium; RHTS 2: conductivity, suspended solids, nitrogen). Design and operational errors were noticed that in the long run may contribute to deteriorating the operational efficiency and even lead to a building collapse (intense erosive phenomena). This study clearly demonstrates that building a rainwater management system is a highly site-specific issue.

Wastewater-based epidemiology (WBE) seeks to use biological or chemical indicators in sewage to provide information on the overall health of a community. This paper provides an overview of the range of applications of WBE over the past two decades, how it has been used to inform public health responses, and considerations for more integrated approaches to WBE based on a review of the literature. The review finds that WBE has been used extensively around the world for the estimation of consumption patterns of illicit drugs and other substances, but a range of novel applications also exist. As a result of the COVID-19 pandemic, many communities used WBE for the first time as a complementary public health surveillance tool, monitoring trends in SARS-CoV-2 prevalence in large cities, and for micro-surveillance on a more targeted level. WBE may continue to be a useful public health surveillance tool in the future; however, several limitations and challenges exist. Consideration of how information obtained through WBE can be used to inform public health responses is essential to understanding the potential costs and benefits compared with conventional public health surveillance techniques.

The study aims to analyze the vulnerability of floods and their impact in the Giulești-Sârbi area, the marginal northwestern neighborhood of Bucharest. The location of the accumulation lake has hydrological importance for the studied area. The anthropogenic dam is one of the susceptible sources of floods, but the most inefficiency of the sewage system is the actual principal cause, which frequently flows back when there are significant increases in rainfall. The motivation for choosing the study is represented by the vulnerability of the Giulești-Sârbi area and by the lack of a study on flood vulnerability and frequency in the area. A questionnaire was also applied locally, some of the results being presented in this paper. The main objectives of the study refer to the spatialization at the street level of the vulnerability of floods and their following impact. It also compares the vulnerability of floods after two key periods: before and after the construction of the dam, respectively 1980 and 2020 – for the comparison and evolution of terrain changes. The problem was also analyzed by the vulnerability related to the slope, land use and geological characteristics. The results show that the Giulești-Sârbi neighborhood is still susceptible to floods. The most affected streets are those from the southeastern part of the neighborhood and punctually to the NW. On the other hand, the application of the questionnaire shows that the southernmost street (Răsadniței Street) did not register problems as often as the current hazard maps from the rowater.ro source for which the highest vulnerability was expected to show. The areas indicating problems according to the questionnaires and Romanian Waters National Administration maps largely coincide with the results of the vulnerability maps resulting in this paper. The main solution that can reduce the effect of flood vulnerability is the modernization of the sewage system.

Aim: The current study undertaken in Tunisia examines the use of wastewaters to monitor SARS-CoV-2 circulation. Materials & methods: Viral genetic materials collected in wastewaters during two different periods (September–October 2020 and February–April 2021) were concentrated using the adsorption-elution method. SARS-CoV-2 genes were researched by real-time PCR. Results: During the first period of the study, viral RNA was detected in 61.11% of the analyzed samples collected from Monastir city with a rate of 88.88% for raw wastewaters and 33.33% for treated wastewaters. Then, during the second period of the study, the quantitative analysis of wastewaters collected from seven governorates showed the presence of viral RNA among around 25% of them with variable RNA loads. The increased amounts of viral RNA detected in wastewaters were accompanied by an increase in the number of COVID-19 patients in Tunisia. Conclusion: Our results emphasize the importance of sewage survey in SARS-CoV-2 tracking., Graphical abstract

The treatment of domestic and industrial wastewater is a source for a large number of airborne microorganisms, which can be released at the environment during mechanical aeration. A meta-analysis of up to 14 industrial and municipal treatment plants was performed to determine the bacterial count in bioaerosols, as well as antibiotic resistance, at different stages of the wastewater treatment (pretreatment, primary, secondary and tertiary treatment), in comparison with bacterial counts of the ambient air surrounding the treatment plants. The highest contamination of the air with microorganisms was observed in the raw sewage inlet and at the biological reactor. In most analyzes, the air in the wastewater treatment plant was characterized by a higher content of microorganisms than at the control point. Bioaerosols from water treatment might be an important source of antibiotic resistance genes, which can be transported considerable distances and can represent a potential risk to humans. Therefore, employees should recognize the health risks associated with the absence of personal protective equipment, such as masks or respirators. © 2021. Journal of Ecological Engineering. All Rights Reserved.

