1. Hysteresis-less mesoscopic CH3NH3PbI3 perovskite hybrid solar cells by introduction of Li-treated TiO2 electrode
- Author
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Jin Hyuck Heo, Sang-Ju Lee, Dae-Hwan Kim, Shi-Joon Sung, Wenping Yin, Sang Hyuk Im, Min Hyuk Chang, Tae Kyu Ahn, and Myoung Sang You
- Subjects
Mesoscopic physics ,Materials science ,Renewable Energy, Sustainability and the Environment ,Energy conversion efficiency ,Analytical chemistry ,Nanotechnology ,Hybrid solar cell ,Conductivity ,Hysteresis ,Electrode ,General Materials Science ,Charge carrier ,Electrical and Electronic Engineering ,Perovskite (structure) - Abstract
A great current density–voltage ( J – V ) hysteresis with respect to the scan direction is important issue in perovskite hybrid solar cells because the power conversion efficiency is sometimes incorrect. Here, we demonstrated >17% mesoscopic CH 3 NH 3 PbI 3 (MAPbI 3 ) perovskite hybride solar cells without significant J – V hysteresis with respective to the scan direction and rated by using Li-treated mesoscopic TiO 2 electrode. The Li-treated mesoscopic TiO 2 electrode improved charge separation/injection from MAPbI 3 into mesoscopic TiO 2 , charge transport in mesoscopic TiO 2 , and surface traps because the conduction band edge of mesoscopic TiO 2 was lowered by ~0.1 eV, the mobility of charge carriers was increased from ~1.1×10 −6 cm 2 /V s to ~2.5×10 −6 cm 2 /V s, the conductivity of mesoscopic TiO 2 was increased from ~5.6×10 −7 S/cm to ~1.6×10 −6 S/cm, and the trap density was reduced from ~1.2×10 16 cm −3 to ~9.3×10 15 cm −3 through Li-treatment. Therefore, the average power conversion efficiency was significantly enhanced from 14.84% to 17.26% at 1 sun condition by the Li-treatment of mesoscopic TiO 2 .
- Published
- 2015