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1. Control of the orbital delocalization and implications for molecular rectification in the radical anions of porphyrins with coplanar 90 degree and 180 degree [beta],[beta]'-fused extensions

2. Quinoxalino[2,3-b']porphyrin behave as [pi]-expanded porphyrins upon one-electron reduction: Broad control of the degree of delocalization through substitution at the macrocycle periphery

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