The outbreak of coronavirus infectious disease-2019 (COVID-19), caused by the Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2), has rapidly spread throughout the world. Several studies have shown that detecting SARS-CoV-2 in untreated wastewater can be a useful tool to identify new outbreaks, establish outbreak trends, and assess the prevalence of infections. On 06 May 2021, over a year into the pandemic, we conducted a scoping review aiming to summarize research data on SARS-CoV-2 in sewage. Papers dealing with raw sewage collected at wastewater treatment plants, sewer networks, septic tanks, and sludge treatment facilities were included in this review. We also reviewed studies on sewage collected in community settings such as private or municipal hospitals, healthcare facilities, nursing homes, dormitories, campuses, airports, aircraft, and cruise ships. The literature search was conducted using the electronic databases PubMed, EMBASE, and Web Science Core Collection. This comprehensive research yielded 1090 results, 66 of which met the inclusion criteria and are discussed in this review. Studies from 26 countries worldwide have investigated the occurrence of SARS-CoV-2 in sewage of different origin. The percentage of positive samples in sewage ranged from 11.6 to 100%, with viral concentrations ranging from ˂LOD to 4.6 × 108 genome copies/L. This review outlines the evidence currently available on wastewater surveillance: (i) as an early warning system capable of predicting COVID-19 outbreaks days or weeks before clinical cases; (ii) as a tool capable of establishing trends in current outbreaks; (iii) estimating the prevalence of infections; and (iv) studying SARS-CoV-2 genetic diversity. In conclusion, as a cost-effective, rapid, and reliable source of information on the spread of SARS-CoV-2 and its variants in the population, wastewater surveillance can enhance genomic and epidemiological surveillance with independent and complementary data to inform public health decision-making during the ongoing pandemic. Graphic Abstract Supplementary Information The online version contains supplementary material available at 10.1007/s12560-021-09498-6.

The problem of sewage disposal has received great attention worldwide. The raw sewage contains a variety of high inorganic and organic matters that affect natural water environment. To mitigate such problem, sewage may be recycled through aquaculture practice. Sewage recycling in aquaculture enhances water productivity through nutrients input. Proper loading of sewage ensures viable aquaculture; otherwise, fish mortality occurs due to poor water quality. To optimize sewage application, two different experiments were conducted, each with four treatments. In both experiments, three fish species namely rohu (Labeo rohita Hamilton, 1822), mrigal (Cirrhinus mrigala Hamilton, 1822), and bata (Labeo bata Hamilton, 1822) were tested in triplicate in FRP (Fibre-Reinforced Plastic) tanks. Different sewage concentrations (0, 25%, 50% and 75%) used in first experiment were prepared by mixing freshwater, showing Biochemical Oxygen Demand (BOD) 2.0 ± 0.4 mg/L, 10.8 ± 1.4 mg/L, 19.6 ± 1.5 mg/L and 41.6 ± 2.58 mg/L, respectively. After 30 days rearing, results showed ≥75% fish survival in sewage concentrations up to 50% with BOD level 19.6 ± 1.5 mg/L. Less than 50% fish survived in 75% sewage concentration, with BOD level as 41.6 ± 2.58 mg/L. The second experiment was conducted for 90 days considering 50% sewage concentration as basal dose with BOD level as 19.6 mg/L as an acceptable limit for fish survival. Split doses of sewage were applied in T1, T2 and T3 treatments fortnightly, weekly and semi-weekly intervals, while single dose was used in C (control) treatment. Application of split doses resulted better hydro-biological changes, including nutrients recovery, in T1, T2 and T3 than that of single dose in control. Fish growth plotted with net primary productivity (NPP), phytoplankton and zooplankton densities exhibited positive correlations in T2 (12 doses) and T3 (24 doses), considered as optimal doses to ensure better water productivity for desirable fish production than sewage with single dose or limited doses (6 doses).

