1. Tandem Functionalization‐Carboxylation Reactions of π‐Systems with CO2.
- Author
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Bertuzzi, Giulio Please confirm that given names and surnames/family names have been identified correctly. -->, Cerveri, Alessandro, Lombardi, Lorenzo, and Bandini, Marco
- Subjects
CARBOXYLATION ,CARBON-carbon bonds ,VISIBLE spectra ,CARBON dioxide ,CATALYSIS ,CATALYSTS - Abstract
The tandem catalytic functionalization/carboxylation of double as well as triple carbon‐carbon bonds with CO2 represent an emerging research area in synthetic organic methodology. In particular, the combination of mild reaction conditions, stoichiometric acceptor/donorless conditions (visible light photoredox catalysis) and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/ complexity from readily available unsaturated hydrocarbons and CO2 as a C1‐buinding block. The most recent developments in the field have been collected in the present review article and organized, based on the different sets of π‐systems/intermediates/reactive partners employed (i.e., nickelalactones, organo‐halides) as well as synthetic strategies (i.e., visible‐light photo redox catalysis). [ABSTRACT FROM AUTHOR]
- Published
- 2021
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