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The effect of the metal ion and ligand design on the enantioselectivity and linkage isomerization of neutral cobalt and zinc bisthiosemicarbazone metallohelicates has been investigated in this work. The electrochemical synthesis has afforded the enantioselective formation of chirally pure cobalt helicates, and the ΛΛ isomer of a single enantiomer has been crystallized as only product for the cobalt methyl-substituted thiosemicarbazone helicate. Interestingly linkage isomers have been formed from zinc ethyl-substituted thiosemicarbazone helicate enantiomers for the first time. The co-existence of these isomers has been evaluated from the point of view of both experimental results and computational calculations. [ABSTRACT FROM AUTHOR]

A [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains. [ABSTRACT FROM AUTHOR]

The electrochemical oxidation of a tin plate in the presence of an acetonitrile suspension of the ligand bis-(4-N-methylthiosemicarbazone)-2,6-diacetylpyridine, H4DAPTsz-Me, yields the complex Sn(H2DAPTsz-Me)(H2O)2 (1). Recrystallisation of 1 in a methanol/acetone solution leads us to isolate yellow crystals of [Sn(H2DAPTsz-Me)(CH3OH)2] · CH3OH (2), structurally characterised. To the best of our knowledge, 2 is the first neutral Sn(II) complex derived from a pentadentate thiosemicarbazone Schiff base ligand. This complex shows a distorted pentagonal bipyramidal geometry for Sn(II), being the metal surrounded by the N3S2 donor set of the bideprotonated ligand [H2DAPTsz-Me]2−. This compound self-assembles into a 3D network through intermolecular hydrogen bonds. [Copyright &y& Elsevier]

A cobalt(II) thiosemicarbazonate mesocate has been structurally characterized as an unexpected mixture of conformational and linkage isomers. Moreover, we have shown that the absence of a nitrogen atom in the spacer of the helicand ligand H2La, enables the assembly of an achiral mesohelical complex in the case of Co(ll) ions. [ABSTRACT FROM AUTHOR]

The reaction of silver acetate with a phosphinothiosemicarbazone ligand, HLPPh, yielded the tetranuclear silver compound [Ag4(LPPh)4] · 2MeOH (1), which after recrystallization results in the cocrystallization of two different silver clusters, [Ag4(LPPh)4]a- [Ag4(LPPh)4]b · 8MeOH (2). The factors involved in the assembly of tetranuclear compounds derived from thiosemicarbazone ligands and the structural differences between the two clusters are analyzed herein. Additionally, HLPPh and complex 1 exhibit photoluminescence in solution at room temperature. [ABSTRACT FROM AUTHOR]