The minimum design velocity for sewage pipes is set based on the planned quantity; however, deriving a reasonable design with only a single standard is limited. Thus, it is necessary to review whether consistent standards, such as the current minimum flow velocity, can efficiently transport the particles flowing in pipes. Improving the design that can determine the minimum design velocity rate and slope according to the concentration, specific gravity, particle size, and characteristics of the pipe material of the sediment flowing into the sewer system is necessary. In this study, the minimum design velocity for each particle size was examined based on the results of the simulation of fluid-solid multiphase flow required for the review process of hydraulic properties inside the pipe. The minimum design velocity standards for domestic and international sewage systems were investigated and compared, and a minimum design flow rate prediction equation was proposed considering the sedimentation. The equation includes the relationship between the particle size and pipe diameter and can be easily estimated.

Phosphorus (P) resource availability and quality is declining and recycling P-fertilizers from waste materials are becoming increasingly important. One important secondary P resource is sewage sludge (SSL) where P is often bound as aluminum phosphate (Al-P), iron phosphate (Fe-P) and polyphosphate (poly-P), respectively. Thermal treatment in different ways is a promising way in P recycling to produce highly plant-available P-fertilizers. To investigate mechanisms behind transformation of hardly available P-species toward plant-available P forms we treated a model SSL containing different kinds of defined P sources by low-temperature conversion (LTC) at 500 ��C and subsequent thermochemical treatment of the LTC product with Na additives (TCT) at 950 ��C, respectively. Pot experiments with ryegrass were carried out to determine the plant availability of P of the different treatments. The poly-P (here pyrophosphates) based fertilizers had a very high plant availability after both thermal treatments. During LTC treatment the plant availability of the Fe-P and Al-P variants increased because of the formation of Fe(II)-phosphates and/or pyro-/polyphosphates. Especially the formation of Al-polyphosphate shows a high plant availability. The subsequent TCT further increased strongly the plant availability of the Fe-P variants because of the formation of highly plant-available CaNaPO4. Thus, a direct TCT without prior LTC probably also produce CaNaPO4 and is recommended for Fe-P based SSL. However, a molar Ca/P ratio of ���1 in the fertilizer is favorable for CaNaPO4 formation. Thus, the knowledge on the source of primary P in SSL is essential for choosing the accurate thermal treatment method to produce highly plant-available P-fertilizers from SSL.

The aim of this a pioneering research is to investigate linear alkylbenzenes (LABs) as biomarkers of sewage pollution in sediments collected from four rivers and estuaries of the south and east of Peninsular Malaysia. The sediment samples went through soxhlet extraction, two-step column chromatography purification, fractionation and gas chromatography-mass spectrometry (GC-MS) analysis. Principal component analysis (PCA) with multivariate linear regression (MLR) was used as well for source apportionment of LABs. The results of this study showed that total LAB concentration was 36-1196 ng g-1dw. The internal to external isomer ratios (I/E ratio) of LABs were from 0.56 to 3.12 indicated release of raw sewage and primary and secondary effluents into the environment of south and east of Peninsular Malaysia. Our research supported that continuous monitoring of sewage pollution to limit the environmental pollution in riverine and estuarine ecosystem.

Publisher Copyright: © 2021 The Authors. Published by American Chemical Society The global prevalence of antibiotic resistance genes (ARGs) is of increasing concern as a serious threat to ecological security and human health. Irrigation with sewage and farmland application of manure or biosolids in agricultural practices introduce substantial selective agents such as antibiotics and toxic metals, aggravating the transfer of ARGs from the soil environment to humans via the food chain. To address this issue, a hyperaccumulator (Sedum plumbizincicola) combined with biochar amendment was first used to investigate the mitigation of the prevalence of ARGs in cadmium and oxytetracycline co-contaminated soil by conducting a pot experiment. The addition of biochar affected the distribution of ARGs in soil and plants differently by enhancing their prevalence in the soil but restraining transmission from the soil to S. plumbizincicola. The planting of S. plumbizincicola resulted in an increase in ARGs in the soil environment. A structural equation model illustrated that mobile genetic elements played a dominant role in shaping the profile of ARGs. Taken together, these findings provide a practical understanding for mitigating the prevalence of ARGs in this soil system with complex contamination and can have profound significance for agricultural management in regard to ARG dissemination control.

