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In this letter, we present the superconducting property characterization of a phase pure, reasonably good quality YBaCuO sample. Studied compound is crystallized in orthorhombic Pmmm space group with lattice parameters a, b, and c being 3.829(2), 3.887(1) and 11.666(3) Å, respectively. Bulk superconductivity is observed below 90 K as evidenced by resistivity and dc/ ac magnetization measurements. The resistivity under magnetic field ( ρTH) measurements showed clearly both the intra-grain and inter-grain transitions, which are supplemented by detailed (of varying frequency and amplitude) ac susceptibility studies as well. The upper critical field at 0 K, i.e. H(0) being determined from ρTH measurements with 50 % criteria of resistivity drop, is ∼70 T. Studied polycrystalline YBaCuO is subjected to detailed heat capacity ( C) studies. C exhibited well-defined anomaly at below 90 K, which decreases with applied field. Although the C anomaly/peak at T reduces with applied field, the same is not completely suppressed in high applied fields of up to 12 T. The Sommerfeld constant ( γ) and Debye temperature ( Θ), as determined from low temperature fitting of C( T) data to Sommerfeld-Debye model, are 10.65 mJ/mole-K and 312.3 K, respectively. The results are compared with existing literature on bulk polycrystalline superconducting YBaCuO sample. [ABSTRACT FROM AUTHOR]

• Pyrolyzed pencil graphite coated cellulose paper used as an interlayer. • Studied effect of different grades of pencil over cellulose paper on Li-S cell. • Pencil is a source of graphite and silica in the interlayer and act as a reservoir to lithium polysulfides. • The DFT calculations performed to calculate interaction between polysulfides and graphite/silica structures. • Capacity values of 1352 and 995 mAh g−1 are attained at 0.1 and 0.5 A g−1. • Cycling stability of 900 mAh g−1 at 1 A g−1 (3.0C) for 350cycles. Lithium-sulfur (Li-S) battery is next generation battery technology but it's commercialization is obstructed primarily due to the shuttling effect of lithium polysulfides (LiPSs). Herein, we report an effective approach using pencil coated pyrolyzed cellulose filter paper as an interlayer to suppress the LiPSs dissolution into the electrolyte and thus allowing effective utilization of active sulfur cathode. Here, the binder clay particles (mainly SiO 2) of pencil graphite facilitate the adsorption of LiPSs, whereas graphite increases the electrical conductivity and acts as a physical barrier to LiPSs. To investigate further, we utilize three different grades of pencil (4B, HB, 5H) which vary in terms of clay (SiO 2) composition. It is observed that the HB pencil coated interlayer has the right balance of silica and graphite, which results in an impressive initial capacity of 1352 and 995 mAh g−1 at the current density of 0.1 and 0.5 A g−1, respectively. The cell exhibit high cycling stability of 900 mAh g−1 at 1 A g−1 (3.0 C) for 350 cycles with a slow capacity decay of 0.07% per cycle. The phenomenon of LiPSs adsorption is further understood using post-cycling analysis, H-cell adsorption testing, and shuttle factor calculation for the development of commercial Li-S batteries. [ABSTRACT FROM AUTHOR]