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Start Over Descriptor "Glucose-6-phosphatase -- Structure" Topic chemistry
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1. Mechanistic studies of the biosynthesis of 2-thiosugar: evidence for the formation of an enzyme-bound 2-ketohexose intermediate in BexX-catalyzed reaction

Author

Sasaki, Eita and Hung-wen Liu

Subjects
Glucose-6-phosphatase -- Structure, Glucose-6-phosphatase -- Chemical properties, Organosulfur compounds -- Structure, Organosulfur compounds -- Chemical properties, Vitamin B1 -- Chemical properties, Chemistry
Abstract

The first mechanistic insight into 2-thiosugar production in an angucycline-type antibiotic, BE-7585A, is reported. The results indicated that the sulfur insertion mechanism in 2-thiosugar biosynthesis shares similarities with that for thiamin biosynthesis.

Published
2010

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