The Three Gorges Reservoir (TGR) plays a crucial role in providing electricity for mega-cities across China. However, since the impoundment was completed in 2006, attention to environmental concerns has also been intensive. In order to determine the distribution, sources, and pollution status of trace elements in the water fluctuation zone of the TGR following ten years of repeated “submergence” and “exposure”, we systematically collected 16 paired surface sediment samples (n = 32) covering the entire main body of the TGR in March 2018 (following 6 months of submergence) and September 2018 (after 6 months of exposure), and quantitatively analyzed 13 elements (e.g., Mn, Fe, V, Cr, Ni, Cu, Zn, As, Sr, Y, Zr, Ba, and Pb) using X-ray fluorescence spectrophotometry (XRF). The results showed that, except for Sr, concentrations of trace metals following submergence were generally higher than those after exposure due to the less settling of suspended solids at the faster flow velocity during the drawdown period. Assessment using enrichment factors (EFs) and a geo-accumulation index (Igeo) both characterized a relatively serious anthropogenic pollution status of metals in the upper reaches of the TGR with respect to the middle-lower reaches. Source apportionment by positive matrix factorization (PMF) analysis indicated that agricultural activities (24.8 and 24.3%, respectively) and industrial emissions (24.5 and 22.9%, respectively) were the two major sources in these two periods, followed by natural sources, domestic sewage, and ore mining. Ecological risk assessment showed that metalloid arsenic (As) could be the main potential issue of risk to aquatic organisms and human health. A new source-specific risk assessment method (pRI) combined with PMF revealed that agricultural activities could be the major source of potential ecological risk and should be prioritized as the focus of metal/metalloid risk management in the TGR.

Existing processes of cleaning emulsion sewage are based on either physicochemical technology with application of complex of reagents – nonorganic electrolytes and organic flocculants, resulting in obtaining highly-mineralized purified water, which cannot be used for technical water supply, or based on complicated technologies of electrocoagulation and ultrafiltration. This required elaboration of a new technology and equipment for cleaning concentrated emulsion sewage, in particular, those containing emulsol of Wedolit EP-5 grade, used for hydro-mechanical expanders of electric-weld pipe lines. The technology stipulates a successive introduction of a reagent – suspension of alumo-silicate based hard-phased sorbent and solution of flocculant of cation type Praestol-650ВС – into emulsion sewage, their mixing with emulsion water in a definite mode, sedimental differentiation of the formed phases in a precipitator-flocculator “ЭП ОФ”, gravitation concentration and dewatering of the obtained sediment at vacuumfilter. The dewatered sediment can be utilized in cement industry and metallurgy. It was shown that application of the hard-phase sorbent does not result in an increase of mineralization of purified water and enables to use it for technical purposes. The group of companies “ECO-PROJECT”, Ekaterinburg, accomplished a project for Chelyabinsk pipe-rolling plant, elaboration and manufacturing of equipment, as well as commissioning and start-up of the equipment. The elaborated technical solutions in the process of equipment running showed a high efficiency and can be used as a base for creation of facilities of any productivity for cleaning multi-type emulsion sewage at enterprises of various industries.

Zwitterionic, cationic, and anionic per- and polyfluoroalkyl substances (PFAS) are increasingly reported in terrestrial and aquatic environments, but their inputs to agricultural lands are not fully understood. Here, we characterized PFAS in 47 organic waste products (OWP) applied in agricultural fields of France, including historical and recent materials. Overall, 160 PFAS from 42 classes were detected from target screening and homologue-based nontarget screening. Target PFAS were low in agriculture-derived wastes such as pig slurry, poultry manure, or dairy cattle manure (median ∑46PFAS: 0.66 μg/kg dry matter). Higher PFAS levels were reported in urban and industrial wastes, paper mill sludge, sewage sludge, or residual household waste composts (median ∑46PFAS: 220 μg/kg). Historical municipal biosolids and composts (1976–1998) were dominated by perfluorooctanesulfonate (PFOS), N-ethyl perfluorooctanesulfonamido acetic acid (EtFOSAA), and cationic and zwitterionic electrochemical fluorination precursors to PFOS. Contemporaneous urban OWP (2009–2017) were rather dominated by zwitterionic fluorotelomers, which represented on average 55% of ∑160PFAS (max: 97%). The fluorotelomer sulfonamidopropyl betaines (X:2 FTSA-PrB, median: 110 μg/kg, max: 1300 μg/kg) were the emerging class with the highest occurrence and prevalence in contemporary urban OWP. They were also detected as early as 1985. The study informs for the first time that urban sludges and composts can be a significant repository of zwitterionic and cationic PFAS.

Numerous fresh and saline-water tropical aquaculture ponds that often can be significant sources super-saturation of CO2 towards the atmosphere are gradually increasing throughout the world. The role of salinity in regulating the chlorophyll-a and dissolved pCO2 in a freshwater aquaculture pond, situated in East Kolkata Wetlands, Eastern India, was tested using a microcosm conducted during summer (April-May) and winter (December���January) months. The effects of enhanced salinity to microcosm sets of 5, 10 and 15 ppt were monitored for nine consecutive days. pH, dissolved oxygen (DO), pCO2(water), chlorophyll-a, and gross primary productivity (GPP) were measured in-situ and every day during the entire microcosm. Enhanced salinity was hypothesised to alter the pCO2(water) and chl-a dynamics of this system significantly. Increasing salinity to 5 ppt would enhance the photosynthetic potential of the existing primary producers and reduce the pCO2(water) significantly, thus boosting the CO2 sink strength. This enhanced CO2 sink strength, accompanied with increased GPP and DO, was also observed in 10 ppt, only during summer; however, low temperature was found to abate the photosynthetic response during winter. Finally, in 15 ppt treatments, drastic chlorophyll-a reduction and extreme CO2 super-saturation showed the existing phytoplankton community cannot cope with such high salinity.

The management and disposal of excess sludge are emerging issues owing to the high costs associated with treatment. In this study, the viability of a modified bentonite was investigated as a conditioning agent for the stabilisation of heavy metals (i.e., Cu, Zn, Cr, Pb, and Cd) and the retention of nutrient species (i.e., total nitrogen (TN), total phosphorus (TP), available nitrogen (available N), and Olsen-phosphorus (Olsen-P)) in sewage sludge for agricultural use. Five grams of modified bentonite resulted in the highest stabilisation rate of heavy metals and strongly contributed to the stabilisation of heavy metals. However, increased amounts of modified bentonite might increase the TN, available N, and TP losses in the conditioned sewage sludge. Through the analytic hierarchy process modelling, optimal concentrations of nutrient species and heavy metals remaining in the conditioned sewage sludge were achieved when the ratio of bentonite to sewage sludge was 1:12.5 (4 g bentonite : 50 g sludge). Moreover, the optimal mixing ratio of the conditioned sewage sludge to the soil (1:2) was suggested for agricultural use. Based on these observations, modified bentonite allowed the sewage sludge to be used as a fertiliser in agriculture by stabilising heavy metals and retaining nutrient species. HIGHLIGHTS The modified bentonite stabilised the heavy metals and retained the nutrient elements in the sewage sludge.; The AHP modelling revealed the optimal ratio of bentonite to sewage sludge (4 g bentonite : 50 g sludge).; The optimal mixing ratio of the conditioned sewage sludge to the soil (1:2) was suggested for agricultural use.; The modified bentonite allowed sewage sludge to be used as a fertiliser in agriculture.